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Synthesis, characterization, and ground electronic state of the unstable monomeric manganese(IV) porphyrin complexes diazido- and bis(isocyanato)(5,10,15,20-tetraphenylporphinato)manganese(IV). Crystal and molecular structure of the bis(isocyanato) complex

Mark J. Camenzind、Frederick J. Hollander、Craig L. Hill1983-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, characterization, and ground electronic state of the unstable monomeric manganese(IV) porphyrin complexes diazido- and bis(isocyanato)(5,10,15,20-tetraphenylporphinato)manganese(IV). Crystal and molecular structure of the bis(isocyanato) complexMark J. Camenzind,…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Confirmation of the Mayo mechanism for the initiation of the thermal polymerization of styrene

Yen K. Chong、Ezio Rizzardo、David H. Solomon1983-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConfirmation of the Mayo mechanism for the initiation of the thermal polymerization of styreneYen K. Chong, Ezio Rizzardo, and David H. SolomonCite this: J. Am. Chem. Soc. 1983, 105, 26, 7761–7762Publication Date (Print):December 1, 1983Publication History Published online1…

Organometallic Complex Synthesis and CatalysisCatalysis and Oxidation ReactionsMachine Learning in Materials Science

WALL MORPHOGENESIS INCOSCINODISCUS WAILESIIGRAN AND ANGST. I. VALVE MORPHOLOGY AND DEVELOPMENT OF ITS ARCHITECTURE1

Anna‐Maria M. Schmid、Benjamin E. Volcani1983-12-01Journal of Phycology

ABSTRACT The morphology of the valve of Coscinodiscus wailesii and the development of its siliceous architecture, studied in the SEM and TEM, is compared with valve formation in Thalassiosira eccentrica (Ehrenberg.) Cleve. Though the areolae‐architecture of these two species differs in such that the cribrum is proxima…

Paleontology and Stratigraphy of FossilsAlgal biology and biofuel productionDiatoms and Algae Research

Metal complex formation with 1,10-diaza-4,7,13,16-tetraoxacyclooctadecane-N,N'-diacetic acid. An approach to potential lanthanide ion selective reagents

C. Allen Chang、Michael E. Rowland1983-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal complex formation with 1,10-diaza-4,7,13,16-tetraoxacyclooctadecane-N,N'-diacetic acid. An approach to potential lanthanide ion selective reagentsC. Allen Chang and Michael E. RowlandCite this: Inorg. Chem. 1983, 22, 26, 3866–3869Publication Date (Print):December 1, 19…

Metal complexes synthesis and propertiesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Compositional variation within some glauconites and illites and implications for their stability and origins

Border Ireland、C. D. Curtis、J. A. Whiteman1983-12-01Sedimentology

ABSTRACT Textural, mineralogical and chemical data are presented for glauconites and illites from the Lower Cretaceous Glauconitic Sand Formation, Alberta, Canada. Single crystal analyses by scanning transmission electron microscopy (STEM) indicate that both glauconite (29 analyses) and illite (44 analyses) correspond…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Further Investigations of a Conversion Series of Dioctahedral Mica/Smectites in the Shinzan Hydrothermal Alteration Area, Northeast Japan

Atsuyuki Inoue、Minoru Utada1983-12-01Clays and Clay Minerals

Abstract A complete conversion series for mica/smectites was found in a hydrothermal alteration envelope around Kuroko-type ore deposits at the Shinzan area, Akita Prefecture, Northeast Japan. The minerals are an alteration product of volcanic glass of Miocene age and are commonly associated with zeolites and silica m…

Geological and Geochemical AnalysisPaleontology and Stratigraphy of FossilsClay minerals and soil interactions

Dry oxidation of silicon: A new model of growth including relaxation of stress by viscous flow

A. Fargeix、G. Ghibaudo1983-12-01Journal of Applied Physics

This paper deals with a model of silicon oxidation including stress relaxation by viscous flow during growth. Based on a Deal–Grove process and a Maxwellian stress relaxation approach, an integrodifferential equation giving the inverse growth rate dt/deox vs eox is established. Valid in any case of thickness growth ra…

Material Dynamics and PropertiesGlass properties and applicationsSilicon Nanostructures and Photoluminescence

Effects of 3' dangling end stacking on the stability of GGCC and CCGG double helixes

Susan M. Freier、Barbara J. Burger、Dirk Alkema 等 5 位作者1983-12-01Biochemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of 3' dangling end stacking on the stability of GGCC and CCGG double helixesSusan M. Freier, Barbara J. Burger, Dirk Alkema, Thomas Neilson, and Douglas H. TurnerCite this: Biochemistry 1983, 22, 26, 6198–6206Publication Date (Print):December 1, 1983Publication Histo…

Enzyme Structure and Function

Energy Principle of Elastic‐Plastic Fracture and Its Application to the Fracture Mechanics of a Polycrystalline Graphite

Mototsugu Sakai、Kazuhiro Urashima、Michio Inagaki1983-12-01Journal of the American Ceramic Society

Utilizing loading‐unloading procedures on the basis of nonlinear energy principles, an empirical method for evaluating the nonlinear fracture mechanics parameters, i.e. the nonlinear energy toughness G c , the crack growth resistance R , the J c value, and the plastic energy dissipation rate φ p , was established. The…

Fatigue and fracture mechanicsGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Channeling Radiation

J. U. Andersen、E. Bonderup、R. H. Pantell1983-12-01Annual Review of Nuclear and Particle Science

Following a major shortage of 99Mo in the 2009–2010 period, concern grew that the aging reactor production facilities needed to be replaced. Most producers were using highly enriched 235U (HEU) as the target material. The Organisation for Economic Co-...Read More

