Materials Literature
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Activation and reaction volumes are reported for the interconversion of the 1A and 5T isomers of FeII complexes in several solvents; the reaction volume ΔV° and the activation volume ΔV15‡ are solvent-dependent but ΔV51‡ for the 5T →1A crossover is markedly negative and virtually solvent-dependent and a transition sta…
Abstract Small‐angle neutron scattering, SANS, stands forth as one of the most important of the new tools for evaluating polymer chain conformation and morphology. This paper reviews the SANS literature through 1982, with a few early 1983 references added. The theory of SANS is outlined and compared to light scatterin…
Preoxidised (OX) or prereduced (RED) TiO2(anatase) powder was exposed to N18O at 295 K in the dark. Three phenomena resulted from subsequent ultraviolet illumination: photoadsorption, photoexchange (with a much higher rate than with 18O2) and photodecomposition forming N2O and, to a lesser extent, N2. The initial rate…
We have carried out an extensive high resolution x-ray scattering study of the nematic-smectic A (N-S A) and reentrant nematic-smectic A (RN-SA) phase transition behaviour in mixtures of octyloxycyanobiphenyl (8OCB and hexyloxycyanobiphenyl (60CB). The smectic A phase boundary is found to be parabolic in the temperatu…
A method for determining the tryptophan content of feed and feedstuffs was established. This method involved three steps: alkaline hydrolysis, pretreatment of the hydrolysate for chromatography, and measurement of tryptophan by ion exchange liquid chromatography. With this method, the recovery of tryptophan in egg-whi…
Subsolidus phase equilibria in the system La 2 O 3 ‐P 2 O 5 were established. The system contains six intermediate compounds having molar La 2 O 3 :P 2 O 5 ratios of 3:1,7:3,1:1,1:2,1:3, and 1:5. It was found that the 3:1 compound has a phase transformation at 935°C. The 1:2 compound decomposes to a mixture of 1:1 and…
The collective transport of charge density waves (CDW) converts into an ordinary current at the contacts with a normal metal. In the present work this conversion is proposed to proceed via the process of phase slippage (PS). The CDW in the quasi-one-dimensional system with a nested Fermi surface and impurities is desc…
The crystal structure of the title compound, [Cu(bipy)2][PF6]2(1), has been determined by X-ray crystallographic methods, using diffractometer data collection; the structure was solved by the heavy-atom method and by successive Fourier syntheses. Compound (1) crystallises in the tetragonal space group I41/acd, a= 16.2…
More than 40 protein species including RNA polymerase were found to be phosphorylated in Escherichia coli on analyses of 32P-labeled cell lysates by single and two-dimensional gel electrophoresis and autoradiography. The protein species and the level of phosphorylation varied depending on the cell growth phase. With […
We report high resolution X-ray scattering measurements of the smectic phases and phase transitions in the material N-(4-n-butyloxy-benzylidene)-4-n-heptylaniline (40.7) (I → N → Sm A → Sm C → Sm B). For the nematic to smectic A transition we have measured the critical exponents γ = 1.45 ± 0.03, ν ∥ = 0.78 ± 0.02, and…
A selection of aliphatic alkenes, substituted styrenes, and cis-stilbene has been epoxidised with aqueous NaOCl, employing two different porphyrins, Mn(TPP)OAc and Mn(TMP)Cl, as catalysts. Large increases in reaction rate, product selectivity, and stereoselectivity are found with the bulkier TMP ligand. The results ar…
The adsorption of acridine orange by H-, Na-, Mg-, Al- and Cu-montmorillonite has been studied by visible and infrared spectroscopy and by X-ray diffraction methods. Adsorption of the dye takes place by the mechanism of cation exchange. The maximum amount of adsorbed dye depends on the exchangeable metallic cation, de…
A picosecond spectroscopic study of trans 1,1′-biindanylidene (‘‘stiff’’ stilbene) has exposed a transient absorption at 351 nm which is not an electronically excited state of the trans or cis forms. The signal strength increases with decreasing viscosity in a manner that is consistent with the decay of the excited tr…
Collective magnetic excitations are supported by multiple ferrite layers. The character of magnetostatic waves is calculated for such systems and is illustrated for three different layers variously spaced (accurate control of the delay characteristics is shown to be possible) as well as for very many similar layers eq…
Abstract Monodisperse polyacrolien (PA) microspheres were obtained by a single step process via two mechanisms: (a) aqueous polymerization of acrolein under alkaline conditions and (b) aqueous radical polymerization of acrolein by irradiation with a cobalt source. The diameter of the former microspheres can be varied…
Temperatures of the nematic → isotropic (TNI) and smectic-A → nematic (TSN) transitions in p-quaterphenyl, p-quinquephenyl and p-sexiphenyl have been determined from differential scanning calorimetry measurements carried out on the pure compounds and their binary mixtures. Both transitions are located below the meltin…
Three anhydrous forms (forms I, II, and III), dihydrate (form IV) and monoacetonate (form V) of carbamazepine were prepared and characterized by elemental analysis, infrared spectrum, X-ray powder diffraction, differential scanning calorimetry (DSC), and differential thermal analysis (DTA). The phase transition of the…
The character and occurrence of mist, hackle, and crack-branching features on ceramic fractures are reviewed and possible mechanisms for causing these features are discussed. Besides glass and polycrystalline fractures, substantial attention is paid to fractures of ceramic crystals, for which new data are presented an…
Low-density structures such as colloidal aggregates become increasingly easy to deform mechanically as their size increases. We use recently-proposed scaling properties of such aggregates to investigate the effects of thermal fluctuations and of gravitational forces on such structures. For typical colloidal aggregates…
The conducting organic salt N-methylphenazinium tetracyanoquinodimethanide can be used as an electrode for the oxidation of NADH at a sufficiently rapid rate to be a good detector in an enzyme coupled sensor.