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Synthesis, structural properties and catalytic activity of MgO-SnO2 nanocatalysts

Hina Perveen、Muhammad Akhyar Farrukh、M. Khaleeq-ur-Rahman 等 5 位作者2014-11-26Russian Journal of Physical Chemistry A

Surfactant controlled synthesis of magnesium oxide-tin oxide (MgO-SnO 2 ) nanocatalysts was carried out via the hydrothermal method. Concentration of sodium dodecyl sulfate (SDS) was varied while all other reaction conditions were kept constant same for this purpose. Furthermore, MgO-SnO 2 nanocatalysts were also prep…

Energetic Materials and CombustionElectronic and Structural Properties of OxidesMagnesium Oxide Properties and Applications

Atmospheric pressure plasma treatmentof polyamide-12 foils

Jana Hanusová、Dušan Kováčik、Monika Stupavská 等 5 位作者2014-11-26Open Chemistry

Abstract The surface of a polyamide-12 (PA-12) foil was modified in order to improve the adhesive properties by two types of atmospheric pressure plasma sources. The samples were characterized using contact angle measurement, adhesive properties measurement and X-ray photoelectron spectroscopy (XPS). The ageing of the…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsFiber-reinforced polymer composites

Rigidity transitions in glasses driven by changes in network dimensionality and structural groupings

K. Vignarooban、P. Boolchand、M. Micoulaut 等 5 位作者2014-11-26Europhysics Letters (EPL)

Calorimetric, Raman and electrical conductivity properties of alkali borates ( , Na) are studied as a function of composition and these show the presence of stiffness transitions and an intermediate phase which are driven by a combination of network dimensionality change and usual topological constraint changes. This…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Graphene magnetism induced by covalent adsorption of aromatic radicals

He Lin、Guido Fratesi、G. P. Brivio2014-11-26Physical Chemistry Chemical Physics

We report a computational study of adsorption of aromatic radicals onto graphene, with the aim of understanding the effect of covalent molecular functionalization on the magnetic and structural properties of graphene. Our results show that the adsorption of an aromatic radical like phenyl also functionalized with dono…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal Radiation and Cooling Technologies

Bimodal crystallization at polymer–fullerene interfaces

Dyfrig Môn、Anthony M. Higgins、David T. James 等 9 位作者2014-11-26Physical Chemistry Chemical Physics

The growth-kinetics of [6,6]-phenyl C61-butyric acid methyl ester (PCBM) crystals, on two different length-scales, is shown to be controlled by the thickness of the polymer layer within a PCBM-polymer bilayer. Using a model amorphous polymer we present evidence, from in situ optical microscopy and grazing-incidence X-…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsPolymer crystallization and properties

Synthesis and adhesion properties of waterborne polyurethane dispersions with long‐branched aliphatic chains

Liang Lei、Zhengbin Xia、Xiaoqiong Lin 等 5 位作者2014-11-26Journal of Applied Polymer Science

ABSTRACT In this study, a series of waterborne polyurethanes (WPUs) with different contents of long‐branched aliphatic chains were synthesized through variation of the amount of diol chain extender trimethylol propane monooleate (TMPM). The effects of the TMPM content on the adhesion properties of the WPUs were invest…

Surface Modification and SuperhydrophobicityPolymer composites and self-healingSilicone and Siloxane Chemistry

Effects Of Nano-Clay Particles And Oxidized Polypropylene Polymers On Improvement Of The Thermal Properties Of Wood Plastic Composite

Hajar Reisi Nafchi、Majid Abdouss、Saeed Kazemi Najafi 等 5 位作者2014-11-26Maderas Ciencia y tecnología

In this study, the effects of oxidized polypropylene, as a compatibilizer, and Nano-clay particles in improving the thermal properties of wood plastic composites are investigated. For this purpose, polypropylene polymer was oxidized in the vicinity of the air oxygen for 2 hours. Then, in order to produce the samples,…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFlame retardant materials and properties

Chemical Aspects of Nanoparticle Ecotoxicology

Laura Sigg、Yang Yue、Hannah Schug 等 10 位作者2014-11-26CHIMIA International Journal for Chemistry

Nanoecotoxicology strives to understand the processes and mechanisms by which engineered nanoparticles (ENP) may exert toxic effects on aquatic organisms. Detailed knowledge of the chemical reactions of nanoparticles in the media and of their interactions with organisms is required to understand these effects. The pro…

Nanoparticles: synthesis and applications

Planar {Ni6} Cluster-Containing Polyoxometalate-based Inorganic–Organic Hybrid Compound and Its Extended Structure

Xingquan Wang、Shuxia Liu、Yiwei Liu 等 8 位作者2014-11-26Inorganic Chemistry

Two {Ni6} cluster-containing inorganic-organic hybrid compounds have been successfully synthesized in the presence of organic amine under hydrothermal conditions, and they were characterized by powder and single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, and IR spectroscopy. Structural…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Nanoclusters Synthesized by Synchrotron Radiolysis in Concert with Wet Chemistry

H. Ōyanagi、Yuuichi Orimoto、Kuniko Hayakawa 等 11 位作者2014-11-26Scientific Reports

Wet chemical reduction of metal ions, a common strategy for synthesizing metal nanoparticles, strongly depends on the electric potential of the metal, and its applications to late transition metal clusters have been limited to special cases. Here, we describe copper nanoclusters grown by synchrotron radiolysis in conc…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applicationsnanoparticles nucleation surface interactions

A fluorescent probe for sensing ferric ions in bean sprouts based on l -histidine-stabilized gold nanoclusters

Yuan Su、Li Qi、Xiaoyu Mu 等 4 位作者2014-11-26Analytical Methods

Fluorescent <sc>l</sc> -histidine-stabilized Au NCs were successfully synthesized by a green one-pot process since <sc>l</sc> -histidine played dual roles as both a stabilizer and a reducing agent. Moreover, the prepared Au NCs were used as a novel fluorescent probe for selective sensing of ferric ions in bean sprouts.

