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Mathematical methods for quantification and comparison of dissolution testing data

Edina Vranić、Aida Mehmedagić、S Hadzović2002-02-20Biomolecules and Biomedicine

In recent years, drug release/dissolution from solid dosage forms has been the subject of intense and profitable scientific developments. Whenever a new solid dosage form is developed or produced, it is necessary to ensure that drug dissolution occurs in an appropriate manner. The pharmaceutical industry and the regis…

Drug Solubulity and Delivery SystemsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Ideal glass in attractive systems with different potentials

Kenneth A. Dawson、Giuseppe Foffi、Gavin D. McCullagh 等 6 位作者2002-02-20Journal of Physics Condensed Matter

We discuss the ideal glass transition for two types of potential model of attractive colloidal systems, i.e. the square-well system and the Yukawa hard-sphere fluid. We use the framework of the ideal mode-coupling theory and we mostly focus our attention on the nature of the singularities predicted by the theory. We a…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Vibrational Analysis of Ferrocyanide Complex Ion Based on Density Functional Force Field

Sun-Kyung Park2002-02-20Bulletin of the Korean Chemical Society

Vibrational properties of ferrocyanide complex ion, <TEX>$[Fe(CN)_6]^{4-}$</TEX> , have been studied based on the force constants obtained from the density functional calculations at B3LYP/<TEX>$6-31G^{\ast\ast}$</TEX> level by means of the normal mode analysis using new bond angle and linear angle internal coordinate…

Advanced Chemical Physics StudiesCrystallography and molecular interactionsBoron and Carbon Nanomaterials Research

Energy Relaxation Dynamics of Excited Triplet States of Directly Linked Zn(II)Porphyrin Arrays

Nam Woong Song2002-02-20Bulletin of the Korean Chemical Society

The energy relaxation dynamics of the lowest excited singlet and triplet states of the Zn(II)porphyrin monomer and its directly linked arrays were comparatively investigated with increasing the number of porphyrin moieties. While the fluorescence decay rates and quantum yields of the porphyrin arrays increased with th…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Predicting Brine Mixing Deep Within the Reservoir, and the Impact on Scale Control in Marginal and Deepwater Developments

Eric Mackay、M. M. Jordan、Farshid Torabi2002-02-20OpenAlex

Abstract Sulphate scale deposition is a common problem in hydrocarbon reservoirs where injection seawater, rich in sulphate, mixes with formation brines, rich in barium, strontium and calcium. The deposition of these scales can cause significant production impairment if it occurs within zones near the production wellb…

Enhanced Oil Recovery TechniquesCalcium Carbonate Crystallization and InhibitionPetroleum Processing and Analysis

Elastic analysis of a mode II crack in a decagonal quasi-crystal

Xian‐Fang Li、Fan Tian-You2002-02-20Chinese Physics

The elastic analysis of a mode II Griffith crack penetrating through a decagonal quasi-crystal along the periodic axis is made within the context of the continuum theory. By using a general solution obtained previously, the problem in the case of uniform shear stress at infinity is solved and the analytical expression…

Aluminum Alloys Composites PropertiesHigh-Velocity Impact and Material BehaviorQuasicrystal Structures and Properties

Determination and Fate of Formic Acid in High Temperature Acid Stimulation Fluids

M. I. Al-Katheeri、H. A. Nasr‐El‐Din、Kevin C. Taylor 等 4 位作者2002-02-20OpenAlex

Abstract Formic acid is present in some corrosion inhibitors and is used as an intensifier in the acid treatment of oil and gas wells. This organic acid is important for the protection of low-carbon steels from acid corrosion at high temperatures and pressure. In this paper, the fate of formic acid used during acid tr…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsThermal and Kinetic Analysis

