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Dithienylcyclopentene-functionalised subphthalocyaninatoboron complexes: Photochromism, luminescence modulation and formation of self-assembled monolayers on gold

Tobias Weidner、Joe E. Baio、Johannes Seibel 等 4 位作者2011-12-03Dalton Transactions

Subphthalocyaninatoboron (SubPc) complexes bearing six peripheral n-dodecylthio substituents and an apical photochromic dithienylperfluorocyclopentene unit were prepared. The photoinduced isomerisation of the apical substituent from the open to the ring-closed form significantly influences the photoluminescence of the…

Porphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Homogeneously mixed porphyrin J-aggregates with rod-shaped nanostructuresvia zwitterionic self-assembly

Yonbon Arai、Kohei Tsuzuki、Hiroshi Segawa2011-12-03Physical Chemistry Chemical Physics

To tailor functional nanomaterials, the co-assembly of self-assembling dyes in a homogeneous way would be a promising approach because the electronic properties can be tuned by the mixing ratio. Although porphyrins are important supramolecular building blocks with unique optical properties, a homogeneously mixed J-agg…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies

Bi 2 O 3 or Bi 6 S 2 O 15 nanowires? The role of templating inorganic additives in nanomaterials formation

Ying Zhou、Greta R. Patzke2011-12-03CrystEngComm

The role of templating sulfate anions in the hydrothermal formation of nanowires from Bi2O3 and K2SO4 is critically discussed on the basis of X-ray diffraction patterns, electron microscopy studies and ion exchange experiments. Thorough analytical investigations of the obtained nanowires together with mechanistic info…

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

High performance three-dimensionally ordered macroporous composite cathodes for intermediate temperature solid oxidefuel cells

Naiqing Zhang、Juan Li、Wei Li 等 5 位作者2011-12-03RSC Advances

The colloidal crystal templating method combined with the fast firing technique is used to prepare the three-dimensionally ordered macroporous (3-DOM) composite cathodes for solid oxide fuel cells. The 3-DOM cathodes present very low polarization resistances, showing high electrocatalytic activity at intermediate temp…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Phosphate Esters Functionalized Dihydroxyl Soybean Oil Tackifier of Pressure‐Sensitive Adhesives

B. Kollbe Ahn、Jonggeun Sung、Xiuzhi Susan Sun2011-12-03Journal of the American Oil Chemists Society

Abstract Dihydroxyl soybean oil (DSO) has shown potential as a tackifier for pressure‐sensitive adhesive (PSA) applications, and perchloric acid was used previously as a catalyst to open the oxirane rings of epoxidized soybean oils (ESO) when we prepared DSO and PSA. Phosphoric acid is a more eco‐friendly catalyst tha…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingPhotopolymerization techniques and applications

Thermal properties of novel polymers based on poly(hydantoin-methyl-p-styrene) and their substrates

Halina Kaczmarek、Marta Chylińska、Marta Ziegler-Borowska2011-12-03Journal of Thermal Analysis and Calorimetry

The following compounds have been synthesized: (a) hydantoins 5,5-dimethylimidazolidine-2,4-dione (1), 1′,3′-dihydrospiro[imidazolidine-4,2′-indene]-2,5-dione (2), 3′,4′-dihydro-1′H-spiro[imidazolidine-4,2′-naphthalene]-2,5-dione (3); (b) monomers: 5,5-dimethyl-3-(4-vinylbenzyl)imidazolidine-2,4-dione (4), 1-(4-vinylb…

Synthesis and biological activitySynthesis and properties of polymersStructural and Chemical Analysis of Organic and Inorganic Compounds

Optical characterisation of silicon nanocrystals embedded in SiO2/Si3N4 hybrid matrix for third generation photovoltaics

Dawei Di、Heli Xu、Ivan Perez‐Würfl 等 5 位作者2011-12-03Nanoscale Research Letters

Silicon nanocrystals with an average size of approximately 4 nm dispersed in SiO2/Si3N4 hybrid matrix have been synthesised by magnetron sputtering followed by a high-temperature anneal. To gain understanding of the photon absorption and emission mechanisms of this material, several samples are characterised optically…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Almost compatible X-microstructures in CuAlNi shape memory alloy

S. Stupkiewicz、Anna Górzyńska-Lengiewicz2011-12-03Continuum Mechanics and Thermodynamics

A systematic study of a specific martensitic microstructure, called the X-microstructure, is carried out with the focus on the CuAlNi shape memory alloy undergoing the cubic-to-orthorhombic transformation. The set of all crystallographically distinct candidate X-microstructures is determined, and it is shown that, acc…

Shape Memory Alloy TransformationsTitanium Alloys Microstructure and PropertiesNonlocal and gradient elasticity in micro/nano structures

Effect of Silica on Uncompatibilized and Compatibilized Styrene Butadiene Rubber and Nitrile Rubber Blends

M. T. Ramesan2011-12-03International Journal of Polymeric Materials

The present paper investigates the interaction of silica filler in uncompatibilized and compatibilized styrene butadiene rubber/nitrile rubber (SBR/NBR) blends of varying compositions. The use of a dynamic mechanical analyzer as a tool for confirming the compatibility by the addition of dichlorocarbene modified styren…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Threshold stress for superplasticity in solid solution magnesium alloys

Hiroyuki Watanabe、Akira Owashi、Tokuteru Uesugi 等 5 位作者2011-12-03The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The effect of alloying elements on the threshold stress for superplasticity was investigated using two binary solid solutions, namely, Mg–Al and Mg–Y alloys. Both alloys exhibited superplasticity, and in spite of the absence of fine particles showed threshold-stress-like behavior. Different origins were suggested for…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Interfacial adsorption of cationic peptideamphiphiles: a combined study of in situspectroscopic ellipsometry and liquid AFM