Gold and Silver Nanoparticles Synthesis and ApplicationsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Expanded graphite—Phenolic resin composites based double layer microwave absorber for X-band applications

Jyoti Prasad Gogoi、Nidhi S. Bhattacharyya2014-11-26Journal of Applied Physics

In this investigation, double layer microwave absorbers are designed and developed with paired combination of 5 wt. %, 7 wt. %, 8 wt. %, and 10 wt. % expanded graphite-novolac phenolic resin (EG-NPR) composites, in the frequency range of 8.2–12.4 GHz. The thickness and compositional combination of the two layers const…

Electromagnetic wave absorption materialsAdvanced Antenna and Metasurface TechnologiesElectromagnetic Compatibility and Measurements

Magnetic Properties and Electronic Structures of Ar3UIV–L Complexes with Ar = C5(CH3)4H– or C5H5 – and L = CH3, NO, and Cl

Frédéric Gendron、Boris Le Guennic、Jochen Autschbach2014-11-26Inorganic Chemistry

Electronic structures and magnetic properties of the U(4+) complexes (C5Me4H)3UNO, (C5Me4H)3UCl, (C5H5)3UCH3, and (C5H5)3UCl are investigated by quantum chemical calculations. On the basis of wave function calculations including spin-orbit (SO) interactions, all complexes have nondegenerate nonmagnetic ground states.…

Advanced Chemical Physics StudiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Decay And Termite Resistance Of Particleboard Manufactured From Wood, Bamboo And Rice Husk

Rafael Rodolfo de Melo、Diego Martins Stangerlin、Ricardo Robinson Campomanes Santana 等 4 位作者2014-11-26Maderas Ciencia y tecnología

The resistance of particleboards, made from wood, bamboo and rice husk, to fungi and termites was evaluated. Panels were composed of 100% wood (Eucalyptus grandis), 100% bamboo (Bambusa vulgaris), 100% rice husk (Oryza sativa), 50% wood and 50% bamboo; and 50% wood and 50% rice husk. Panels exposed to the decay the br…

Engineering and Material Science Research

HfB2-SiC (10–20 vol %) ceramic materials: Manufacture and behavior under long-term exposure to dissociated air streams

V. G. Sevastyanov、Е. П. Симоненко、А. Н. Гордеев 等 9 位作者2014-11-26Russian Journal of Inorganic Chemistry

Ultra-high-temperature composite materials HfB 2 -SiC containing 10, 15, and 20 vol % SiC were prepared by spark plasma sintering. The behavior of the samples prepared under long-term exposure to subsonic dissociated airstreams of a high-frequency induction plasmatron was studied. The total test time per sample was 35…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

Persistent Detwinning of Iron-PnictideEuFe2As2Crystals by Small External Magnetic Fields

S. Zapf、C. Stingl、K. W. Post 等 14 位作者2014-11-26Physical Review Letters

Our comprehensive study on ${\mathrm{EuFe}}_{2}{\mathrm{As}}_{2}$ reveals a dramatic reduction of magnetic detwinning fields compared to other $A{\mathrm{Fe}}_{2}{\mathrm{As}}_{2}$ ($A=\mathrm{Ba}$, Sr, Ca) iron pnictides by indirect magnetoelastic coupling of the ${\mathrm{Eu}}^{2+}$ ions. We find that only $\ensurem…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Silver/Gold Core–Shell Nanoprism‐Based Plasmonic Nanoprobes for Highly Sensitive and Selective Detection of Hydrogen Sulfide

Xinjian Yang、Yuqian Ren、Zhiqiang Gao2014-11-26Chemistry - A European Journal

A simple and highly sensitive and selective hydrogen sulfide assay utilizing plasmonic nanoprobes is presented in this report. The assay employs the etching of silver in the Ag/Au core-shell nanoprisms, accompanied by surface plasmon resonance (SPR) signal depression and shift. Briefly, thin layers of gold are first c…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Conditions for requiring nonlinear thermoelectric transport theory in nanodevices

Julien Azema、P. Lombardo、A.-M. Daré2014-11-26Physical Review B

In this paper, we examine the conditions under which the nonlinear transport theory is inescapable, when a correlated quantum dot is symmetrically coupled to two leads submitted to temperature and voltage biases. By detailed numerical comparisons between nonlinear and linear currents, we show that the claimed nonlinea…

Advanced Thermoelectric Materials and DevicesAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Synthesis and characterization of biocompatibility of tenorite nanoparticles and potential property against biofilm formation

Davoodbasha MubarakAli、Jegatheesan Arunkumar、Pooja Pratheesh 等 6 位作者2014-11-26Saudi Pharmaceutical Journal

Aim is to assess the anti-biofilm property of tenorite nanoparticles and to study their suitability as a possible coating material for medical implants. Tenorite (CuO) nanoparticles were synthesized by the optimized thermal decomposition method and characterized using TEM, XRD, FTIR and UV-Vis analysis. Their influenc…

Bone Tissue Engineering MaterialsAdvanced Photocatalysis TechniquesNanoparticles: synthesis and applications