Materials Literature
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A large-scale single-crystalline ZnO hexangular prism was successfully synthesized through a simple gamma-irradiation method at room temperature and under ambient pressure. The product of a ZnO hexangular prism with a rim of 230 +/- 10 nm and a length up to 8.5 microm was well monodisperse and showed a very strong and…
Abstract A set of novel aromatic polyamides containing pyridine pendent groups was prepared from aromatic diamines and new monomers that are 5‐substituted derivatives of isophthalic acid bearing nicotinamide, isonicotinamide, or picolinamide groups. The polymers were obtained in high yield and high molecular weight by…
We present a quantitative theory for ferromagnetism in diluted III-V ferromagnetic semiconductors in the presence of the two types of defects commonly supposed to be responsible for compensation: As antisites and Mn interstitials. In each case we reduce the description to that of an effective random Heisenberg model w…
Surface immobilized polyamidoamine (PAMAM) dendrimer templated Pt nanoparticles were employed as precursors to heterogeneous catalysts. CO oxidation catalysis and in situ infrared spectroscopy were used to evaluate conditions for dendrimer removal. Infrared spectroscopy showed that PAMAM dendrimer amide bonds begin de…
Control of the size, shape, and structure of mesoporous transition metal oxide materials is important in their correlations with corresponding optoelectronic and photocatalytic properties. Highly ordered cubic phases of mixed-valent mesoporous molybdenum oxides have been prepared by the reduction and decomposition of…
Abstract Rubber compounds are reinforced with fillers such as carbon black and silica. The cure characteristics of a filled rubber compound vary with the filler type and content. The influence of the type of carbon black on the cure characteristics of carbon black filled natural rubber compounds is investigated using…
In this paper, we present a new method to fabricate carbon microspheres with supported silver nanoparticles on the surfaces. In this method, pollen grains were first treated with AgNO(3) aqueous solution, then preoxidized in air at 300 degrees C and carbonized in nitrogen at 600 degrees C, resulting in the silver/carb…
Coaxial nanowires: Single-crystalline CdS nanowires (NWs) are successfully coated with a uniform silica layer to give coaxial structures (see TEM image). The coating improves the high-temperature stability of the NWs and enhances their photoluminescence emission, compared with uncoated NWs. Stimulated emission and las…
Abstract Styrene‐ b ‐(ethylene‐ co ‐butylene)‐ b ‐styrene (SEBS) and styrene‐ b ‐(ethylene‐ co ‐propylene) (SEP, SEPSEP) block copolymers with different styrene contents and different numbers of blocks in the copolymer chain were functionalized by melt radical grafting with glycidyl methacrylate (GMA) and employed as…
A novel strategy for the preparation of a mesoporous silica film, in which the in-plane alignment of the honeycomb packed mesochannels is strictly controlled, is developed. The highly aligned porous structure is achieved by using a substrate with a rubbing-treated polyimide coating in the evaporation induced self-asse…
The crystallographic polarity of ZnO epilayers was determined by x-ray diffraction (XRD) using anomalous dispersion near the Zn K edge. The method is not destructive and is straightforward to carry out using a typical XRD measurement system. The polarity difference between the Zn (0001) and O (0001¯) surfaces could be…
The aim of the present work has been to study the possibility of obtaining modified gliadin films with improved water resistance and mechanical properties by means of promoting intermolecular covalent bonds between polypeptide chains. Prior to casting films, formaldehyde, glutaraldehyde, and glyoxal were used to cross…
The nematic droplets with director configurations intermediate between the bipolar and radial structures have been investigated experimentally and theoretically. The liquid crystal 4'-n-pentyl-4-cyanobiphenyl (5CB) with a variable addition of the lecithin dispersed in polyvinylbutyral has been used. The characteristic…
Abstract Lightweight and flexible composite coatings of p ‐toluene sulfonic acid doped polyaniline (PANI–TSA) with various mass fractions and polyacrylate were prepared for electromagnetic interference (EMI) shielding. Both the volume and surface conductivities of the composite coatings increased with increasing PANI–…
Dramatic morphological changes are observed in the Langmuir-Blodgett (LB) film assemblies of poly(ethylene glycol)-b-(styrene-r-benzocyclobutene) block copolymer (PEG-b-(S-r-BCB)) after intramolecular cross-linking of the S-r-BCB block to form a linear-nanoparticle structure. To isolate architectural effects and allow…
Abstract Thermoplastic elastomers (TPEs) based on poly(styrene‐ b ‐ethylene/butylene‐ b ‐styrene) (SEBS), modified with poly(2,6‐dimethyl‐1,4‐phenylene ether) (PPE), were investigated by a new testing method. The development and characterization of TPEs with improved temperature and oil resistance is a current area of…
Diamond is the hardest known material; however, its mechanical stability, in particular the yield strength σy, is not known. We report reproducible generation of plastic deformation of diamond at room and low temperatures. We determined σy=130–140GPa by measuring the pressure distribution over the diamond anvils and b…
The crystal structure of the delta-phase in the Sb-Te binary system has been determined by synchrotron powder diffraction. It is clearly shown that many intermetallic compounds, which have different stacking periods depending on compound composition, exist in this phase. These structures are based on the cubic ABC sta…
The influence of different solvents on the individualization of single-walled carbon nanotubes (SWNTs) was investigated by several methods. A stable solution of individual SWNTs in o-dichlorobenzene was obtained by a combination of ultrasonication and ultracentrifugation. Atomic force microscopy height analysis confir…
Novel 3-arm ABC, 4-arm ABCD, and 5-arm ABCDE asymmetric star polymers comprising the conductive polyacetylene precursor, poly(4-methylphenyl vinyl sulfoxide) (PMePVSO), and other segments, such as polystyrene, poly(alpha-methylstyrene), poly(4-methoxystyrene), poly(4-trimethylsilylstyrene), and poly(4-methylstyrene),…