Materials Literature
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The Cu(II) and Fe(III) complexes of water-soluble tetrakis( N, N, N -trimethylanilinium)porphyrin (TTAP) and tetrakis( N -methylpyridyl)porphyrin (TMPyP) were placed within the interlayers of Ca(II)−montmorillonite through ion exchange. The free base forms of the porphyrins were also added to samples of Cu(II)− and Fe…
A previous investigation of EuVO4–BtVO4 binary system has indicated the existence of a solid-solution of Eu1–xBixVO4 up to x= 0.60, with a zircon-type structure. In this work we have reinvestigated the synthesis conditions, thus extending the upper limit to x= 0.74. X-Ray diffraction techniques associated with Raman a…
Self-assembled monolayers of alkanethiol derivatives have been used to control the anchoring of nematic films of alkylcyanobiphenyl (nCB) liquid crystals. Variation of the surface field, via the ω-functional group presented at the liquid crystal interface, has allowed us to explore both orientational wetting and ancho…
A typical hydrophilic monomer, acrylic acid (AAc), was graft polymerized onto poly (3-hydroxybutyrate) (PHB) and its copolymer poly (3-hydroxybutyrate-co-3-hydroxyvalerate) |P (HB-HV)| by 60Co-γ-rays preirradiation technique. Degree of grafting (Xg) of PHB was higher than that of the copolymer of 24 mol% HV content (2…
A scanning reference electrode technique (SRET) is described which is sufficiently stable and sensitive as to allow the automatic acquisition of time lapse isopotential contour maps of localised corrosion phenomena occurring in contact with molar concentrations of aqueous electrolyte. The SRET is demonstrated to be a…
Alkenyl succinic anhydride (ASA) gives sizing features efficiently to papersheet by being added to pulp suspensions as cationic ASA emulsions. Although the reactive structure of ASA is necessary for paper sizing, the previous paper revealed that alkenyl succinic acid (ASAcid), the hydrolyzed form of ASA, is the predom…
The concentration of the product nitric oxide, [NO(X 2 Π r )] product, formed in the title reactions is measured as a function of the vibrational energy distribution in the for v‘ ≤ 6 in a rapidly pumped discharge-flow reactor at ∼298 K and a total pressure of ∼2 Torr using laser-excited fluorescence techniques. For t…
A pH-dependent X-ray absorption fine structure (XAFS) study has been undertaken to provide a structural interpretation of the spectroscopic properties of the Met121 Glu mutant of azurin from Pseudomonas aeruginosa (Azp). Ligand binding studies have been carried out to investigate the effect of the cavity formed at the…
29 Si NMR spectrometry has been used to determine the number molecular weight distribution of polymerization degrees of a system of oligomers formed in the sol-gel polycondensation of tetraethoxysilane (TEOS). On the basis of identification of the oligomers, monitoring of the concentration changes during the initial p…
A fine pore characterization method for less-crystalline porous solids has been applied to activated carbons. In the analysis, the microporosity of the solid was classified into effective micropores and inaccessible pores, depending upon the accessibility of the pore to an N2 molecule at 77 K. The volume fraction of e…
This paper presents the design, analysis, and application of permanent magnets in a hysteresis motor with a view to improve the overall performance of such motors. The novel rotor consists of 36% cobalt steel alloys with neodymium boron iron permanent magnets. This hybrid design combines the advantageous performance f…
A low-mass solution to electrical insulation in the lunar environment may be possible by embedding bare HV conductors within the lunar soil itself. In the paper, a 'standard' NASA soil (lunar simulant) representing chemical and physical conditions found in some lunar samples was used in laboratory experiments, and its…
The plasma polymerization of a variety of substituted perfluorocyclohexane monomers (perfluorocyclohexane, perfluoromethylcyclohexane, perfluoro-1,2-dimethylcyclohexane, perfluoro-1,3-dimethylcyclohexane, and perfluoro-1,3,5-trimethylcyclohexane) is systematically compared under identical experimental conditions. The…
The structure of the complex [(η5-Cp*)Co]2H3, a compound once believed to have an unsupported CoCo double bond, has been accurately determined with single-crystal neutron diffraction techniques. The arrangement of three hydrogen atoms in an equilateral triangle bridging the cobalt−cobalt bond, first revealed in an X-r…
A high iron content saponite from Griffith Park, CA, (griffithite variety) was pillared by aluminum polycation solutions with different Al/clay ratios. X-ray diffraction shows that the intercalation process begins when aluminum polycation solutions are added, being completed during the dialysis washing of the samples.…
Subsurface bilayers are found to exist at the air−water interface of spontaneously forming vesicular solutions of sodium bis(2-ethylhexyl)sulfosuccinate, (AOT). The bilayers produce long-range repulsive forces that increase the stability of foam and emulsion films formed from these solutions. In addition, during film…
The effects of neutron-induced damage on the tritium retention have been studied experimentally for graphite and other carbon-based materials in the damage range ⩽4 dpa and for beryllium in the range ⩽40 dpa. The results for graphite and other carbon-based materials are in qualitative agreement with previous studies w…
In the present paper, we describe the synthesis and characterization of a novel negative-type soluble photosensitive polyimide (PSPI). A group of new photosensitive polyimides has been prepared by condensation of dianhydrides bearing photoreactive ester groups and aromatic diamines in N -methylpyrrolidone (NMP), follo…
Thread interaction at the warp and weft crossing points of a tensioned fabric is an important aspect of the mechanical properties of the fabric. In this paper, a new approach to measuring changes in thread interaction at the crossing points due to fabric structure and yarn irregularity is discussed. This has been achi…
Variable-temperature 59 Co nuclear magnetic longitudinal relaxation and line width measurements have been performed on dilute aqueous solutions of 12 octahedral cobalt(III) complexes spanning a large range of isotropic chemical shifts (−1−12 570 ppm) at two fields (4.7 and 11.7 T). A variable-concentration 59 Co longi…