Materials Literature
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Nano- and microcrystalline diamond deposition on pretreated WC–Co substrates: structural properties and adhesion, Fraga, M A, Contin, A, Rodríguez, L A A, Vieira, J, Campos, R A, Corat, E J, Airoldi, V J Trava
Electrodes, one of the key components of organic field‐effect transistors (OFETs), exert great influence on the device performance as well as circuit fabrication. Conventional metal electrodes generally show poor contact quality with organic semiconductors, especially in bottom‐contact geometry. Development of appropr…
Epoxy resins were modified with 10-(2,5-dihydroxyl phenyl)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and 1,1′-(methylenedi-4,1-phenylene) bismaleimide (BDM). The resulting blends were then cured with 4, 4′-diaminodiphenyl sulfone. Thermal properties of the cured epoxy resins were investigated by differential…
The flame retardancy and mechanical properties of polyamide‐6 (PA6)/aluminum diethylphosphinate (AlPi) composite are greatly improved by the addition of novelly synthesized phosphorus flame retardant‐based diepoxide (DEP) during extrusion. The PA6/AlPi/DEP composite passes V‐0 rating of UL94 test with limiting oxygen…
We report the direct observation of polarization resolved electronic Raman scattering in a gated monolayer graphene device. The evolution of the electronic Raman scattering spectra with gate voltage and its polarization dependence are in full agreement with theoretical expectations for nonresonant Raman processes invo…
Two-dimensional (2D) π-conjugated microporous polymers recently attracted tremendous interest due to their unique structural and electronic properties compared with 1D polymers and also graphene. In this paper, we present a comprehensive electronic structure investigation of several representative 2D conjugated polyme…
We present a simple solution‐based general approach for the preparation of flexible, transparent, and conducting composite films with molecular level dispersion of individual graphene nanosheets in the polymer [poly( N ‐hydroxymethyl) acrylamide] hosts via in situ polymerization. The graphene oxide (GO) concentration…
Thermally responsive polymers present an interesting avenue for tuning the optical properties of nanomaterials on their surfaces by varying their periodicity and shape using facile processing methods. Gold bowtie nanoantenna arrays are fabricated using nanosphere lithography on prestressed polyolefin (PO), a thermopla…
Two different physical processes, (i) fast grain-boundary diffusion (FGBD) of oxygen and (ii) hindered oxygen diffusion in a surface space-charge layer, yield oxygen isotope diffusion profiles in a similar form. Two features are observed, with the short, sharp profile close to the surface being followed by a longer, s…
In the current study, the influence of delta (δ) ferrite on the corrosion susceptibility of AISI 304 austenitic stainless steel was evaluated in 1Molar concentration of sulphuric acid (H2SO4) and 1Molar concentration of sodium chloride (NaCl). The study was performed at ambient temperature using electrochemical techni…
A facile one-pot synthesis method has been developed successfully for the preparation of crystalline silver selenide (Ag2Se) nanoparticles at low temperatures (5–7 °C) within few minutes. The method is based on the formation of phase separation and interface-reaction mechanism. During the synthesis, a microemulsion sy…
We report, herein, the results of an in depth study and concomitant analysis of the AC conduction [σ'(ω): f=20 Hz to 2 MHz] mechanism in a reduced graphene oxide-zinc sulfide (RGO-ZnS) composite. The magnitude of the real part of the complex impedance decreases with increase in both frequency and temperature, whereas…
We present a method for the determination of the average number of polymer molecules on the surface of A(II)B(VI) luminescent core-shell nanocrystals (CdSe/ZnS, ZnSe/ZnS quantum dots, and CdS/ZnS nanorods) encapsulated with amphiphilic polymer. Poly(maleic anhydride-alt-1-tetradecene) (PMAT) was quantitatively labeled…
Abstract Thermal transport properties in hybridised graphene and boron nitride ribbons (HGBNRs) under different strains are studied by using reverse nonequilibrium molecular dynamics simulations. It is found that the effect of strains on the thermal conductivity is different for different types of strains. When the te…
A halogen-free flame retardant of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-containing H-benzimidazole (DHBI) was synthesized and subsequently used as co-curing agent of 4,4′-diamino-diphenylmethane for diglycidyl ether of bisphenol-A. The structure of DHBI was characterized by Fourier transform infrared (FTI…
On the basis of the modified couple stress theory, some analytical results are obtained for vibrational parameters of micro-spinning Rayleigh beams with an axial mass-eccentricity distribution. The modified couple stress theory is a nonclassical continuum theory capable to capture the size effects in small-scale struc…
In this study, water-repellent, oil-repellent and flame-retardant cotton fabrics were developed by solgel technique. With this aim, nanosols were prepared using tetraethylorthosilicate and hexadecyltrimethoxysilane as precursors, guanidine dihydrogen phosphate as flame-retardant agent and Guard AFB as conventional wat…
Due to the particular activation and inhibition behavior of silver nanoparticles (AgNPs) on microbes at various concentrations, it's crucial to exploit the special concentration effect in environment. Here, we studied the viability variation of Phanerochaete chrysosporium (P. chrysosporium) under exposure to citrate-c…
Three new hybrid ionic liquids (ILs) based on cage silsesquioxane (SQ) were rapidly prepared in high yields from octa(mercaptopropyl)silsesquioxane and 1-allyl-3-methylimidazolium salts (Br(-), BF4(-), PF6(-)) through the photochemical thiol-ene reaction. These SQ-based ILs exhibited low glass transition temperatures…
A series of nanostructured co-doped Co(1-x-y)Ni(x)Fe(y)Sb3 were fabricated using a rapid hydrothermal method at 170 °C for a duration of 12 h, followed by evacuated-and-encapsulated heating at 580 °C for a short period of 5 h. The resulting samples were characterized using powder X-ray diffraction, field emission scan…