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Excitonic Coupling and Femtosecond Relaxation of Zinc Porphyrin Oligomers Linked with Triazole Bridge: Dynamics and Modeling

Aleksey Bukreev、K. M. Mikhailov、I. V. Shelaev 等 9 位作者2016-03-03The Journal of Physical Chemistry A

The synthesis of new zinc porphyrin oligomers linked by a triazole bridge was carried out via "click" reaction. A split in the porphyrin oligomer B-band was observed. It was considered as evidence of exciton-excitonic coupling. The relaxation of excited states in Q-band porphyrin oligomers was studied by the femtoseco…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

SHEARING STRENGTH TEST OF ORTOPEDIC TITANIUM ALLOY SCREW PRODUCED IN THE PROCESS OF 3D TECHNOLOGY PRINTING

Patrycja Ruszniak、Jerzy Jóźwik、Dawid Ostrowski 等 4 位作者2016-03-03Advances in Science and Technology – Research Journal

The aim of the present article is the assessment of technical shear resistance (technological shear) of orthopedic screw made of titanium alloy Ti6Al4V, produced using incremental technology in the process of 3D printing process. The first part of the work presents incremental techniques in production engineering. The…

Bone Tissue Engineering MaterialsAdditive Manufacturing Materials and ProcessesTitanium Alloys Microstructure and Properties

Liquid-liquid Extraction of Copper(II) ions from Sulfate Media with Salicylidene Chloroaniline Isomers

Mihad Bouzgou、Sana Almi、Djamel Barkat2016-03-03Analytical Chemistry Letters

The liquid-liquid extraction of copper(II) ions from sulfate media with three Schiff bases extractants used were salicylidene-2-chloroaniline, sal-2-cla, salicylidene-3-chloroaniline, sal-3-cla, and salicylidene-4-chloroaniline, sal-4-cla, diluted in chloroform at 25°C are studied with the following parameters: pH and…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Ternary diffusion path in terms of eigenvalues and eigenvectors

L. R. Ram‐Mohan、M. A. Dayananda2016-03-03The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Based on the transfer matrix methodology, a new analysis is presented for the description of slopes of the ternary diffusion path for a solid–solid diffusion couple. Concentration profiles and diffusion paths for isothermal, ternary diffusion couples are examined in the context of eigenvalues and eigenvectors obtained…

Thermal properties of materialsComposite Material MechanicsBrake Systems and Friction Analysis

Design and analysis of frequency-independent reflectionless single-layer metafilms

Yasuhiro Tamayama2016-03-03Optics Letters

We develop a theory for realizing frequency-independent, reflectionless, single-layer metafilms based on the Brewster effect. A designed metafilm based on the theory is numerically analyzed using a finite-difference time-domain method. The numerical analysis demonstrates that the reflectance of the metafilm vanishes i…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsAdvanced Antenna and Metasurface Technologies

In-situ Quasi-Instantaneous e-beam Driven Catalyst-Free Formation Of Crystalline Aluminum Borate Nanowires

Ignacio González-Martínez、Thomas Gemming、Rafael G. Mendes 等 9 位作者2016-03-03Scientific Reports

The catalyst-assisted nucleation and growth mechanisms for many kinds of nanowires and nanotubes are pretty well understood. At times, though, 1D nanostructures form without a catalyst and the argued growth modes have inconsistencies. One such example is the catalyst-free growth of aluminium borate nanowires. Here we…

Quantum Dots Synthesis And PropertiesBoron and Carbon Nanomaterials ResearchCopper-based nanomaterials and applications

Multifunktionale Beschichtung verbessert Zelladhäsion auf Titan durch kooperativ wirkende Peptide

Mareen Pagel、Rayk Hassert、Torsten John 等 7 位作者2016-03-03Angewandte Chemie

Abstract Die Verbesserung der Zelladhäsion auf einer Biomaterialoberfläche ist entscheidend für den Langzeiterfolg eines Titanimplantats. Ein neues Konzept ist die Kombination aus sehr affiner und stabiler Adhäsion an Titanoberflächen mit spezifisch zellbindenden Motiven in einem Molekül. Ein l‐3,4‐Dihydroxyphenylalan…

Polymer Surface Interaction StudiesChemical Synthesis and AnalysisMolecular Junctions and Nanostructures

Random-diluted triangular plaquette model: Study of phase transitions in a kinetically constrained model

Silvio Franz、Giacomo Gradenigo、Stefano Spigler2016-03-03Physical review. E

We study how the thermodynamic properties of the triangular plaquette model (TPM) are influenced by the addition of extra interactions. The thermodynamics of the original TPM is trivial, while its dynamics is glassy, as usual in kinetically constrained models. As soon as we generalize the model to include additional i…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Recent Patents on Nanoparticles and Nanoformulations for Cancer Therapy

Animikh Ray、Abhirup Mandal、Mary Joseph 等 4 位作者2016-03-03Recent Patents on Drug Delivery & Formulation

Cancer is a major malignancy which has claimed numerous lives worldwide. Despite huge resources being utilized to develop cancer therapeutics, no effective cure has been found so far. Hence there is a need to look at emerging technologies for a solution. Nanoparticle is one such technology that has become feasible and…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsGraphene and Nanomaterials Applications

Optical and electron beam studies of gamma-irradiated AlGaN/GaN high-electron-mobility transistors

Anupama Yadav、Cameron Glasscock、Elena Flitsiyan 等 11 位作者2016-03-03Radiation effects and defects in solids

The impact of 60Co gamma-irradiation on n-channel AlGaN/GaN high-electron-mobility transistors was studied by means of temperature-dependent electron beam-induced current (EBIC) and cathodoluminescence (CL) techniques. For the doses up to ∼250 Gy, an enhancement of minority carrier transport was observed as evident fr…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Surface modification of activated carbon fabric with ozone, part 1: Kinetics and oxidation degree

Franco Cataldo、Mihai V. Putz、Ornella Ursini 等 4 位作者2016-03-03Fullerenes Nanotubes and Carbon Nanostructures

Two samples of activated carbon fabrics (ACF) with very high surface area (>1300 to >1800 m2/g) were reacted with ozone inside a closed flask under static conditions. The kinetics of ozone decomposition and reaction with the ACF surface was measured in the gas phase using Fourier transform infrared analysis (FT-IR) sp…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchFiber-reinforced polymer composites

In-vivo evaluation of apocynin for prevention of Helicobacter pylori-induced gastric carcinogenesis

Tessa Horemans、Gaëlle Boulet、Marian Van Kerckhoven 等 10 位作者2016-03-03European Journal of Cancer Prevention

The emergence of antibiotic-resistant Helicobacter pylori strains impacts the efficacy of eradication therapy and promotes the development of alternative treatment strategies. Apocynin inhibits neutrophil NADPH oxidase and hence may decrease reactive oxygen species-mediated tissue damage in H. pylori-infected stomach…

Helicobacter pylori-related gastroenterology studiesGastric Cancer Management and OutcomesPhytochemistry and Bioactive Compounds

Synthesis, microstructure, optical and field emission studies of iron vanadium oxide nanosheets

Satish S. Badadhe、Sachin R. Suryawanshi、Rounak Naphade 等 7 位作者2016-03-03Journal of Physics D Applied Physics

Abstarct We report a single step growth of thin graphene-like, densely packed FeV 3 O 8 (FVO) nanosheets on silicon substrates via facile hydrothermal synthesis. These nanosheets have dimensions of a few microns with thin edges, offering very high aspect ratio. These FVO nanosheets exhibit excellent field emission beh…

Carbon Nanotubes in CompositesPorphyrin and Phthalocyanine ChemistryTransition Metal Oxide Nanomaterials

Steady- and Transient-State Analyses of Fully Ceramic Microencapsulated Fuel with Randomly Dispersed Tristructural Isotropic Particles via Two-Temperature Homogenized Model—II: Applications by Coupling with COREDAX

Yoonhee Lee、Bumhee Cho、Nam Zin Cho2016-03-03Nuclear Engineering and Technology

In Part I of this paper, the two-temperature homogenized model for the fully ceramic microencapsulated fuel, in which tristructural isotropic particles are randomly dispersed in a fine lattice stochastic structure, was discussed. In this model, the fuel-kernel and silicon carbide matrix temperatures are distinguished.…

Advanced ceramic materials synthesisNuclear reactor physics and engineeringNuclear Materials and Properties

Fluorinated microwave exfoliated graphite oxide: structural features and double layer capacitance

P.A. Khavrel、E.V. Skokan、Alexey V. Rybalchenko 等 9 位作者2016-03-03Fullerenes Nanotubes and Carbon Nanostructures

Fluorinated microwave exfoliated graphite oxide (MEGO) samples containing 5.7–29.3 at.% of fluorine were prepared by gas phase treatment of MEGO with XeF2. According to X-ray photoelectron spectroscopy and infrared spectroscopy data, fluorination of MEGO occurs at C=C bonds while leaving the oxygenated domains intact,…

Graphene research and applicationsSupercapacitor Materials and FabricationFiber-reinforced polymer composites

Three-way catalytic converter reactions aspects at near-ambient temperatures on modified Pd-surfaces

Kanak Roy、Ruchi Jain、Manoj Kumar Ghosalya 等 5 位作者2016-03-03Comptes Rendus Chimie

The dissolution of oxygen in palladium plays an important role in palladium catalysis. The present study shows that the surface modification (SM) due to the dissolution of atomic oxygen into the subsurfaces of palladium can be used as a control to tune its catalytic activity. CO oxidation and NO + H 2 + O 2 reaction w…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceSemiconductor materials and devices

Unconventional superconductivity and interaction induced Fermi surface reconstruction in the two-dimensional Edwards model

Dai-Ning Cho、Jeroen van den Brink、Holger Fehske 等 5 位作者2016-03-03Scientific Reports

We study the competition between unconventional superconducting pairing and charge density wave (CDW) formation for the two-dimensional Edwards Hamiltonian at half filling, a very general two-dimensional transport model in which fermionic charge carriers couple to a correlated background medium. Using the projective r…

Organic and Molecular Conductors ResearchIron-based superconductors researchElectronic and Structural Properties of Oxides

The steady-state and transient electron transport within bulk zinc-blende indium nitride: The impact of crystal temperature and doping concentration variations

Poppy Siddiqua、Stephen K. O’Leary2016-03-03Journal of Applied Physics

Within the framework of a semi-classical three-valley Monte Carlo electron transport simulation approach, we analyze the steady-state and transient aspects of the electron transport within bulk zinc-blende indium nitride, with a focus on the response to variations in the crystal temperature and the doping concentratio…

Semiconductor Quantum Structures and DevicesGaN-based semiconductor devices and materialsGa2O3 and related materials

From natural photosynthesis to molecular photovoltaics

Danuta Wróbel2016-03-03Molecular Crystals and Liquid Crystals

In many technological applications the mankind mimics the nature. One of the excellent examples is photosynthesis. The knowledge of the natural photosynthesis mechanisms is extremely useful in understanding of molecular processes occurring in photovoltaics.In this review article the photophysical fundamental aspects o…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryFullerene Chemistry and Applications

Influence of carbides morphology on the mechanical properties for Fe-C-V alloys

M. Kawalec、M. Górny2016-03-03International Journal of Cast Metals Research

The paper presents the results of tests on the spheroidising treatment of vanadium carbides VC done with magnesium master alloy and RE. The conducted metallographic studies have shown that introducing the magnesium master alloy to an Fe–C–V system of eutectic composition causes the crystallisation of spheroidal carbid…

Metal and Thin Film MechanicsAdvanced materials and compositesMetal Alloys Wear and Properties