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Hierarchical Porous Nickel Cobaltate Nanoneedle Arrays as Flexible Carbon-Protected Cathodes for High-Performance Lithium–Oxygen Batteries

Hairong Xue、Shichao Wu、Jing Tang 等 7 位作者2016-03-11ACS Applied Materials & Interfaces

Rechargeable lithium-oxygen (Li-O2) batteries are consequently considered to be an attractive energy storage technology because of the high theoretical energy densities. Here, an effective binder-free cathode with high capacity for Li-O2 batteries, needle-like mesoporous NiCo2O4 nanowire arrays uniformly coated on the…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Experimental Inferential Structure Determination of Ensembles for Intrinsically Disordered Proteins

David H. Brookes、Teresa Head‐Gordon2016-03-11Journal of the American Chemical Society

We develop a Bayesian approach to determine the most probable structural ensemble model from candidate structures for intrinsically disordered proteins (IDPs) that takes full advantage of NMR chemical shifts and J-coupling data, their known errors and variances, and the quality of the theoretical back-calculation from…

Protein Structure and DynamicsEnzyme Structure and FunctionMolecular spectroscopy and chirality

Approaching Bulk Carrier Dynamics in Organo-Halide Perovskite Nanocrystalline Films by Surface Passivation

Robert Stewart、Christopher Grieco、Alec V. Larsen 等 5 位作者2016-03-11The Journal of Physical Chemistry Letters

The electronic properties of organo-halide perovskite absorbers described in the literature have been closely associated with their morphologies and processing conditions. However, the underlying origins of this dependence remain unclear. A combination of inorganic synthesis, surface chemistry, and time-resolved photo…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesSolid-state spectroscopy and crystallography

Synthesis of well-defined Fe3O4 nanorods/N-doped graphene for lithium-ion batteries

Jiqing Jiao、Wen-Da Qiu、Jianguo Tang 等 5 位作者2016-03-11Nano Research

The geometric size and distribution of magnetic nanoparticles are critical to the morphology of graphene (GN) nanocomposites, and thus they can affect the capacity and cycling performance when these composites are used as anode materials in lithium-ion batteries (LiBs). In this work, Fe 3 O 4 nanorods were deposited o…

Advancements in Battery MaterialsGraphene research and applicationsMagnetic Properties and Synthesis of Ferrites

Use of genetically encoded, light-gated ion translocators to control tumorigenesis

Brook T. Chernet、Dany Spencer Adams、Maria Lobikin 等 4 位作者2016-03-11Oncotarget

// Brook T. Chernet 1 , Dany S. Adams 1 , Maria Lobikin 1 , Michael Levin 1 1 Center for Regenerative and Developmental Biology and Department of Biology Tufts University, Medford, MA 02155, USA Correspondence to: Michael Levin, e-mail: michael.levin@tufts.edu Keywords: V mem , bioelectricity, voltage, RAS, optogeneti…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchbioluminescence and chemiluminescence research

Photosensitizer-Conjugated Hyaluronic Acid-Shielded Polydopamine Nanoparticles for Targeted Photomediated Tumor Therapy

Jieun Han、Wooram Park、Sin‐jung Park 等 4 位作者2016-03-11ACS Applied Materials & Interfaces

Photodynamic therapy (PDT) is a widely used clinical option for tumor therapy. However, the clinical utilization of conventional small-molecule photosensitizers (PSs) for PDT has been limited by their low selectivity for disease sites, and undesirable photoactivation. To overcome these limitations, we demonstrated a t…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

μ-Nitrido Diiron Macrocyclic Platform: Particular Structure for Particular Catalysis

P. Afanasiev、Alexander B. Sorokin2016-03-11Accounts of Chemical Research

The ultimate objective of bioinspired catalysis is the development of efficient and clean chemical processes. Cytochrome P450 and soluble methane monooxygenase enzymes efficiently catalyze many challenging reactions. Extensive research has been performed to mimic their exciting chemistry, aiming to create efficient ch…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Increased Nanoparticle Delivery to Brain Tumors by Autocatalytic Priming for Improved Treatment and Imaging

Liang Han、Derek Kai Kong、Ming‐Qiang Zheng 等 19 位作者2016-03-11ACS Nano

The blood-brain barrier (BBB) is partially disrupted in brain tumors. Despite the gaps in the BBB, there is an inadequate amount of pharmacological agents delivered into the brain. Thus, the low delivery efficiency renders many of these agents ineffective in treating brain cancer. In this report, we proposed an "autoc…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranosticsBarrier Structure and Function Studies

Supramolecular Vesicles Based on Complex of Trp-Modified Pillar[5]arene and Galactose Derivative for Synergistic and Targeted Drug Delivery

Kui Yang、Yincheng Chang、Jia Wen 等 8 位作者2016-03-11Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTSupramolecular Vesicles Based on Complex of Trp-Modified Pillar[5]arene and Galactose Derivative for Synergistic and Targeted Drug DeliveryKui Yang, Yincheng Chang, Jia Wen, Yuchao Lu, Yuxin Pei*, Shoupeng Cao, Feng Wang, and Zhichao Pei*View Author Information College…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

Atomically thin optical lenses and gratings

Jiong Yang、Zhu Wang、Fan Wang 等 11 位作者2016-03-11Light Science & Applications

Two-dimensional (2D) materials have emerged as promising candidates for miniaturized optoelectronic devices due to their strong inelastic interactions with light. On the other hand, a miniaturized optical system also requires strong elastic light–matter interactions to control the flow of light. Here we report that a…