Shuyi Han、Wenwen Xu、Meiwen Cao 等 8 位作者2011-12-03Soft Matter

The adsorption of cationic amphiphilic peptides, composed of six consecutive hydrophobic amino acid residues (G, A, and V) at the N-terminus and one cationic charge residue (K) at the C-terminus, at the hydrophilic silica/water interface has been investigated at pH 6.0 by in situspectroscopic ellipsometry (SE) and liq…

Lipid Membrane Structure and BehaviorSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Mn-doped ZnO nanotubes: from facile solution synthesis to room temperature ferromagnetism

Jinxia Duan、Hao Wang、Hao Wang 等 8 位作者2011-12-03CrystEngComm

Mn-doped ZnO nanotubes have been synthesized via a simple, soft solution route at 70 °C without any surfactants and templates using zinc acetate, manganese acetate and sodium hydroxide as raw materials. The nanotubes are of 1.0–2.5 μm in length, 300–500 nm in outer diameter, and 50–80 nm in wall thickness. The microst…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Crystalline Structure of Microbial Cellulose Compared with Native and Regenerated Cellulose

Ramin Khajavi、Ebrahim Jahangirian Esfahani、Morteza Sattari2011-12-03International Journal of Polymeric Materials

Microbial cellulose is a chemically pure form of plant cellulose with an ultrafine reticulated structure. In this study, microbial cellulose was biosynthesized in a static condition by acetobacter xylinium (Gluconacetobacter xylinus) of three different mono- and disaccharides, and its crystallinity structure was inves…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Dynamic Factors Controlling Targeting Nanocarriers to Vascular Endothelium

Vladimir R. Muzykantov、Ravi Radhakrishnan、David M. Eckmann2011-12-03Current Drug Metabolism

Endothelium lining the luminal surface of blood vessels is the key target and barrier for vascular drug delivery. Nanocarriers coated with antibodies or affinity peptides that bind specifically to endothelial surface determinants provide targeted delivery of therapeutic cargoes to these cells. Endothelial targeting co…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryPolymer Surface Interaction Studies

Ring-opening polymerization of cyclic esters in the presence of choline/SnOct2 catalytic system

Marcin Sobczak2011-12-03Polymer Bulletin

Low-molecular weight poly(ε-caprolactone), polylactides, and copolymers of ε-caprolactone and lactide were synthesized by ring-opening polymerization of cyclic monomers with choline (CHOL) as a initiator and SnOct 2 as a catalyst. Polymerization was conducted in bulk (120–160 °C) with high yield. Effects of temperatur…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Spectroscopic IR, EPR, and operandoDRIFT insights into surface reaction pathways of selective reduction of NO by propene over the Co–BEAzeolite

Piotr Pietrzyk、Christophe Dujardin、Kinga Góra‐Marek 等 5 位作者2011-12-03Physical Chemistry Chemical Physics

Interaction of a Co-BEA catalyst with individual components (NO, C(3)H(6), CO, O(2)) and mixtures simulating the real feed of the selective catalytic reduction (SCR) of nitric oxide in static and pulse experiments at variable temperatures was investigated by means of IR, EPR, and operando DRIFT spectroscopy coupled wi…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsAmmonia Synthesis and Nitrogen Reduction

The study of compatibility of polyethylene and polypropylene by using irradiated polyethylene wax

H. H. El‐Nahas、Yasser H. Gad、M. A. Elhady 等 4 位作者2011-12-03Radiation effects and defects in solids

The modification of the compatibility between polyethylene (PE) and polypropylene (PP) by using irradiated PE wax (PE wax) is the purpose of this study. In this part, polymer blends based on various ratios of PE and PP were blended with 2.5% PE wax in all the blend ratios to determine the optimum ratio of the blend to…

Polymer crystallization and propertiesFiber-reinforced polymer compositesTribology and Wear Analysis

The crystal structure of human UDP-glucose pyrophosphorylase reveals a latch effect that influences enzymatic activity

Quan Yu、Xiaofeng Zheng2011-12-03Biochemical Journal

UGPase (UDP-glucose pyrophosphorylase) is highly conserved among eukaryotes. UGPase reversibly catalyses the formation of UDP-glucose and is critical in carbohydrate metabolism. Previous studies have mainly focused on the UGPases from plants, fungi and parasites, and indicate that the regulatory mechanisms responsible…

Glycosylation and Glycoproteins ResearchEnzyme Structure and FunctionEnzyme Production and Characterization

In situ redox functionalization of composite electrodes for high power–high energy electrochemical storage systems via a non-covalent approach

Lénaïc Madec、Audrey Bouvrée、Philippe Blanchard 等 8 位作者2011-12-03Energy & Environmental Science

The growing demand for new global resources of clean and sustainable energy emerges as the greatest challenge in today's society. For numerous applications such as hybrid vehicles, electrochemical storage systems simultaneously require high energy and high power. For this reason, intensive researches focus on proposin…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Gas-liquid phase synthesis of highly luminescent InP/ZnS core/shell quantum dots using zinc phosphide as a new phosphorus source

Zan Feng、Jicun Ren2011-12-03Journal of Materials Chemistry

In this paper, we describe a simple and efficient approach for synthesis of highly luminescent InP/ZnS core/shell quantum dots (QDs) in gas-liquid phase reaction using zinc phosphide (Zn3P2) as a new phosphorus source and indium(III) myristate as indium precursor. The effects of experimental conditions, such as the ra…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCarbon and Quantum Dots Applications