Materials Literature
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Cyanide-bridged M(V)-Mn(III) (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Mn(III) Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations a…
A facile approach to prepare poly(3-hexylthiophene) (P3HT)/cadmium selenide quantum dot (CdSe QD) hybrid coaxial nanowires by a stepwise self-assembly process is reported. P3HT nanowires of ≈20 nm diameter are first prepared by self-assembly in a poor solvent such as cyclohexanone, and then as-prepared CdSe QDs are de…
Magneto-active shape memory composites by incorporating ferromagnetic microparticles in a thermo-responsive polyalkenamer, Cuevas, J M, Alonso, J, German, L, Iturrondobeitia, M, Laza, J M, Vilas, J L, León, L M
Bismuth-antimony-telluride alloy, Bi(0.5)Sb(1.5)Te3, nanocrystals (NCs) have been synthesized by direct chemical solution synthesis, in which the bismuth and antimony precursors, dissolved in a phenyl ether solution and coordinated with dodecanethiol, directly reacted with tellurium in trioctylphosphine. Transmission…
A flexible self-healing system capable of healing puncture damage has been manufactured. Our material consists of three layers: a poly(dimethyl siloxane) (PDMS) composite, embedded with a self-healing microcapsule system, sandwiched between two layers of poly(urethane) coated nylon. The total structure thickness range…
We present the results of high resolution core level photoelectron spectroscopy employed to investigate the electronic structure of clean and oxygen covered Ir(111) surface. Ir 4f7/2 core level spectra are shown to be very sensitive to the local atomic environment. For the clean surface we detected two distinct compon…
In this work, different CuFe(1-x)Cr(x)O(2) compositions with 0 <or= x <or= 1 were prepared by a standard solid-state reaction. These oxides crystallize with the delafossite structure. The phase stability and thermal behavior of the complete CuFe(1-x)Cr(x)O(2) solid solution was studied by thermogravimetric analysis an…
An urchin-like Zn/ZnO core−shell structure was synthesized and deposited directly on an indium tin oxide (ITO) glass substrate by using a thermal evaporation method. Structural characterization reveals that the hybrid material is composed of a micrometer scale sphere-shaped metallic Zn core and a shell made up of nume…
As titanium dioxide (TiO(2)) nanoparticles are widely used commercially, the potential effects of TiO(2) nanoparticles on humans are a concern. To evaluate the effects of TiO(2) nanoparticles on hepatic and renal functions and correlate changes to oxidative stress, Sprague-Dawley rats were treated with TiO(2) particle…
We present an extensive molecular simulation study of the behavior of a flexible hydrophobic 25-mer polymer at interfaces presenting a range of chemistries from hydrophobic (-CH(3)) to hydrophilic (-CONH(2)). We quantify the free energy of adsorption, conformational equilibria, and translational and conformational dyn…
A smart copolymer film that is sensitive to nucleotide species in solution was developed. The film exhibits ann excellent reversible wettability response to nucleotide solutions, which is accompanied by a phase change and the corresponding swell and shrinkage of the copolymer.
Hierarchical poly(3-hexylthiophene)(P3HT)/carbon nanotube (CNT) supramolecular structures were fabricated through a bottom-up CNT induced P3HT crystallization strategy. P3HT nanowires growing perpendicular from CNT surface have uniform width and height. The density and the length of these nanowires can be controlled b…
For the thermal response of shape-memory polymer (SMP) it has been experimentally demonstrated that the actuation can be achieved using interactive solvent. In this paper, the effect of the solubility parameter of the interactive solvent on the shape recovery behavior and glass transition temperature of polystyrene SM…
A systematic methodology is presented for the selective crystallization of the metastable form of a monotropic dimorph, l -glutamic acid, for batch cooling crystallization. Attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy coupled with chemometrics was used to determine the solute concentr…
Spontaneous formation of smectic and columnar structures was observed when spherical gold nanoparticles were functionalized with mesogenic thiols (see layered structure and X-ray pattern of a sample in smectic phase). The particle ordering is stimulated by softening of the interparticle potential and flexibility for d…
Divide and conquer: Polymer nanoparticles with phase-separation structures prepared with block copolymers and homopolymer blends were used to fabricate unique suprapolymer structures by cross-linking one polymer moiety and dissolving the other (see scheme; PI = polyisoprene, PSt = polystyrene).
Flow-induced aggregation of colloidal particles leads to aggregates with fairly high fractal dimension (df approximately 2.4-3.0) which are directly responsible for the observed rheological properties of sheared dispersions. We address the problem of the decrease in aggregate size with increasing hydrodynamic stress,…
Abstract Disorder and doping can strongly affect the properties of graphene. Here we analyze these effects on several samples by Raman spectroscopy. In particular, we show that pristine and unprocessed graphene samples deposited on silicon, covered with a thin silicon oxide layer, show strong variations in their Raman…
Electrically generated spin polarization is probed directly in bulk GaN using Kerr rotation spectroscopy. A series of n-type GaN epilayers are grown in the wurtzite phase both by molecular beam epitaxy (MBE) and metalorganic chemical vapor deposition (MOCVD) with a variety of doping densities chosen to broadly modulat…
Spontaneous emission (SE) from a two-level atom in a photonic crystal (PC) with anisotropic one-band model is investigated using the fractional calculus. Analytically solving the kinetic equation in terms of the fractional exponential function, the dynamical discrepancy of SE between the anisotropic and isotropic syst…