Metamaterials and Metasurfaces Applications2D Materials and ApplicationsPlasmonic and Surface Plasmon Research

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)-co-chlorinated Poly(vinyl chloride) (PVC-co-CPVC) Fiber

Suree Brown、Yan‐Feng Yue、Li‐Jung Kuo 等 10 位作者2016-03-11Industrial & Engineering Chemistry Research

The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical p…

Advanced Polymer Synthesis and CharacterizationRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Ratiometric Array of Conjugated Polymers–Fluorescent Protein Provides a Robust Mammalian Cell Sensor

Subinoy Rana、S. Gokhan Elci、Rubul Mout 等 11 位作者2016-03-11Journal of the American Chemical Society

Supramolecular complexes of a family of positively charged conjugated polymers (CPs) and green fluorescent protein (GFP) create a fluorescence resonance energy transfer (FRET)-based ratiometric biosensor array. Selective multivalent interactions of the CPs with mammalian cell surfaces caused differential change in FRE…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsAdvanced Biosensing Techniques and Applications

Systematic study of Ge1−xSnx absorption coefficient and refractive index for the device applications of Si-based optoelectronics

Huong Tran、Wei Du、Seyed Amir Ghetmiri 等 11 位作者2016-03-11Journal of Applied Physics

The absorption coefficient and refractive index of Ge1−xSnx alloys (x from 0% to 10%) were characterized for the wavelength range from 1500 to 2500 nm via spectroscopic ellipsometry at room temperature. By applying physical models to fit the obtained data, two empirical formulae with extracted constants and coefficien…

Photonic and Optical DevicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Solution-Processed CuS NPs as an Inorganic Hole-Selective Contact Material for Inverted Planar Perovskite Solar Cells

Haixia Rao、Weihai Sun、Senyun Ye 等 9 位作者2016-03-11ACS Applied Materials & Interfaces

Organic-inorganic hybrid perovskite solar cells (PSCs) have drawn worldwide intense research in recent years. Herein, we have first applied another p-type inorganic hole-selective contact material, CuS nanoparticles (CuS NPs), in an inverted planar heterojunction (PHJ) perovskite solar cell. The CuS NP-modification of…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters

Sophie Feuillastre、Mathilde Pauton、Long‐Hui Gao 等 11 位作者2016-03-11Journal of the American Chemical Society

This work describes the first thermally activated delayed fluorescence material enabling circularly polarized light emission through chiral perturbation. These new molecular architectures obtained through a scalable one-pot sequential synthetic procedure at room temperature (83% yield) display high quantum yield (up t…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Nanotechnology-Based Drug Delivery Systems for Photodynamic Therapy of Cancer: A Review

Giovana Calixto、Jéssica Bernegossi、Laura Marise de Freitas 等 5 位作者2016-03-11Molecules

Photodynamic therapy (PDT) is a promising alternative approach for improved cancer treatment. In PDT, a photosensitizer (PS) is administered that can be activated by light of a specific wavelength, which causes selective damage to the tumor and its surrounding vasculature. The success of PDT is limited by the difficul…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsPhotodynamic Therapy Research Studies

Effective energy storage from a triboelectric nanogenerator

Yunlong Zi、Jie Wang、Sihong Wang 等 7 位作者2016-03-11Nature Communications

To sustainably power electronics by harvesting mechanical energy using nanogenerators, energy storage is essential to supply a regulated and stable electric output, which is traditionally realized by a direct connection between the two components through a rectifier. However, this may lead to low energy-storage effici…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules

Jun Zhao、Ye-Nan Wang、Wen‐Wen Dong 等 6 位作者2016-03-11Inorganic Chemistry

A new luminescent terbium-metal-organic framework [Tb3(L)2(HCOO)(H2O)5]·DMF·4H2O (1) (H4L = 4,4'-(pyridine-3,5-diyl)diisophthalic acid) has been successfully assembled by Tb(3+) ions and an undeveloped pyridyl-tetracarboxylate. Compound 1 exhibits a 3D porous (3,8)-connected (4.5(2))2(4(2).5(12).6(6).7(5).8(3)) topolo…

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionLanthanide and Transition Metal Complexes

In Situ Raman Spectroscopy of Copper and Copper Oxide Surfaces during Electrochemical Oxygen Evolution Reaction: Identification of Cu III Oxides as Catalytically Active Species

Yilin Deng、Albertus D. Handoko、Yonghua Du 等 5 位作者2016-03-11ACS Catalysis

Scanning electron microscopy, X-ray diffraction, cyclic voltammetry, chronoamperometry, in situ Raman spectroscopy, and X-ray absorption near-edge structure spectroscopy (XANES) were used to investigate the electrochemical oxygen evolution reaction (OER) on Cu, Cu 2 O, Cu(OH) 2, and CuO catalysts. Aqueous 0.1 M KOH wa…

Electrocatalysts for Energy ConversionElectrochemical Analysis and ApplicationsCopper-based nanomaterials and applications

Metal–Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production

Amarajothi Dhakshinamoorthy、Abdullah M. Asiri、Hermenegildo Garcı́a2016-03-11Angewandte Chemie International Edition

Metal-organic frameworks (MOFs) are crystalline porous materials formed from bi- or multipodal organic linkers and transition-metal nodes. Some MOFs have high structural stability, combined with large flexibility in design and post-synthetic modification. MOFs can be photoresponsive through light absorption by the org…

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis