Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDifferential dynamic modulus of polyisobutylene with high molecular weight. 1. Single-step large shearing deformationsYoshinobu Isono, Kenji Itoh, Toshio Komiyatani, and Teruo FujimotoCite this: Macromolecules 1991, 24, 15, 4429–4432Publication Date (Print):July 1, 1991Publi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTControl of molecular tilt angles in oriented monolayers deposited by a chemical adsorption technique and application of the monolayers as an alignment filmNorihisa Mino, K. Nakajima, and K. OgawaCite this: Langmuir 1991, 7, 7, 1468–1472Publication Date (Print):July 1, 1991Pu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetalloporphyrin photochemistry with matrix isolationKenneth S. Suslick, Jocelyn F. Bautista, and Randall A. WatsonCite this: J. Am. Chem. Soc. 1991, 113, 16, 6111–6114Publication Date (Print):July 1, 1991Publication History Published online1 May 2002Published inissue 1 July…
Abstract A chiral aluminium complex of a Schiff&s base is a new initiator for the preparation of defined (number‐average degree of polymerization, functionality) oligomers derived from heterocyclic monomers (oxiranes, β‐lactones).
Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful…
Abstract The synthesis of highly uniform (1,08 ≤ M w / M n ≤ 1,13) telechelic poly(ε‐caprolactone) terminated at both ends with OH groups and its derivatization leading to poly(ε‐caprolactone) with pyrene end‐groups are described. The synthesis, carried out in THF at room temperature, involves initiation with (CH 3 CH…
The radiative and Auger emissions in cascade (RAC) model constructed earlier [G. Omar and Y. Hahn, Phys. Rev. A (to be published)] is applied to the calculation of the final-charge-state distribution in the decay of ${\mathrm{Ar}}^{+}$(1s\ifmmode\bar\else\textasciimacron\fi{}) with an initial 1s hole created by synchr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChain conformation and dynamics of crystalline 1,4-trans-polyisoprene and its inclusion compound with perhydrotriphenyleneFrederic C. Schilling, Piero Sozzani, and Frank A. BoveyCite this: Macromolecules 1991, 24, 15, 4369–4375Publication Date (Print):July 1, 1991Publication…
Polycrystalline samples of Ba2Me2Fe28O46 (Me2-X, Me=Ni, Cu, Mg, and Zn) hexagonal ferrite have been prepared by the classical ceramic method. Low-temperature magnetic properties and Curie temperature were investigated. The substitution of Fe2+ ion with Ni2+, Cu2+, and Mg2+ ions decreases spontaneous moment of Me2-X du…
Chemical transformations that occur under flooded conditions in two limestone soils from flood-prone agricultural areas of south Florida were investigated. Redox potential and pH of Krome very gravelly loam and Chekika very gravelly loam soils were monitored over a 5-week submergence period. Within 2 days of flooding,…
Abstract The effect of ultrasonic waves upon foam extrusion has been investigated by using a special die attached to an extruder. The die consists of a special ultrasonic horn, having a circular channel, that vibrates at 20 KHz. Various ultrasonic amplitudes and flow rates were employed during extrusion of a foamed po…
We present new Monte Carlo calculations of the third and fourth virial coefficients for isotropic systems of different two-dimensional hard convex bodies: ellipses, rectangles and spherocylinders for various aspect ratios, and needles. Our results differ significantly from previously published values. The accuracy of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIntramolecular charge transfer properties of dicyanovinyl-substituted aromaticsAlan R. Katritzky, Dong Wei Zhu, and Kirk S. SchanzeCite this: J. Phys. Chem. 1991, 95, 15, 5737–5742Publication Date (Print):July 1, 1991Publication History Published online1 May 2002Published in…
Experiments show that the characteristic periodic damage pattern that results from the optical fuse can be produced by purely thermal means by heating the fiber to temperatures in the 700-1000 degrees C range in the absence of light. The nature of the damage region bubbles suggests local temperatures high enough to so…
Dissolution rates of two commercial soda—lime silicate glasses and Pyrex borosilicate glass (Corning 7740) have been measured as a function of pH. The dissolution rate was constant with time and increased with increase in pH from 4 to 9. The activation energy for dissolution was nearly constant with pH for the Pyrex b…
A new genus of naviculoid diatoms is described from subalpine tarns on Mount Giluwe (Papua New Guinea). Its relationship to other groups is discussed.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoluminescence studies of silver-exchanged cadmium selenide crystals: modification of a chemical sensor for aniline derivatives by heterojunction formationLarry K. Leung, Norma J. Komplin, Arthur B. Ellis, and Ned TabatabaieCite this: J. Phys. Chem. 1991, 95, 15, 5918–592…
A vapor explosion is a physical event in which a hot liquid (fuel) transfers its internal energy to a colder, more volatile liquid (coolant); thus the coolant vaporizes at high pressures and expands analyses work on its surroundings. In postulated severe accidents in current fission reactors, vapor explosions are cons…
The static adhesion of living L1210 cells (in serum-containing medium) to the surface of (styrene/methylmethacrylate) copolymers differing in styrene content (from 5% to 50% of styrene units) was investigated. The examination of wettability of the copolymer surfaces showed that the contact angle of water on the hydrop…
Slow diffusion of cobalt chloride with Na2[Fe(CN)5NO]-5H2O in aqueous solution produced crystals of Co[Fe(CN)5NO]-5H2O suitable for analysis by three-dimensional, single-crystal X-ray diffractometry. This polynuclear transition metal cyanide crystallized in the cubic space group Fm3m (No. 225, O5 h), a = 10.28 I (2)Å,…