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Three-dimensional Biomimetic Technology: Novel Biorubber Creates Defined Micro- and Macro-scale Architectures in Collagen Hydrogels

Veronica Rodriguez-Rivera、John W. Weidner、Michael J. Yost2016-02-12Journal of Visualized Experiments

Tissue scaffolds play a crucial role in the tissue regeneration process. The ideal scaffold must fulfill several requirements such as having proper composition, targeted modulus, and well-defined architectural features. Biomaterials that recapitulate the intrinsic architecture of in vivo tissue are vital for studying…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

RESOURCE-SAVING TECHNOLOGY FOR HIGH-SPEED HOT EXTRUSION OF BIMETALLIC ROD PARTS

И. В. Качанов、V. N. Shary、В. В. Власов2016-02-12Science & Technique

Processes of high-speed shaping changes and especially high-speed hot extrusion create efficient conditions for treatment of weakly plastic and poorly deformable materials which are widely used in tool making facilities. Due to the fact that high-speed stamping provides accurate billets with increased mechanical prope…

Metal Alloys Wear and PropertiesEngineering and Environmental StudiesPolymer Science and Applications

The phases and morphology of CuInSe2 films prepared by different electrical deposition technologies

Kegao Liu、Hui Liu、Jing Li 等 4 位作者2016-02-12Integrated ferroelectrics

CuInSe2 as one I-III-VI ternary compound with direct band gap, has become one of the most promising photovoltaic materials due to high optical absorption coefficient and conversion efficiency. CuInSe2 films were prepared by electrodeposition with CuCl2·2H2O, InCl3, SeO2 as raw materials. The phases of product films we…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Microstructures and Magnetic Properties of Annealed Zr–Co Alloys

Gyutae Lee、Ki Woong Moon、Kwang-Won Jeon 等 4 位作者2016-02-12IEEE Transactions on Magnetics

The microstructures and magnetic properties of Zr2Co11phase prepared by a rapid solidification method and subsequent annealing at 500 °C were studied using X-ray diffraction and electron diffraction. At a wheel surface velocity of 20 m/s, both orthorhombic and rhombohedral structures were observed in as-spun ribbons.…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

In-situ solution chemical reaction deposition of Bi2S3 quantum dots on mesoscopic TiO2 films for application in quantum-dot-sensitized solar cells

Yuanliang Ma、Haiqin Li、Jing Yuan2016-02-12Integrated ferroelectrics

Bi2S3 quantum dots modified mesoscopic TiO2 films were prepared by in-situ solution chemical reaction deposition, using ethylene glycol monomethylether (EGME) and ethanol as solvent of Cationic precursor solution and anionic precursor solution respectively. UV-vis-NIR absorption spectra reveal that the Bi2S3 QDs exten…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Amylose Stereoselectively Includes Poly( d ‐alanine) to Form Inclusion Complex in Vine‐Twining Polymerization: A Novel Saccharide–Peptide Supramolecular Conjugate

Ryuya Gotanda、Kazuya Yamamoto、Jun‐ichi Kadokawa2016-02-12Macromolecular Chemistry and Physics

In this study, it is found that amylose stereoselectively includes poly(d‐alanine) in the polyalanine stereoisomers in vine‐twining polymerization to form the corresponding inclusion complex, a novel saccharide–peptide supramolecular conjugate. The vine‐twining polymerization is performed by thermostable phosphorylase…

biodegradable polymer synthesis and propertiesSupramolecular Self-Assembly in MaterialsAmino Acid Enzymes and Metabolism

Thermodynamic Models for Determination of the Solubility of Boc-(R)-3-Amino-4-(2, 4, 5-trifluorophenyl)butanoic acid in Different Pure Solvents and (Tetrahydrofuran + n-Butanol) Binary Mixtures with Temperatures from 280.15 to 330.15 K

Shimin Fan、Wenge Yang、Qirun Guo 等 7 位作者2016-02-12Journal of Chemical & Engineering Data

A gravimetric method was taken to measure the solubility of the Boc-(R)-3-amino-4-(2,4,5-trifluorophenyl)butanoic acid under atmospheric pressure in methanol, ethanol, propanol, n -butanol, ethyl acetate, and tetrahydrofuran as well as in the (tetrahydrofuran + n -butanol) mixtures from 280.15 to 330.15 K.The experime…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Structural and electronic properties of multilayer graphene on monolayer hexagonal boron nitride/nickel (111) interface system: A van der Waals density functional study

Celal Yelgel2016-02-12Journal of Applied Physics

The structural and electronic properties of multilayer graphene adsorbed on monolayer hexagonal boron nitride (h-BN)/Ni(111) interface system are investigated using the density functional theory with a recently developed non-local van der Waals density functional (rvv10). The most energetically favourable configuratio…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

Tungsten oxide nanowire synthesis from amorphous-like tungsten films

Raghunandan Seelaboyina2016-02-12Nanotechnology

A synthesis technique which can lead to direct integration of tungsten oxide nanowires onto silicon chips is essential for preparing various devices. The conversion of amorphous tungsten films deposited on silicon chips by pulsed layer deposition to nanowires by annealing is an apt method in that direction. This persp…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Synthesis and evaluation of multitopic bisbenzothiazolyl calix[4]arenes for ionic toxicants

Lakhbeer Singh Arora、Har Mohindra Chawla、Nalin Pant2016-02-12Supramolecular chemistry

Two new benzothiazolyl calix[4]arene-based multitopic molecular receptors L-1 and L-2 have been synthesised and evaluated for recognition of ionic toxicants. The receptors selectively interact with copper, silver and fluoride ion toxicants as assessed through UV-visible, NMR and colorimetric techniques. The stability…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Acquired resistance to HSP90 inhibitor 17-AAG and increased metastatic potential are associated with MUC1 expression in colon carcinoma cells

Xin Liu、Lili Ban、Gang Luo 等 12 位作者2016-02-12Anti-Cancer Drugs

Heat shock protein 90 (HSP90) is a molecular chaperone required for the stability and function of many proteins. The chaperoning of oncoproteins by HSP90 enhances the survival, growth, and invasive potential of cancer cells. HSP90 inhibitors are promising new anticancer agents, in which the benzoquinone ansamycin 17-a…

Heat shock proteins researchEnzyme Structure and FunctionATP Synthase and ATPases Research

An Optimal Burn Regime in a Controlled Tokamak Fusion Power Plant

Julio J. Martinell、Javier E. Vitela2016-02-12IEEE Transactions on Plasma Science

The optimal conditions for the burn regimes of a tokamak fusion power plant are obtained under the assumption that electron and ion temperatures can be controlled independently by means of external auxiliary heating. The study of the system is based on a volume-averaged 0-D two-temperature model in which different ope…

Magnetic confinement fusion researchLaser-Plasma Interactions and DiagnosticsFusion materials and technologies

Investigation of Ternary Phase Diagrams of (Water + Butyric Acid + Phenyl Acetate) at Different Temperatures

Kayhan Bayazıt、Hasan Uslu、Aslı Gök 等 6 位作者2016-02-12Journal of Chemical & Engineering Data

The system {(water (1) + butyric acid (2) + phenyl acetate (3)} at different temperatures, such as 298.15 K, 308.15 K, 318.15 K, and at a constant pressure (101.3 ± 0.5 kPa) in terms of liquid liquid phase equilibria were investigated. The solubility curves for each system were found. The consistency for the experimen…

Thermodynamic properties of mixturesCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Shape transformation of Ag nanospheres to triangular Ag nanoplates: Hydrogen peroxide is a magic reagent

