Materials Literature
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Injecting charge into dangling bond wires on Si(001) has been shown to induce polarons, which are weakly coupled to the underlying bulk phonons. We present elevated temperature tight binding molecular dynamics simulations designed to obtain a diffusion barrier for the diffusive motion of these polarons. The results in…
A new $\mathrm{N}\mathrm{H}\mathrm{\ensuremath{\cdots}}\mathrm{N}$ hydrogen-bonded ferroelectric crystal of $[{\mathrm{C}}_{\mathrm{6}}{\mathrm{H}}_{\mathrm{12}}{\mathrm{N}}_{\mathrm{2}}\mathrm{H}{\mathrm{]}}^{\mathrm{+}}\mathrm{R}\mathrm{e}{\mathrm{O}}_{\mathrm{4}}^{\mathrm{\ensuremath{-}}}$ ($\mathrm{d}\mathrm{a}\ma…
Hierarchically ordered macroporous networks (see Figure) composed of TiO2 tubes made of anatase nanocrystals have been fabricated by sol–gel coating of organic eggshell membrane consisting of interwoven shell membrane fibers. The unique hierarchical structure, together with the high surface area and substantial porosi…
Thin films of incompatible block copolymers self-assemble into highly regular supramolecular structures with characteristic dimensions in the 10–100 nm regime. There is increasing interest in controlling the resulting structures and utilizing them, for instance in the area of nanotechnology. So far, research has conce…
We introduce a path to a possibly new class of magnetic materials whose properties are determined entirely by the presence of a low concentration of specific point defects. Using model Hamiltonian and ab initio band structure methods we demonstrate that even large band gap nonmagnetic materials as simple as CaO with a…
In this paper we present the first results on emission in metamaterial. We show how the specific properties of metallic composite material can modify the emission of an embedded source. We show that under proper conditions the energy radiated by a source embedded in a slab of metamaterial will be concentrated in a nar…
The effect of free carriers on dispersion and damping of coupled phonon-plasmon modes is considered in the long-wave approximation. The electron and phonon scattering rate as well as Landau damping are taken into account.
We study the interaction between a one dimensional magnetic nanostructure and a thin film superconductor. It is shown that different magnetic distributions produce characteristic magnetic field signatures. Moreover, the magnetic structure can induce a weak link in the superconducting film, or be positioned directly ab…
Effect of urethane based bonding agent on the cure characteristics and mechanical properties of natural rubber/whole tyre reclaim–short nylon fiber composite have been studied. Tensile strength, tear strength, elongation at break, and heat build-up were studied in both orientations of the fibers. The processability as…
The nucleation behavior of poly(ε-caprolactone) (PCL) on friction-deposited poly(tetrafluoroethylene) (PTFE) was investigated by means of atomic force microscopy (AFM). This technique allows for imaging of the nucleation and crystallization processes in real time. An estimation of the PCL crystal orientation on the PT…
Ferromagnetic particles used for the catalytic growth of single-walled carbon nanotubes (SWNTs), which are embedded in a graphitic shell, represent a major obstacle in studying the bulk material. We have explored a purification method that is based on a mixing of the SWNT suspension with inorganic nanoparticles in an…
Ellipsometric parameters of layer-by-layer self-assembled osmium complex-derivatized poly(allylamine) and glucose oxidase multilayers, (PAH-Os) n (GOx) n, were measured at different wavelengths during oxidation−reduction cycles. Data were analyzed using an isotropic single layer model for the enzyme films. The changes…
The Hofmann−Klemen effect describes the observed reduction in expandable character and cation exchange capacity of lithium-saturated montmorillonite upon mild heating. Although it is widely accepted that the observed changes are due to the lithium ions becoming fixated within the layer structure of the clay mineral, s…
The spreading of small silicone oil drops (capillary regime of spreading) over various dry thick porous substrates (permeable in both normal and tangential directions) was experimentally investigated. The time evolution of the radii of both the drop base and the wetted region on the surface of the porous substrate was…
Poly(ethylene terephthalate) (PET) microfiber was in-situ formed by compounding PET with polyethylene (PE) through a single screw extruder of a Haake rheometer system, where a rod die with comparatively smaller diameter (2.1 mm) was used, and the extrudate was drawn in a certain drawing ratio (3.1:1) and quickly coole…
Dimethyl sulfoxide (CH3S(O)CH3: DMSO) is an important product of dimethyl sulfide (CH3SCH3: DMS) photooxidation. The mechanism of the OH-radical initiated oxidation of DMSO is still highly uncertain and a major aim of recent studies has been to establish if methane sulfinic acid (CH3S(O)OH: MSIA) is a major reaction p…
The preparations, X-ray structures, and detailed physical characterizations are presented for three new tetranuclear Fe(III)/RCO(2)(-)/phen complexes, where phen = 1,10-phenanthroline: [Fe(4)(OHO)(OH)(2)(O(2)CMe)(4)(phen)(4)](ClO(4))(3).4.4MeCN.H(2)O (1.4.4MeCN.H(2)O); [Fe(4)O(2)(O(2)CPh)(7)(phen)(2)](ClO(4)).2MeCN (2…
This paper discusses a direct (one-pot) polymerization process to prepare isotactic polypropylene (i-PP) having a terminal functional group including Cl, OH, and NH 2 . The chemistry involves metallocene-mediated propylene polymerization using rac -Me 2 Si[2-Me-4-Ph(Ind)] 2 ZrCl 2 /MAO complex in the presence of styre…
A series of aluminum complexes featuring with the ketiminate ligand, OCMeCHCMeNHAr (Ar = 2,6-(i)Pr(2)C(6)H(3), 1), have been prepared and characterized spectroscopically and structurally. Reactions of 1 with trialkylaluminum in 1:1 or 1:2 molar ratio generate four- and five-coordinated aluminum complexes (OCMeCHCMeNAr…
The influence of a basic aqueous solution on a hydrogen-bonding-directed layer-by-layer (LbL) self-assembled film, based on poly(acrylic acid) (PAA) and poly(4-vinylpyridine) (PVP), was investigated. The composition change of a multilayer film in a NaOH solution was monitored by X-ray photoelectron spectroscopy, Fouri…