Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRemote oxidation of unactivated carbon-hydrogen bonds in steroids via oxometalloporphinatesPaul A. Grieco and Timothy L. StukCite this: J. Am. Chem. Soc. 1990, 112, 21, 7799–7801Publication Date (Print):October 1, 1990Publication History Published online1 May 2002Published i…
A technique was developed to estimate the R ‐curve behavior of Y‐TZP using indentation‐produced flaws. This technique allows crack‐growth resistance to be determined for short crack extensions (micrometers). For Y‐TZP samples sintered at 1600°C for 1 h (mean grain size, 0.7 μm), the crackgrowth resistance increases ra…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanistic studies of olefin epoxidation by a manganese porphyrin and hypochlorite: an alternative explanation of saturation kineticsJames P. Collman, John I. Brauman, Philip D. Hampton, Hiroo Tanaka, D. Scott Bohle, and Robert T. HembreCite this: J. Am. Chem. Soc. 1990, 11…
Graphite-alkaline metal systems (lithium, potassium, rubidium, cesium) have been investigated under high-pressure conditions. New graphite intercalation compounds of C4M composition with alkali metal contents twice as high as in those obtained with traditional methods without applying high pressure have been produced.…
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction of cyclohexene with iodosylbenzene catalyzed by non-porphyrin complexes of iron(III) and aluminum(III). Newly discovered products and a new mechanistic proposalYihui Yang, Francois Diederich, and Joan Selverstone ValentineCite this: J. Am. Chem. Soc. 1990, 112, 21,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluorine-containing photoreactive polyimide. 6. Synthesis and properties of a novel photoreactive polyimide based on photo-induced acidolysis and the kinetics for its acidolysisToshihiko Omote, Ken'ichi Koseki, and Tsuguo YamaokaCite this: Macromolecules 1990, 23, 22, 4788–4…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA photoelectron-photoion coincidence study of iron pentacarbonylK. Norwood, A. Ali, G. D. Flesch, and C. Y. NgCite this: J. Am. Chem. Soc. 1990, 112, 21, 7502–7508Publication Date (Print):October 1, 1990Publication History Published online1 May 2002Published inissue 1 Octobe…
The viscosities of supercooled liquid fructose and glucose are measured between a lower viscosity limit corresponding to 95°C and an upper limit of about 10 6 Pa.s. The glass transition temperature of fructose is estimated from the viscosity data using different extrapolation procedures. The Vogel‐Tamman‐Fulcher and p…
The synthesis and crystal structure of two novel adducts of manganese(I1) and nitronyl nitroxide radicals of formula Mn- (hfac)z(NITpPy)z (I) and MnCI,(NITpPy), (II), where hfac = hexafluoroacetylacetonate and NlTpPy = 2-(4-pyridyl)- 4,4,5,5-tetramethyI-4,5-dihydroH-l-i midazolyl-1 - oxy1 3-oxide, are reported. Compou…
Abstract Ordered illite/smectite (I/S) and illite in a pelitic rock from a prograde metamorphic sequence in North Wales were observed by transmission electron microscopy. The dominant phyllosilicate noted was diagenetic-metamorphic illite, occurring as subparallel packets of layers, each about a few hundred Ångstroms…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyhedral aluminosilsesquioxanes as models for aluminosilicates: unique synthesis of anionic aluminum/silicon/oxygen frameworksFrank J. Feher and Keith J. WellerCite this: Organometallics 1990, 9, 10, 2638–2640Publication Date (Print):October 1, 1990Publication History Publ…
The ground state of the SiC3 molecule is found to be a closed-shell cyclic C2v symmetry structure which can be described as a four-membered ring with a transannular (cross ring) carbon–carbon bond, r(C–C)=1.469 Å. Theoretical studies with a triple-zeta plus double-polarization function (TZ2P) basis set in conjunction…
alpha-Spectrin, myosin light chain kinase (MLCK), and caldesmon have been detected in the nuclei of rat liver cells by 125I-calmodulin overlay, immunoblotting, and immunocytochemical methods. alpha-Spectrin is localized in the nuclear matrix, nuclear envelope, and nuclear pores. It has also been detected inside the nu…
Upon weekly i.m. injections of disodium gold thiomalate (Na2AuTM) 100% of A.SW mice produced IgG autoantibodies to antinuclear Ag and nucleolar Ag, respectively; about 70% of C57BL/6 mice produced IgG antinuclear Ag, whereas DBA/2 mice were resistant. Moreover, C57BL/6 mice, but not DBA/2 mice, showed increased mesang…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNuclear magnetic resonance study of polyisoprene/poly(vinylethylene) miscible blendsJoel B. Miller, K. J. McGrath, C. M. Roland, C. A. Trask, and A. N. GarrowayCite this: Macromolecules 1990, 23, 21, 4543–4547Publication Date (Print):October 1, 1990Publication History Publis…
An explanation for the mechanism generating a pretilted nematic liquid crystal conformation aligned on rubbed alkylbranched-polyimide layers is given based on a steric interaction model. An analytical calculation using this model was shown to agree fairly well with the data of torsional coupling strength obtained in t…
A model low-molecular-weight polymer mixture was studied as a function of temperature near the critical point by small-angle neutron scattering (SANS) and dynamic light scattering (DLS). SANS measurements reveal a crossover in the static susceptibility from mean-field to non-mean-field behavior at ${\mathit{T}}_{\math…
A model calculation based on the effective-medium theory of the oxygen-induced reconstruction of the (110) and (100) surfaces of Cu is presented. Equilibrium structures are calculated from a minimization of the total energy of the system. Missing-row-type reconstructions are found to be most stable in both cases, and…
Abstract This paper reports the use of Electron Parametric Resonance (EPR) for preliminary investigation of radicals formed from P,p'‐dioctyldiphenylamine (‘Irganox’, an antioxidant) during heating in a synthetic aviation lubricant base oil di‐2‐ethylhexylsebacate. Relative concentrations of radicals were found to be…