Kai Li、Qian Wu、Yangyang Shan 等 9 位作者2016-02-12Integrated ferroelectrics

Triangular Ag nanoplates were prepared using AgNO3, PVP, NaBH4, Na3CA and H2O2 as reagents. The obtained triangular Ag NPs were characterized by transmission electron microscopy and UV-visible spectrophotometer. TEM results showed that, the edge lengths of triangular Ag NPs were in the range of 35–95 nm. The thickness…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

High-Pressure Chemistry of Graphene Oxide in the Presence of Ar, N2, and NH3

Matteo Ceppatelli、Demetrio Scelta、Giulia Tuci 等 6 位作者2016-02-12The Journal of Physical Chemistry C

The high pressure structural and reactive beahvior of graphene oxide (GO) in the presence of Ar, N 2, and NH 3 was studied in diamond anvil cells (DAC) by X-ray diffraction (XRD) and vibrational spectroscopy (FTIR and Raman), with the purpose of investigating the use of pressure for N-doping and functionalization of G…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Induced Correspondence of a Local π‐Aromatic Sextet in Heteroannulenes: Synthesis and Characterization

Abhijit Mallick、Juwon Oh、Dongho Kim 等 6 位作者2016-02-12Chemistry - A European Journal

Acid-catalyzed [3+3] condensation reactions of two hitherto unknown tripyrrane moieties with pentafluorobenzaldehyde has led to the formation of new generation heteroannulene (4.1.4.1) and mutant heteroannulene (1.1.1.1.1.1). Inclusion of local π-aromatic sextets, namely the N-methyl pyrrole rings through β,β-linkages…

Porphyrin and Phthalocyanine ChemistryFullerene Chemistry and ApplicationsSynthesis and Properties of Aromatic Compounds

Application of On-Line NIR for Process Control during the Manufacture of Sitagliptin

George Zhou、Shane T. Grosser、Lei Sun 等 11 位作者2016-02-12Organic Process Research & Development

The transamination-chemistry-based process for sitagliptin is a through-process, which challenges the crystallization of the active pharmaceutical ingredient (API) in a batch stream composed of multiple components. Risk-assessment-based design of experiment (DoE) studies of particle size distribution (PSD) and crystal…

Spectroscopy and Chemometric AnalysesAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

ELECTROLYTIC-PLASMA TREATMENT OF INNER SURFACE OF TUBULAR PRODUCTS

Yu. G. Alekseev、A. Yu. Korolyov、В. С. Нисс 等 4 位作者2016-02-12Science & Technique

While manufacturing a number of important tubular products stringent requirements have been imposed on quality of their inner surfaces. The well-known methods for inner surface treatment of pipes include sandblasting, chemical cleaning with acid reagents (oxalic, formic, sulfamic, orthophosphoric acids) and electroche…

Industrial Engineering and TechnologiesMaterial Properties and ApplicationsEngineering and Environmental Studies

The imaging properties of the metal superlens

Chen Zhao、Yun-Song Zhou、Yan Zhang 等 4 位作者2016-02-12Optics Communications

The zero-refraction property of a metal film can be used to image so that the metal film behaves as a superlens. Experimentally, the metal superlens is sandwiched between the photosensitivity resist (PR) and the dielectric spacer in the photolithograph device to produce images. In this paper, the imaging conditions of…

Metamaterials and Metasurfaces ApplicationsLiquid Crystal Research AdvancementsOptical Coatings and Gratings

Structural Insights into the Tetrameric State of Aspartate-β-semialdehyde Dehydrogenases from Fungal Species

Qinqin Li、Zhixia Mu、Rong Zhao 等 8 位作者2016-02-12Scientific Reports

Aspartate-β-semialdehyde dehydrogenase (ASADH) catalyzes the second reaction in the aspartate pathway, a pathway required for the biosynthesis of one fifth of the essential amino acids in plants and microorganisms. Microarray analysis of a fungal pathogen T. rubrum responsible for most human dermatophytoses identified…

Protein purification and stabilityEnzyme Structure and FunctionBiochemical and Molecular Research