Gelation of an aqueous fluorinated dye solution
The gelation of aqueous solutions of sodium 1-(3,5-bistrifluoromethylphenylazo)-2-hydroxy-6-naphthalenesulfonate is investigated by means of 19F NMR spectroscopy.
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Phase behavior of poly(ε‐caprolactone)/ poly (vinylidene fluoride) blends
Abstract The miscibility of blends of poly (ε‐caprolactone) (PCL)/poly(vinylidene fluoride) (PVDF) was studied by measuring the cloud point, melting point depression and crystallization kinetics. Lower critical solution temperature (LCST) behavior was observed at PCL‐rich compositions, whilst it was not observed at hi…
Secondary-ion mass spectrometric analysis of anisotropic oxygen self-diffusion in barium hexaaluminate single crystals
Oxygen self-diffusion in a barium hexaaluminate (Ba0.75Al11O17.25) single crystal has been analysed by secondary-ion mass spectrometric analysis (SIMS) after diffusion annealing the sample in 18O2. Depth profiles of the isotopic concentration in the crystal showed that oxygen penetration normal to the c axis (⊥c) was…
Monte Carlo simulation study of crystallization in rapidly supercooled one-component plasmas
Development of solidification processes in rapidly supercooled one-component plasmas is studied by a Monte Carlo (MC) simulation method with a number of particles 1458. Evolutions of interparticle correlations and of local and extended bond-orientational orders are investigated microscopically. Layered structures emer…
Polymer dispersed liquid crystal infrared light shutter
We have developed a polymer dispersed liquid crystal (PDLC) device for operation in the midinfrared region of the electromagnetic spectrum. This device can be incorporated in thermal imaging systems that utilize pyroelectric vidicons for night vision applications. The infrared electro-optic properties of several PDLCs…
Morphology of polyethylene blends. II: Formation of a range of morphologies in blends of polyethylene with increasing content of styrene‐isoprene‐styrene triblock copolymers during extrusion‐blowing
Abstract Blends containing polyethylene (LDPE, LLDPE, or LDPE‐LLDPE) with different weight percent of styrene‐isoprene‐styrene (SIS) triblock copolymers have been obtained by extrusion‐blowing. The morphology of the blends, investigated by scanning electron microcopy (SEM), has been related to composition but also to…
The Effect of Wear and Laundering on Flame-Retardant Fabrics
Information on the time-related criteria of the degradation of protective clothing materials after wear and laundering is lacking. The materials were obtained from three sources in the evaluation of the material changes due to wear and laundering. The materials consisted of FR wool, aramid, FR viscose blend and FR cot…
Anodic Behavior of Iron in Ammoniacal Carbonate Solution: I . Steady‐State Polarization and Cyclic Voltammetry
Two distinct Tafel regions are observed in the active region of the anodic polarization curve of iron in ammoniacal carbonate solution. A prepassive layer may form in the Tafel region at the higher overpotentials. A hydrogen oxidation peak is proposed to occur in the lower overpotential Tafel region. Anodic dissolutio…
Molecular Dynamics Study of Li2SiO3in the Liquid and Glassy States
Molecular dynamics simulation (MD) has been carried out for Li2SiO3 in the molten and glassy states. The parameters of the pair potential functions were determined by a trial and error method so that the results of X-ray diffraction analysis could be well reproduced. The changes in the structure and dynamic properties…
Hydrated rare-earth-metal ion-exchanged zeolite a : characterization by luminescence spectroscopy. Part 1.—The Gd 3+ ion
The luminescence properties under high-resolution excitation and emission conditions at 4.2 K of hydrated Gd3+ion-exchanged zeolite A are reported. From these luminescence measurements it is found that in a sample containing 0.8 wt.% Gd3+, only one site appears to be occupied by Gd3+. In a freshly prepared sample cont…
High Temperature Strength of SiC-AlN Solid Solutions and Composites as Evaluated by Small Punch Tests
Fully dense compacts of SiC-AlN solid solution and composite were fabricated by the combination of reaction synthesis and hot isostatic pressing (HIP). Their strength and deformation behavior were investigated from room temperature to 1773 K by a Modified Small Punch (MSP) test which has been found to be suitable for…
Static disorder of dodecasil 3C. A single-crystal study with synchrotron radiation
A crystal of dodecasil 3C (ZSM-49, 136 SiO 2 ) was prepared and heat treated to expel the enclathrated guest species. The structure of this sample was refined [space group Fd [unk] m , a = 19.369(6) Å] to R w = 0.057 from 1068 reflections collected at 573 K with synchrotron radiation at λ = 0.593 Å. Anisotropic refine…
Properties of a semi‐crystalline and an amorphous thermotropic liquid crystalline polymer
Abstract The physical properties, thermal stability, rheology and tensile properties of a commercial semi‐crystalline and an amorphous thermotropic liquid crystalline polymer (TLCP) have been investigated. Analysis by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA) confirm the pr…
Effect of Purity on Diffusivity and Solubility of Hydrogen in Aluminum
Diffusion coefficient and solubility of hydrogen in commercial pure solid aluminum of 2N(99.7 mass%) were measured by means of the ordinary desorption method, and they were compared with those of high-purity 4N aluminum. A variety of distribution of intermetallic compound particles did not essentially influence the hy…
The structure and magnetism of a trimetallic µ-oxo ruthenium( IV ) porphyrin–iron( III ) salicylideneamine complex containing the Fe–O–Ru–O–Fe system
The redox reaction between trans-dioxotetraphenylporphyrinruthenium(VI) and two equivalents of the five-coordinate iron(II) salicylideneamine complex Fe(salmah) in toluene results in the transfer of two electrons and formation of the novel bis-µ-oxo trimetallic complex [RuIV(tpp){OFeIII(salmah)}2] containing first and…
Friction welding of shape memory alloy
(1992). Friction welding of shape memory alloy. Welding International: Vol. 6, No. 1, pp. 20-25.
Lariat ether bola-amphiphiles: formation of crown ether based bola-amphisomes
The first crown ether-based bola-amphiphiles are prepared and are shown to aggregate into a previously unknown type of niosome.
Radiation-Induced Segregation in 20Cr/25Ni/Nb Stainless Steel
Intergranular corrosion of irradiated austenitic steels has been attributed to compositional changes produced by radiation-induced segregation at grain boundaries, and the effect has been investigated for the 20Cr/25Ni/Nb stainless steel employed as fuel cladding in advanced gas-cooled reactors. Analytical electron mi…
Formation process of kaolinite from the amorphous mixture of silica and alumina
The formation process of kaolinite from the amorphous mixture of silica and alumina by hydrothermal reaction was studied by XRD, IR, DTA-TG, TEM, and high-resolution solid state 29 Si- and 27 Al-MAS/NMR. The amorphous mixture of the starting material prepared with commercially available silica-sol and alumina-sol was…
Reduction of Platinum Corrosion in Molten Glass
In order to ensure the high quality necessary for use in scientific instruments, most high-technology optical glasses are melted in platinum containers. In general, this noble metal has excellent corrosion and erosion resistance, as well as low solubility, when in contact with molten glass. Therefore the dangers of di…