Nuclear reactor physics and engineeringGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Silicon-29 nuclear magnetic resonance study of hydroxyl sites on dehydrated silica gel surfaces, using silylation as a probe

Dean W. Sindorf、Gary E. Maciel1983-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSilicon-29 nuclear magnetic resonance study of hydroxyl sites on dehydrated silica gel surfaces, using silylation as a probeDean W. Sindorf and Gary E. MacielCite this: J. Phys. Chem. 1983, 87, 26, 5516–5521Publication Date (Print):December 1, 1983Publication History Publish…

Mesoporous Materials and Catalysis

A Pre´cis of Developments in Computational Methods for Transient Analysis

Thomas J.R. Hughes、Ted Belytschko1983-12-01Journal of Applied Mechanics

Recent developments in computational transient analysis methodology are described. Emphasis is placed on fundamental properties of some of the most widely used algorithms, the techniques used to analyze their behavior, and newer procedures that attain greater computational efficiency.

High voltage insulation and dielectric phenomena

An Analysis of Various Properties of Surface Discharge Using a Transmission-Line Model

Atsushi Kanematsu、Goro Sawa、Masayuki Ieda1983-12-01Japanese Journal of Applied Physics

A transmission-line model for surface discharge and the analytical solution of the model have been presented previously. In this paper, an attempt is made to interpret the various properties of surface discharge with this model. The properties discussed are the discharge starting voltage vs the specific capacitance; t…

High voltage insulation and dielectric phenomenaPlasma Diagnostics and ApplicationsAerosol Filtration and Electrostatic Precipitation

Physical Arrangement of High-Alumina Clay Types in a Missouri Clay Deposit and Implications for Their Genesis

Walter Keller、R. P. Stevens1983-12-01Clays and Clay Minerals

Abstract Sedimentologic zones that are differentiated by changes in lithology, mineralogy, chemical composition, and crystal morphology observable in scanning electron micrographs occur in Missouri high-alumina clay deposits. These properties and changes suggest that the high-alumina materials originated from Pennsylv…

Soil and Unsaturated FlowRecycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactions

Dielectric function for a quasi-two-dimensional semiconducting system

Johnson Lee、Harold N. Spector1983-12-01Journal of Applied Physics

We present a calculation of the dielectric function for a quasi-two-dimensional electron gas (Q2D) and compare our results with those obtained for two-dimensional (2D) and three-dimensional (3D) electron gases. We also compare our results to those obtained using the Thomas–Fermi approximation. We find that for a Q2D s…

Quantum and electron transport phenomenaSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Characteristics of a New Dosemeter Material: LiF(Mg,Cu,P)

Larry A. DeWerd、John Cameron、Dake Wu 等 5 位作者1983-12-01Radiation Protection Dosimetry

Abstract Some of the dosimetric properties of a high sensitivity thermoluminescence dosemeter material, LiF(Mg,Cu,P), are described. This material, prepared at the Chinese Academy of Medical Sciences, has about 23 times higher sensitivity than that of LiF(Mg,Ti). It is stable and reusable without significant loss of s…

Luminescence Properties of Advanced MaterialsAdvanced Radiotherapy TechniquesRadiation Detection and Scintillator Technologies

The Interpretation of Broadened Gd 3+ EPR Spectra of Polycrystalline Ceramics

H. J. A. Koopmans、M. M. A. Perik、B. Nieuwenhuijse 等 4 位作者1983-12-01physica status solidi (b)

Abstract An interpretation is given of the broadened EPR spectra of Gd 3+ ions, which are frequently observed in polycrystalline ceramics and glasses. A reasonable simulation of the spectra is obtained, when these are regarded as a superposition of a large number of normal EPR powder spectra, each of which can be desc…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Graphitizability of carbonaceous materials as studied by TEM and X‐ray diffraction

A. Oberlin、M. Oberlin1983-12-01Journal of Microscopy

SUMMARY Progressive graphitization is measured from X‐ray patterns by the probability P for finding a carbon layer pair reaching the graphite order in the solid. TEM studies show that all carbons (whether graphitizing or not) contain small basic structural units less than 10 Å both in thickness and in diameter which a…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchFiber-reinforced polymer composites

Specific-heat measurements and critical exponents of the ferroelastic phase transition inPb3(PO4)2andPb3(P1−xAsxO4)2

Ekhard K. H. Salje、B. Wruck1983-12-01Physical review. B, Condensed matter

The ferroelastic phase transitions in ${\mathrm{Pb}}_{3}$${(\mathrm{P}{\mathrm{O}}_{4})}_{2}$ and ${\mathrm{Pb}}_{3}{({\mathrm{P}}_{1\ensuremath{-}x}{\mathrm{As}}_{x}{\mathrm{O}}_{4})}_{2}$ are accompanied by large excess specific heats in a wide temperature range above ${T}_{c}$ and critical crossover above and below…

Glass properties and applicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Surface‐enhanced Raman spectra of aromatic amino acids and proteins adsorbed by silver hydrosols

Igor Nabiev、Vladimir A. Savchenko、E. S. Efremov1983-12-01Journal of Raman Spectroscopy

Abstract Surface‐enhanced Raman spectra of some amino acids (Phe, Tyr, Trp, His, Leu and Ala) and cytotoxin I from Naja naja oxiana adsorbed by silver hydrosols have been obtained. The spectra are enhanced from 100 to 200 times. Addition of aqueous solutions of the amino acids to the hydrosol resulted in the appearanc…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchProtein Interaction Studies and Fluorescence Analysis