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Soluble Polyamides and Polyimides Functionalized with Benzo‐15‐Crown‐5‐Pendant Groups

Eva M. Maya、Ángel E. Lozano、José G. de la Campa 等 4 位作者2004-02-01Macromolecular Rapid Communications

Abstract Summary: A new diamine monomer containing a crown ether was made to react with commercial diacid chlorides and dianhydrides to yield new aromatic polyamides and polyimides. The crown ether moiety was introduced as a pendant group so that the polymers showed enhanced solubility in organic solvents, good therma…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Space charge development and breakdown in XLPE under DC field

M. Abou-Dakka、A. Bulinski、S.S. Bamji2004-02-01IEEE Transactions on Dielectrics and Electrical Insulation

The correlation between space charge accumulation and insulation failure has been investigated in four, polyethylene-based materials subjected to a DC field of 50 kV/mm. Two of the materials contained tree-retardant additives and all four materials were aged for extended periods up to 19,000 h. The specimens were remo…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

High-Pressure Synthesis, Crystal Structure, and Properties of the New Orthorhombic Rare-Earth meta-Oxoborates RE(BO2)3 (RE = Dy – Lu)

Holger Emme、Tanja Nikelski、Thomas Schleid 等 6 位作者2004-02-01Zeitschrift für Naturforschung B

The new orthorhombic meta-oxoborates RE(BO 2 ) 3 (≡REB 3 O 6 ) (RE = Dy-Lu) have been synthesized under high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C. They are isotypic to the known ambient pressure phase Tb(BO 2 ) 3 , space group Pnma. In contrast to Dy(BO…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Chitosan: A Natural Biopolymer for the Adsorption of Residue Oil from Oily Wastewater

Abdul Latif Ahmad、S. Sumathi、B.H. Hameed2004-02-01Adsorption Science & Technology

Chitosan, poly-β-(1,4)-2-acetamido-2-deoxy-Đ-glucose ( N-deacetylated) was used as an adsorbent to adsorb the excess oil from oily wastewater. Chitosan is a biodegradable cationic biopolymer achieved by the extensive deacetylation of chitin obtained from prawn shell waste. Palm oil mill effluent (POME) is one of the m…

Nanocomposite Films for Food Packaging

Gadolinium Magnetic Resonance Contrast Agents Produce Analytic Interference in Multiple Serum Assays

Kerry A.S. Proctor、Lokinendi V. Rao、William L. Roberts2004-02-01American Journal of Clinical Pathology

Gadolinium magnetic resonance contrast agents are known to interfere with some clinical chemistry tests, particularly colorimetric assays for serum calcium. We studied the effects of 4 agents, gadodiamide, gadoversetamide, gadopentetate dimeglumine, and gadoteridol, for interference with multiple serum assays. Gadodia…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Structural and chemical response to varying [4] B content in zoned Fe-bearing olenite from Koralpe, Austria

John M. Hughes、Andreas Ertl、M. D. Dyar 等 6 位作者2004-02-01American Mineralogist

Tourmaline has recently been shown to incorporate large amounts of substituent B at the tetrahedral site. To characterize the response of the tourmaline atomic arrangement to differing amounts of substitution of B for Si, five samples were separated from a core-to-rim (∼3 mm) section of an Fe-bearing olenite with a da…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones: Synthesis of the Flavouring δ‐Decalactone Molecule

Avelino Corma、Sara Iborra、María Mifsud 等 5 位作者2004-02-01Advanced Synthesis & Catalysis

Abstract The system Sn‐Beta/hydrogen peroxide is applied to the Baeyer–Villiger oxidation of delfone to δ‐decalactone, which is an industrial fragrance. The reaction is carried out without solvent and with a substrate/catalyst ratio>200 (wt/wt). Starting with an enantiomerically enriched delfone it is shown that th…

Mesoporous Materials and CatalysisCatalysis for Biomass ConversionChemical Synthesis and Reactions

Effect of Rare‐Earth Dopants on Mechanical Properties of Alumina

D. Amutha Rani、Yu‐ichi Yoshizawa、Kiyoshi Hirao 等 4 位作者2004-02-01Journal of the American Ceramic Society

We report here about the effect of rare‐earth dopants on the improvement of room‐temperature mechanical properties of alumina. Rare‐earth ions (RE = Yb 3+ , Er 3+ , and La 3+ ) of different ionic radii in a minimum concentration of 1000 ppm were added as dopants individually to high‐purity alumina and densified by pre…

Advanced ceramic materials synthesisGlass properties and applicationsThermal properties of materials

Mathematical Modeling of Radon Emanation

Tomozo SASAKI、Yasuyoshi GUNJI、Takeshi Okuda2004-02-01Journal of Nuclear Science and Technology

It is well known that radon emanation is affected by moisture. The models which explain radon emanation can be considered to come in three types. One is to predict the maximum possibility of radon emanation assuming uniform distribution of radium in a solid grain independent of moisture. The other two are to explain m…

Radioactivity and Radon MeasurementsGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Combined Spectroscopic and Theoretical Study of Narrow Band Gap Heterocyclic Co-oligomers Containing Alternating Aromatic Donor ando-Quinoid Acceptor Units

M. Carmen Ruiz Delgado、V. Hernández、Juan T. López Navarrete 等 5 位作者2004-02-01The Journal of Physical Chemistry B

In this paper we analyze, with the help of density-functional theory calculations, the relationship between the molecular structure and the optical and vibrational properties of two narrow band gap π-conjugated co-oligomers containing an alternating sequence of aromatic donor and o -quinoid acceptor units. The optimiz…

Nonlinear Optical Materials ResearchSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers

Illite-Smectite Mixed-Layer Minerals in Felsic Volcaniclastic Rocks from Drill Cores, Kakkonda, Japan

Atsuyuki Inoue、Alain Meunier、Daniel Beaufort2004-02-01Clays and Clay Minerals

Abstract Crystallization processes of the illite-smectite (I-S) mixed-layer mineral series during alteration of felsic vitric materials in volcaniclastic sediments through two drill holes (IT-2 and IT-8) near the Kakkonda active geothermal system, Japan, were examined by optical microscopy, scanning and transmission e…

Clay minerals and soil interactionsTherapeutic Uses of Natural ElementsGeological and Geophysical Studies Worldwide

Microstructured Hydrophobic Skin for Hydrodynamic Drag Reduction

Ashwin Balasubramanian、Adam Miller、Othon K. Rediniotis2004-02-01AIAA Journal

6Wood, D. H., “A Three-Dimensional Analysis of Stall-Delay on Horizontal-Axis Wind Turbine,” Journal of Wind Engineering and Industrial Aerodynamics, Vol. 37, 1991, pp. 1–14. 7Cebecci, T., An Engineering Approach to the Calculation of Aerodynamic Flows, Springer, Berlin, 1999, pp. 51–62. 8Banks, W. H. H., and Gaad, G.…

Surface Modification and SuperhydrophobicityAerosol Filtration and Electrostatic PrecipitationIcing and De-icing Technologies

Biaxial stretching and structure of various LLDPE resins

Abdellah Ajji、Jean‐Marc Auger、Jiangbing Huang 等 4 位作者2004-02-01Polymer Engineering and Science

Abstract The purpose of this study is to investigate the biaxial stretchability, the structure developed, molecular orientation and shrinkage of linear low‐density octene copolymers (LLDPEs) biaxially stretched using a laboratory biaxial stretcher. Seven resins having different molecular characteristics were used in t…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

Prospects for Atomic Resolution and Neutron Crystallography in Drug Design

Leighton Coates、Dean A. A. Myles2004-02-01Current Drug Targets

The number of protein crystal structures being refined to atomic resolution is increasing each year as well as the size of proteins being studied. There are currently 346 structures in the protein data bank which have been refined to or beyond atomic resolution. The benefits of atomic resolution X-ray data are discuss…

Protein Structure and DynamicsEnzyme Structure and FunctionX-ray Diffraction in Crystallography

Synthesis of Aragonite by the Carbonation Process

Ji‐Whan Ahn、Kyungsun Choi、Seok‐Hyun Yoon 等 4 位作者2004-02-01Journal of the American Ceramic Society

The conditions necessary for synthesizing aragonite by the carbonation process were investigated. Aragonite formation was found to have no relation to the pH value, the mole ratio of MgCl 2 /Ca(OH) 2 , or the magnesium/calcium ion concentration in a solution. The synthesis of aragonite requires a concentration of magn…

Calcium Carbonate Crystallization and Inhibition

Effect of nitrogen addition on formation of secondary austenite in duplex stainless steel weld metals and resultant properties

V. Muthupandi、P. Bala Srinivasan、S. K. Seshadri 等 4 位作者2004-02-01Science and Technology of Welding & Joining

The gas tungsten arc (GTA) welding process is widely employed for fabricating duplex stainless steel (DSS) components. The microstructural phase balance is disturbed in DSS welds owing to the thermal cycles associated with welding and the desired phase balance is generally achieved either through control of heat input…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

New method to diffusion bond superalloys

A. A. Shirzadi、E. R. Wallach2004-02-01Science and Technology of Welding & Joining

A new method for diffusion bonding nickel base and cobalt base superalloys has been developed, which is based on non-chemical oxide removal before the bonding process. Using this method, diffusion bonds were produced in nickel base and cobalt base superalloys with ‘virtually invisible’ bond interfaces and compositions…

Material Properties and Applications

Synthesis of unsaturated polyester‐clay nanocomposites using reactive organoclays

Xiao‐An Fu、Syed Qutubuddin2004-02-01Polymer Engineering and Science

Abstract Two polymerizable cationic surfactants, vinylbenzyl n‐alkyldimethyl (n = 12 or 18) ammonium chlorides, were used for functionalization of montmorillonite (MMT) and preparation of unsaturated polyester (UP)‐clay nanocomposites. Polymerizable organophilic clays were prepared by exchanging the sodium ions of MMT…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsPorphyrin and Phthalocyanine Chemistry

Magnetic phase diagrams of manganites in the electron doping region

S. M. Dunaevskiĭ2004-02-01Physics of the Solid State

The paper reviews the physical properties of the R 1− x A x MnO 3 manganites ( R =La, Pr, Nd, Sm, etc., A =Ca, Sr, Ba) in the region of their electron doping where the divalent atom concentration x in the compound lies in the interval 0.5< x <1.0. Experimental magnetic phase diagrams of the most well-studied compounds…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Fire Retardance in Poly(butylene terephthalate). The Effects of Red Phosphorus and Radiation‐Induced Cross‐Links

Aliaksandr I. Balabanovich、Thomas A. Zevaco、W. Schnabel2004-02-01Macromolecular Materials and Engineering

Abstract Summary: The combustion performance of poly(butylene terephthalate) (PBT) can be improved by the addition of red phosphorus provided it is intermolecularly cross‐linked upon irradiation with 60 Co γ‐rays in the presence of triallyl cyanurate (TAC). At a content of 3 or 4 wt.‐% the latter significantly promote…

Polymer crystallization and propertiesFlame retardant materials and propertiesFiber-reinforced polymer composites