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Controlled Surface-Assembly of Nanoscale Leaf-Type Cu-Oxide Electrocatalyst for High Activity Water Oxidation

Khurram Saleem Joya、Huub J. M. de Groot2016-02-11ACS Catalysis

The controlled surface deposition of a robust and high-performance nanostructured copper-oxide ( CuO x -NLs) electrocatalyst for water oxidation is presented. The material exhibits a characteristic leaf-type morphology and self-assembles on a copper substrate by straightforward constant-current anodization. The oxygen…

Electrocatalysts for Energy ConversionAdvanced battery technologies researchCopper-based nanomaterials and applications

Investigating the Impact of Polymer Functional Groups on the Stability and Activity of Lysozyme–Polymer Conjugates

Melissa Lucius、Rebecca Falatach、Cameron McGlone 等 10 位作者2016-02-11Biomacromolecules

Polymers are often conjugated to proteins to improve stability; however, the impact of polymer chain length and functional groups on protein structure and function is not well understood. Here we use RAFT polymerization to grow polymers of different lengths and functionality from a short acrylamide oligomer with a RAF…

Advanced Polymer Synthesis and CharacterizationProtein purification and stabilityEnzyme Structure and Function

Artificial perfect electric conductor-perfect magnetic conductor anisotropic metasurface for generating orbital angular momentum of microwave with nearly perfect conversion efficiency

Menglin L. N. Chen、Lijun Jiang、Wei E. I. Sha2016-02-11Journal of Applied Physics

Orbital angular momentum (OAM) is a promising degree of freedom for fundamental studies in electromagnetics and quantum mechanics. The unlimited state space of OAM shows a great potential to enhance channel capacities of classical and quantum communications. By exploring the Pancharatnam-Berry phase concept and engine…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsAdvanced Antenna and Metasurface Technologies

Liposomal adjuvants for human vaccines

Carl R. Alving、Zoltán Beck、Gary R. Matyas 等 4 位作者2016-02-11Expert Opinion on Drug Delivery

INTRODUCTION: Liposomes are well-known as drug carriers, and are now critical components of two of six types of adjuvants present in licensed vaccines. The liposomal vaccine adjuvant field has long been dynamic and innovative, and research in this area is further examined as new commercial products appear in parallel…

Nanoparticle-Based Drug DeliveryImmunotherapy and Immune ResponsesRNA Interference and Gene Delivery

Synthesis and Characterization of Sulfonated Carbon-Based Graphene Oxide Monolith by Solvothermal Carbonization for Esterification and Unsymmetrical Ether Formation

Akhil V. Nakhate、Ganapati D. Yadav2016-02-11ACS Sustainable Chemistry & Engineering

Herein, we report solvothermal carbonization of biomass, such as glucose, in the presence of a small amount of graphene oxide (GO) as a structure-directing agent that yields a carbon-based graphene oxide monolith (CGO monolith). The CGO monolith was functionalized with chlorosulfonic acid under mild reaction condition…

Supercapacitor Materials and FabricationZeolite Catalysis and SynthesisCatalysis for Biomass Conversion

Polymer-lipid hybrid systems: merging the benefits of polymeric and lipid-based nanocarriers to improve oral drug delivery

Shasha Rao、Clive A. Prestidge2016-02-11Expert Opinion on Drug Delivery

INTRODUCTION: A number of biobarriers limit efficient oral drug absorption; both polymer-based and lipid-based nanocarriers have demonstrated properties and delivery mechanisms to overcome these biobarriers in preclinical settings. Moreover, in order to address the multifaceted oral drug delivery challenges, polymer-l…

Nanoparticle-Based Drug DeliveryAdvancements in Transdermal Drug DeliveryAdvanced Drug Delivery Systems

Syngas Production via Reverse Water‐Gas Shift Reaction over a Ni‐Al 2 O 3 Catalyst: Catalyst Stability, Reaction Kinetics, and Modeling

Andreas Wolf、Andreas Jess、Christoph Kern2016-02-11Chemical Engineering & Technology

Abstract The synthesis of liquid fuels from CO 2 , e.g., separated from flue gases of power plants, and H 2 from renewables, i.e., water electrolysis, is a concept for substituting fossil fuels in the transport sector. It consists of two steps, syngas production via reverse water‐gas shift (RWGS) and synfuel productio…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysts for Methane Reforming

Synthesis and characterization of ZnO nanoflowers using C hlamydomonas reinhardtii: A green approach

M. Divya Rao、P. Gautam2016-02-11Environmental Progress & Sustainable Energy

Recently, there has been a lot of interest in the synthesis and application of nanoparticles with anisotropic morphologies. The focus of this study has been to use a biologically mediated, low temperature approach for the synthesis of zinc oxide nanoflowers. “Green” methods have a number of advantages over conventiona…

Solar-Powered Water Purification MethodsAdvanced Nanomaterials in CatalysisLaser-Ablation Synthesis of Nanoparticles

Demonstrating an Order-of-Magnitude Sampling Enhancement in Molecular Dynamics Simulations of Complex Protein Systems

Albert C. Pan、Thomas M. Weinreich、Stefano Piana 等 4 位作者2016-02-11Journal of Chemical Theory and Computation

Molecular dynamics (MD) simulations can describe protein motions in atomic detail, but transitions between protein conformational states sometimes take place on time scales that are infeasible or very expensive to reach by direct simulation. Enhanced sampling methods, the aim of which is to increase the sampling effic…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Enhanced Supply of Hydroxyl Species in CeO2-Modified Platinum Catalyst Studied by in Situ ATR-FTIR Spectroscopy

Yu Katayama、Takeou Okanishi、Hiroki Muroyama 等 5 位作者2016-02-11ACS Catalysis

The recent development of anion exchange membranes (AEMs) has increased the potential of anion exchange membrane fuel cells (AEMFCs). Although highly active electrocatalysts for specific reactions have been successfully developed by placing the most importance on the fuel species, only a few studies have focused on OH…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceFuel Cells and Related Materials

Gold Nanorods as Colorful Chromogenic Substrates for Semiquantitative Detection of Nucleic Acids, Proteins, and Small Molecules with the Naked Eye

Xiaoming Ma、Zhitao Chen、Palanisamy Kannan 等 6 位作者2016-02-11Analytical Chemistry

Herein, we report for the first time a colorful chromogenic substrate, which displays vivid color responses in the presence of different concentration of analytes. Our investigation reveals that the selective shortening of gold nanorods (AuNRs) could generate a series of distinct colors that covers nearly the whole vi…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesBiosensors and Analytical Detection

Recent Progress on the Design and Applications of Polysaccharide‐Based Graft Copolymer Hydrogels as Adsorbents for Wastewater Purification

Hemant Mittal、Suprakas Sinha Ray、Masami Okamoto2016-02-11Macromolecular Materials and Engineering

Gum polysaccharides are one of the most abundant bio‐based polymers. They are generally derived from plants as exudates or from microorganisms and have diverse applications in many industries, especially in the food industries where they are used as emulsifiers and thickeners. In their natural form, gum polysaccharide…

Hydrogels: synthesis, properties, applicationsAdvanced Cellulose Research StudiesPolysaccharides Composition and Applications

Study of tribological properties on Al/Al 2 O 3 /MoS 2 hybrid composite processed by powder metallurgy

K. Kanthavel、K. R. Sumesh、P.T. Saravanakumar2016-02-11Alexandria Engineering Journal

Aluminium ceramic composites with improved mechanical and chemical properties are essential and needed in aerospace and automotive application. The aluminium matrix composite reinforced with ceramic material of alumina (Al 2 O 3 ) has good tribological properties. However, aluminium based ceramic composites require im…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Self-induced synthesis of phase-junction TiO2 with a tailored rutile to anatase ratio below phase transition temperature

Weikang Wang、Jie‐Jie Chen、Xing Zhang 等 6 位作者2016-02-11Scientific Reports

The surface phase junction of nanocrystalline TiO2 plays an essential role in governing its photocatalytic activity. Thus, facile and simple methods for preparing phase-junction TiO2 photocatalysts are highly desired. In this work, we show that phase-junction TiO2 is directly synthesized from Ti foil by using a simple…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

Localised corrosion in AA 2099-T83 aluminium-lithium alloy: The role of grain orientation

Yan Ma、Xiaorong Zhou、Yi Liao 等 7 位作者2016-02-11Corrosion Science

The mechanism for localised corrosion in AA 2099-T83 alloy during immersion in 3.5% NaCl solution is investigated. It is found that localised corrosion tends to occur in the grain with relatively large Schmid factor. The localised corrosion is related to selective dissolution of T1 (Al2CuLi) phase that preferentially…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Distance-Dependent Plasmon-Enhanced Singlet Oxygen Production and Emission for Bacterial Inactivation

Oriol Planas、Nicolás Macía、Montserrat Agut 等 5 位作者2016-02-11Journal of the American Chemical Society

Herein, we synthesized a series of 10 core-shell silver-silica nanoparticles with a photosensitizer, Rose Bengal, tethered to their surface. Each nanoparticle possesses an identical silver core of about 67 nm, but presents a different silica shell thickness ranging from 5 to 100 nm. These hybrid plasmonic nanoparticle…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesAdvanced Nanomaterials in Catalysis

Mechanisms of fatigue crack growth – a critical digest of theoretical developments

Piyas Chowdhury、Hüseyin Şehitoğlu2016-02-11Fatigue & Fracture of Engineering Materials & Structures

ABSTRACT Recent advances in the processing technology are permitting the manufacture of novel metallic materials with superior fatigue properties via microstructure tailoring. In the light of these promising developments, there is a rising need for establishing a synergy between state‐of‐the‐art experimental character…

Fatigue and fracture mechanicsHigh-Velocity Impact and Material BehaviorFire effects on concrete materials

Inorganic nanoparticles for optical bioimaging

Daniel Jaque、Cyrille Richard、Bruno Viana 等 6 位作者2016-02-11Advances in Optics and Photonics

The tremendous progress in the synthesis of different inorganic nanoparticles with pretailored size, shape, structural, compositional, and surface properties has significantly raised their potential applications in biomedicine. Optically active inorganic nanoparticles are those that, based on inorganic materials, can…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Current Challenges and Prospective Research for Upscaling Hybrid Perovskite Photovoltaics

Spencer T. Williams、Adharsh Rajagopal、Chu‐Chen Chueh 等 4 位作者2016-02-11The Journal of Physical Chemistry Letters

Organic-inorganic hybrid perovskite photovoltaics (PSCs) are poised to push toward technology translation, but significant challenges complicating commercialization remain. Though J-V hysteresis and ecotoxicity are uniquely imposing issues at scale, CH3NH3PbI3 degradation is by far the sharpest limitation to the techn…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations

Teng Zhang、Kuntal Manna、Wenbin Lin2016-02-11Journal of the American Chemical Society

New and active earth-abundant metal catalysts are critically needed to replace precious metal-based catalysts for sustainable production of commodity and fine chemicals. We report here the design of highly robust, active, and reusable cobalt-bipyridine- and cobalt-phenanthroline-based metal-organic framework (MOF) cat…

Metal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications