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PREPARATION AND CHARACTERIZATION OF BROMINATED NATURAL RUBBER APPLIED IN SILICA-FILLED NATURAL RUBBER VULCANIZATES

Nuchanart Onchoy、Pranee Phinyocheep2016-02-09Rubber Chemistry and Technology

ABSTRACT Functionalization of NR with a bromine atom was developed and explored for its application in a silica-reinforced NR system. Two possible pathways were investigated: the direct addition of a bromine atom using N-bromosuccinimide (NBS) with FeCl2 as a catalyst in the latex phase (NR–Br); and an indirect method…

Catalytic Alkyne ReactionsPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods

Critical regime for the insulator–metal transition in highly ordered conjugated polymers gated with ionic liquid

Hiroshi Ito、Tomonori Harada、Hisaaki Tanaka 等 4 位作者2016-02-09Japanese Journal of Applied Physics

Abstract We report the room-temperature and low-temperature transport properties of a poly(2,5-bis(3-hexadecylthiophene-2-yl)thieno[3,2-b]thiophene) (PBTTT) film gated with an ionic liquid based on 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide at different annealing temperatures of the PBTTT film. By…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications

Improvement of thermal stability of p‐type ZnO:(Al,N) fabricated by oxidizing Zn3N2:Al thin films

Yuefei Wang、Dongyu Song、Li Li 等 6 位作者2016-02-09Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract The authors report the fabrication of p‐type ZnO thin films with improved thermal stability. The p‐type ZnO thin films were obtained by oxidizing Zn3N2:Al thin films in an oxygen ambient. Both Zn3N2:Al and Zn3N2 thin films were deposited on fused silica substrates at 100 °C by megnetron sputtering. X‐ray diff…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

A Critical Approach to the Biocompatibility Testing of Niti Orthodontic Archwires

B. Uzer、B. Gumus、SM Toker 等 8 位作者2016-02-09International Journal of Metallurgy and Metal Physics

The biocompatibility of Nickel-Titanium (NiTi) archwires was investigated by simulating actual contact state of archwires around brackets, which enabled incorporation of realistic mechanical conditions into ex situ experiments. Specifically, archwires (undeformed, and bound to brackets on acrylic dental molds) were st…

Corrosion Behavior and InhibitionShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Magnetic and Thermal Properties of TmV2Al20 Single Crystals

Qiankun Lei、Takahiro Namiki、Yosikazu Isikawa 等 5 位作者2016-02-09Journal of the Physical Society of Japan

The magnetization and specific heat of TmV 2 Al 20 single crystals were measured in the temperature range from 0.5 to 300 K in external magnetic fields up to 7 T. TmV 2 Al 20 was found to be paramagnetic above 0.5 K. Clear magnetic anisotropy was observed along the three principal crystallographic axes in the field ab…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

A taxonomic synopsis of South American Cyanogomphini Carle with description of Cyanogomphus angelomachadoi sp. nov. from the Cerrado of Brazil (Odonata: Gomphidae)

Ângelo Parise Pinto、Marcus Vinicius Oliveira Almeida2016-02-09Zootaxa

A synopsis of Cyanogomphini Carle, 1986 (sensu Belle 1996), including all species currently under the genera Cyanogomphus Selys, 1873, and Tibiagomphus Belle, 1992, is provided. Cyanogomphus angelomachadoi sp. nov. (Holotype ♂ deposited in DZRJ: Brazil, Minas Gerais State, Jaboticatubas municipality, Parque Nacional d…

Freshwater macroinvertebrate diversity and ecologyRemote Sensing and LiDAR ApplicationsDiatoms and Algae Research

Electrochromism in sputter deposited W1-yMoyO3thin films

Miguel A. Arvizu、C.G. Granqvist、Gunnar A. Niklasson2016-02-09Journal of Physics Conference Series

Electrochromic (EC) properties of tungsten-molybdenum oxide (W 1-y Mo y O 3 ) thin films were investigated. The films were deposited on indium tin oxide covered glass by reactive DC sputtering from tungsten and molybdenum targets. Elemental compositions of the W 1-y Mo y O 3 films were determined by Rutherford back sc…

Gas Sensing Nanomaterials and SensorsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Surfactant-induced core/shell phase equilibrium in hydrogels

Jonas Gernandt、Per Hansson2016-02-09The Journal of Chemical Physics

The formation of core/shell structures in hydrogels upon interaction with surfactants is a well-known phenomenon, but whether they are equilibrium states or not is still under debate. This paper presents an equilibrium theory of phase coexistence in hydrogels meant to answer the question of the stability of core/shell…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Crystal structure of poly[octaaqua-tris(benzene-1,2,4,5-tetracarboxylato)tetralanthanum(III)] hexahydrate, C30H34La4O38

Wentao Qiao、Dan Zhao、Fa‐Xue Ma2016-02-09Zeitschrift für Kristallographie - New Crystal Structures

Abstract C30H34La4O38, triclinic, P1̅ (no. 2), a = 9.2405(1) Å, b = 10.6952(1) Å, c = 10.8307(1) Å, α = 86.239(1)°, β = 84.014(1)°, γ = 81.367(1)°, V = 1051.13(2) Å3, Z = 1, R gt (F) = 0.033, wR ref (F 2 ) = 0.072, T = 296 (2) K.

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesPolyoxometalates: Synthesis and Applications

Non-isothermal curing kinetics, chemorheological behaviour, and IR spectral study of two trifunctional phenylethynyl-terminated imide oligomers compared with the corresponding bifunctional structure

Changwei Liu、Chunyan Qu、Chengyang Wang 等 9 位作者2016-02-09Progress in Reaction Kinetics and Mechanism

Two trifunctional phenylethynyl-terminated imide oligomers, m-TPEPA and p-TPEPA, were systematically compared with the corresponding bifunctional phenylethynyl-terminated imide oligomer, BPEPA. The non-isothermal curing kinetics, Master Plots method, and rheological behaviour of the three high performance oligomers we…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersThermal and Kinetic Analysis

Larva of Palaemnema brasiliensis Machado (Odonata: Platystictidae), from Amazonas, Brazil

Ulisses Gaspar Neiss、Neusa Hamada2016-02-09Zootaxa

The larva of Palaemnema brasiliensis Machado, 2009 is described and illustrated based on last-instar larvae and exuviae of reared larvae collected in a blackwater stream in Barcelos and Presidente Figueiredo municipalities, Amazonas state, Brazil. The larva of P. brasiliensis can be distinguished from the two South Am…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Experimental analysis and WallDYN simulations of the global nitrogen migration in ASDEX Upgrade L-mode discharges

G. Meisl、K. Schmid、M. Oberkofler 等 8 位作者2016-02-09Nuclear Fusion

Abstract This work presents ASDEX Upgrade experiments, where the nitrogen deposition and re-erosion on divertor manipulator samples and the effect of its transport through the plasma were studied. These results are compared to WallDYN-DIVIMP simulations based on SOLPS plasma backgrounds and employing an improved WallD…

Magnetic confinement fusion researchLaser-Plasma Interactions and DiagnosticsFusion materials and technologies

Alpha heating and isotopic mass effects in JET plasmas with sawteeth

R. Budny2016-02-09Nuclear Fusion

Abstract The alpha heating experiment in the Joint European Torus (JET) 1997 DTE1 campaign is re-examined. Several effects correlated with tritium content and thermal hydrogenic isotopic mass < A > weaken the conclusion that alpha heating was clearly observed. These effects delayed the occurrence of significant sawtoo…

Magnetic confinement fusion researchFusion materials and technologiesPlasma Diagnostics and Applications

In situ detection of the Zn 2+ release process of ZnO NPs in tumour cells by confocal laser scanning fluorescence microscopy

Wenshuang Song、Xiaoling Tang、Yong Li 等 6 位作者2016-02-09IET Nanobiotechnology

The use of zinc oxide (ZnO) nanoparticles (NPs) for cancer is not yet clear for human clinical applications, which is primarily due to the lack of a better understanding of the action mechanisms and cellular consequences of the direct exposure of cells to these NPs. In this work, the authors have selected zinquin ethy…

Quantum Dots Synthesis And PropertiesNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

DNA binding and cleavage properties of the Ce (III) complex of a diaza-crown ether

Fangzhen Li、Fa-mei Feng、Jiaoyi Wu 等 5 位作者2016-02-09Progress in Reaction Kinetics and Mechanism

The hydrolytic cleavage of pUC19 DNA as promoted by the trivalent cerium complex (CeL) of diaza-crown ether ligand L (1,4,10,13-tetraoxa-7,16-diazacyclooctadecane) was examined in detail. The interaction of CeL with calf thymus DNA was investigated by UV-Vis spectroscopy. Furthermore, studies on the effects of pH, rea…

Metal complexes synthesis and propertiesDNA and Nucleic Acid ChemistryLanthanide and Transition Metal Complexes

Production and Photodissociation of the Methyl Perthiyl Radical

Neil C. Cole-Filipiak、Mark Shapero、Courtney Haibach-Morris 等 4 位作者2016-02-09The Journal of Physical Chemistry A

The photodissociation dynamics of the methyl perthiyl (CH3SS) radical are investigated via molecular beam photofragment translational spectroscopy, using "soft" electron ionization to detect the radicals and their photofragments. With this new capability, we have shown that CH3SS can be generated from flash pyrolysis…

Radical Photochemical ReactionsPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Assessment of drug content uniformity of atropine sulfate triturate by liquid chromatography–tandem mass spectrometry, X-ray powder diffraction, and Raman chemical imaging

K. Moriyama、Yoichiro Takami、Natsuki Uozumi 等 10 位作者2016-02-09Journal of Pharmaceutical Health Care and Sciences

BACKGROUND: Atropine sulfate is an anticholinergic agent for treatment of hypertrophic pyloric stenosis and is orally administrated as a triturate with lactose hydrate. Because of the low safety margin of atropine sulfate, triturate uniformity is a key safety factor. In this study, we assessed the uniformity of atropi…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyX-ray Diffraction in Crystallography

Temperature‐Sensitive (BA)(AC)2 Miktoarm Star Diblock Copolymer Based on PMMA, PPEGMA, and PNIPAm

Jie Zhu、Yuyang Liu、Liqun Xiao 等 4 位作者2016-02-09Macromolecular Chemistry and Physics

A well‐defined (BA)(AC)2 miktoarm star diblock copolymer, (PPEGMA32‐b‐PMMA41)‐b‐(PMMA45‐b‐PNIPAm19)2, is synthesized by the combination of ATRP and click reaction. The miktoarm star block copolymer and its precursors are characterized by means of NMR and SEC/MALLS measurements. The copolymer exhibits a low critical ag…

Advanced Polymer Synthesis and CharacterizationSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Properties of SnS thin films grown by physical vapour deposition

M. Ganchev、P. Vitanov、M. Sendova-Vassileva 等 5 位作者2016-02-09Journal of Physics Conference Series

Thin films of tin sulfide (SnS) were prepared by thermal evaporation technique on glass substrates and on n-type Si substrate and their physical properties were studied. The phase of the obtained thin films before and after thermal treatment was confirmed by X-ray diffraction analysis and Raman spectra. Optical transm…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsSemiconductor materials and interfaces

Influence of magnet shaping on cogging torque of surface‐mounted PM machines

Samad Taghipour Boroujeni、Vahid Zamani2016-02-09International Journal of Numerical Modelling Electronic Networks Devices and Fields

Summary In the presented work, influence of magnet shaping on cogging torque of surface‐mounted Permanent Magnet (PM) machines is investigated. The considered PM shape for the magnet shaping is the loaf‐shape PM with off‐set arcs. For the first time, based on the solution of the Poissons's equation, an analytical mode…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Bearings and Levitation Dynamics