Magnetic ordered phase inLa0.6Sr0.4MnO3ferromagnets

Laura Steren、M. Sirena、J. Guimpel2002-02-20Physical review. B, Condensed matter

The ferromagnetic phase of ${\mathrm{La}}_{0.6}{\mathrm{Sr}}_{0.4}{\mathrm{MnO}}_{3}$ thin films has been investigated through measurements of magnetization loops at different temperatures, zero-field-cooled and field-cooled magnetization curves obtained under different magnetic fields. We have found that the main sou…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsAdvanced Condensed Matter Physics

Dynamics of supercooled liquids: density fluctuations and mode coupling theory

Emanuela Zaccarelli、Giuseppe Foffi、Paolo De Gregorio 等 6 位作者2002-02-20Journal of Physics Condensed Matter

We write equations of motion for density variables that are equivalent to Newton's equations. We then propose a set of trial equations parametrized by two unknown functions to describe the exact equations. These are chosen to best fit the exact Newtonian equations. Following established ideas, we choose to separate th…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Thermodynamics and Statistical Mechanics

Magnetic inhomogeneity and variable-range hopping transport at temperatures above the ferromagnetic transition inLa1.4Sr1.6Mn2−yTiyO7system

Hong Zhu、Xianming Liu、Keqing Ruan 等 4 位作者2002-02-20Physical review. B, Condensed matter

The magnetic and transport properties of the layered manganites ${\mathrm{La}}_{1.4}{\mathrm{Sr}}_{1.6}{\mathrm{Mn}}_{2\ensuremath{-}y}{\mathrm{Ti}}_{y}{\mathrm{O}}_{7}$ $(y&lt;~0.10)$ are investigated. For the undoped and doped samples, magnetization and electron-spin-resonance experiments exhibit coexistence of the…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Synthesis and macroscopic second-order nonlinear optical properties of poly(ether imide)s containing a novel two-dimensional carbazole chromophore with nitro acceptors

Wen‐Jang Kuo、Ging‐Ho Hsiue、Ru‐Jong Jeng2002-02-20Journal of Materials Chemistry

Taking advantage of the multifunctional characteristics of carbazole along with rational molecular design, a two-dimensional carbazole chromophore with strong nitro acceptors was synthesized by a facile synthetic route. A first molecular hyperpolarizability of 163 × 10−30 esu was acquired through solvatochromic method…

Nonlinear Optical Materials ResearchSolid-state spectroscopy and crystallographySynthesis and properties of polymers

Vibrations in glasses and Euclidean random matrix theory

T S Grigera、V Martín-Mayor、G Parisi 等 4 位作者2002-02-20Journal of Physics Condensed Matter

We study numerically and analytically a simple off-lattice model of scalar harmonic vibrations by means of Euclidean random matrix theory. Since the spectrum of this model shares the most puzzling spectral features with the high-frequency domain of glasses (non-Rayleigh broadening of the Brillouin peak, boson peak and…

Material Dynamics and PropertiesNonlinear Photonic SystemsQuantum Electrodynamics and Casimir Effect

Liquid-liquid phase transition in one-component fluids

G. Malescio、Giancarlo Franzese、Giuseppe Pellicane 等 6 位作者2002-02-20Journal of Physics Condensed Matter

The stability of a one-component model system interacting through an isotropic potential with an attractive part and a softened core is investigated through integral equations and molecular dynamics simulation. The ‘penetrability ’ of the soft core makes it possible for the system to pass from an expanded liquid struc…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Fitting the excess wing in the dielectric α-relaxation of propylene carbonate

R. Hilfer2002-02-20Journal of Physics Condensed Matter

A novel fitting function for the complex frequency-dependent dielectric susceptibility is introduced and compared against other fitting functions for experimental broadband dielectric loss spectra of propylene carbonate taken from Schneider et al (Schneider U, Lunkenheimer P, Brand R and Loidl A 1999 Phys. Rev. E 59 6…

Material Dynamics and PropertiesThermodynamic properties of mixturesSolid-state spectroscopy and crystallography

Comparative Study of Different Barite Dissolvers: Technical and Economic Aspects

István Lakatos、J. Lakatos-Szabó、B. Kosztin2002-02-20OpenAlex

Abstract An extensive research programme was launched with the aim at evaluating the potential of seven different polyamino carboxylic acids (PACAs) using both technical and economic aspects. Dissolving capacity of each compounds was determined under equilibrium conditions as a function of concentration for barite and…

Enhanced Oil Recovery TechniquesCalcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniques

Cationic Indium Alkyl Complexes Incorporating Aminotroponiminate Ligands

Fabien Delpech、Ilia A. Guzei、Richard F. Jordan2002-02-20Organometallics

The synthesis and structures of indium complexes incorporating the bidentate monoanionic ligand N, N ‘ -diisopropylaminotroponiminate ( i Pr 2 -ATI) are described. The reaction of InCl 3 with Li[ i Pr 2 -ATI] yields ( i Pr 2 -ATI)InCl 2 ( 3 ), which is converted to ( i Pr 2 -ATI)InMe 2 ( 4 ) by reaction with MeLi; 4 i…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesLanthanide and Transition Metal Complexes

Chemical Vapor Deposition of Ga2O3Thin Films on Si Substrates

Doo Hyun Kim2002-02-20Bulletin of the Korean Chemical Society

Amorphous <TEX>$Ga_2O_3$</TEX> films have been grown on Si(100) substrates by metal organic chemical vapor deposition (MOCVD) using gallium isopropoxide, <TEX>$Ga(O^iPr)_3$</TEX>, as single precursor. Deposition was carried out in the substrate temperature range 400-800 <TEX>$^{\circ}C$</TEX>. X-ray photoelectron spec…

ZnO doping and propertiesSemiconductor materials and devicesGa2O3 and related materials

Synthesis, properties and structural characterization of an intermolecular photosensitive complex: (HGly-Gly)3PMo12O40·4H2O

Zheng‐Bo Han、Enbo Wang、Guoyou Luan 等 8 位作者2002-02-20Journal of Materials Chemistry

The first heteropoly acid–dipeptide complex, (HGly-Gly)3PMo12O40·4H2O, was synthesized and characterized by elemental analysis, IR, UV, 1H NMR and single crystal X-ray diffraction. The X-ray crystallographic study showed that the crystal structure was constructed from N–H⋯O and O–H⋯O hydrogen bonds among the (HGly-Gly…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Synthesis, Structure, and Magnetic Properties of Tetranuclear Cubane-like and Chain-like Iron(II) Complexes Based on the N 4 O Pentadentate Dinucleating Ligand 1,5-Bis[(2-pyridylmethyl)amino]pentan-3-ol

J.M. Clemente-Juan、C. Mackiewicz、M. Vérelst 等 7 位作者2002-02-20Inorganic Chemistry

The tetranuclear complexes [Fe(4)(pypentO)(pym)(3)(Oac)(NCS)(3)] x 1.5EtOH (1), [Fe(4)(pypentO)(pym)(Oac)(2)(NCS)(2)(MeO)(2)(H(2)O)] x H(2)O (2), [Fe(2)(pypentO)(NCO)(3)](2) (3), and [Fe(2)(pypentO)(N(3))(3)](2) (4) have been prepared, and their structure and magnetic properties have been studied (pypentOH = 1,5-bis[(…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

CsMBi3Te6 and CsM2Bi3Te7 (M = Pb, Sn): New Thermoelectric Compounds with Low-Dimensional Structures

Kuei‐Fang Hsu、Duck Young Chung、Sangeeta Lal 等 7 位作者2002-02-20Journal of the American Chemical Society

The new materials CsPbBi(3)Te(6) and CsPb(2)Bi(3)Te(7) were discovered through reactions of CsBi(4)Te(6) with PbTe, whereas the isostructural materials CsSnBi(3)Te(6) and CsSn(2)Bi(3)Te(7) were discovered through corresponding reactions with SnTe. The compounds can also be prepared from stoichiometric mixtures of Cs(2…

Advanced Thermoelectric Materials and DevicesHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity