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Calibrating the X-ray attenuation of liquid water and correcting sample movement artefacts duringin operandosynchrotron X-ray radiographic imaging of polymer electrolyte membrane fuel cells

Nan Ge、Stéphane Chevalier、James Hinebaugh 等 9 位作者2016-02-09Journal of Synchrotron Radiation

Synchrotron X-ray radiography, due to its high temporal and spatial resolutions, provides a valuable means for understanding the in operando water transport behaviour in polymer electrolyte membrane fuel cells. The purpose of this study is to address the specific artefact of imaging sample movement, which poses a sign…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsMachine Learning in Materials Science

Gap plasmonics of silver nanocube dimers

Dario Knebl、Anton Hörl、Andreas Trügler 等 7 位作者2016-02-09Physical review. B./Physical review. B

We theoretically investigate gap plasmons for two silver nanocubes coupled through a molecular tunnel junction. In the absence of tunneling, the redshift of the bonding mode saturates with decreasing gap distance. Tunneling at small gap distances leads to a damping and slight blueshift of the bonding mode, but no low-…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchMolecular Junctions and Nanostructures

Identification of imine reductase‐specific sequence motifs

Silvia Fademrecht、Philipp N. Scheller、Bettina M. Nestl 等 5 位作者2016-02-09Proteins Structure Function and Bioinformatics

Chiral amines are valuable building blocks for the production of a variety of pharmaceuticals, agrochemicals and other specialty chemicals. Only recently, imine reductases (IREDs) were discovered which catalyze the stereoselective reduction of imines to chiral amines. Although several IREDs were biochemically characte…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionBiochemical and Molecular Research

Plasmonic nanostructures for organic photovoltaic devices

Sungmo Ahn、Devin M. Rourke、Wounjhang Park2016-02-09Journal of Optics

Due to the increasing demand on high-efficiency organic photovoltaic (OPV) devices, light management technique has become an active research subject. Especially, plasmonic approach was proven to be suitable for application in OPV and has shown lots of successful results. In this review, we summarize recent studies on…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Plasmonic surface lattice resonances in arrays of metallic nanoparticle dimers

Alastair D. Humphrey、William L. Barnes2016-02-09Journal of Optics

We investigate the optical response of square arrays of metallic nanoparticles where each lattice site is occupied by two particles, a dimer. In particular we examine the surface lattice resonances arising in these structures when the in-plane dipole moments associated with the plasmon modes of the nanoparticles coupl…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

PCDTBT based solar cells: one year of operation under real-world conditions

Yiwei Zhang、Edward Bovill、James Kingsley 等 8 位作者2016-02-09Scientific Reports

We present measurements of the outdoor stability of PCDTBT:PC71BM based bulk heterojunction organic solar cells for over the course of a year. We find that the devices undergo a burn-in process lasting 450 hours followed by a TS80 lifetime of up to 6200 hours. We conclude that in the most stable devices, the observed…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

Temperature Dependence of NMR Parameters Calculated from Path Integral Molecular Dynamics Simulations

Martin Dračínský、Petr Bouř、Paul Hodgkinson2016-02-09Journal of Chemical Theory and Computation

The influence of temperature on NMR chemical shifts and quadrupolar couplings in model molecular organic solids is explored using path integral molecular dynamics (PIMD) and density functional theory (DFT) calculations of shielding and electric field gradient (EFG) tensors. An approach based on convoluting calculated…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyQuantum, superfluid, helium dynamics

A literature survey on asset management in electrical power [transmission and distribution] system

Swasti R. Khuntia、José L. Rueda、S. Bouwman 等 4 位作者2016-02-09International Transactions on Electrical Energy Systems

Asset management is one of the key components in a transforming electric power industry. Electric power industry is undergoing significant changes because of technical, socio-economical and environmental developments. Also, because of restructuring and deregulation, the focus has been on transmission and distribution…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationPower System Reliability and Maintenance

Xylan decoration patterns and the plant secondary cell wall molecular architecture

Marta Busse‐Wicher、Nicholas J. Grantham、Jan J. Łyczakowski 等 5 位作者2016-02-09Biochemical Society Transactions

The molecular architecture of plant secondary cell walls is still not resolved. There are several proposed structures for cellulose fibrils, the main component of plant cell walls and the conformation of other molecules is even less well known. Glucuronic acid (GlcA) substitution of xylan (GUX) enzymes, in CAZy family…

Advanced Cellulose Research StudiesPolysaccharides and Plant Cell WallsPolysaccharides Composition and Applications

Integrated foam fractionation for heterologous rhamnolipid production with recombinant Pseudomonas putida in a bioreactor

Janina Beuker、Anke Steier、Andreas Wittgens 等 6 位作者2016-02-09AMB Express

Heterologeous production of rhamnolipids in Pseudomonas putida is characterized by advantages of a non-pathogenic host and avoidance of the native quorum sensing regulation in Pseudomonas aeruginosa. Yet, downstream processing is a major problem in rhamnolipid production and increases in complexity at low rhamnolipid…

Microbial bioremediation and biosurfactantsMicroplastics and Plastic PollutionPickering emulsions and particle stabilization

High‐Performance Flexible Multilayer MoS2 Transistors on Solution‐Based Polyimide Substrates

Won Geun Song、Hyuk‐Jun Kwon、Jozeph Park 等 11 位作者2016-02-09Advanced Functional Materials

Transition metal dichalcogenides (TMDs) layers of molecular thickness, in particular molybdenum disulfide (MoS2), become increasingly important as active elements for mechanically flexible/stretchable electronics owing to their relatively high carrier mobility, wide bandgap, and mechanical flexibility. Although the su…

2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Theoretical study on rotary-sliding disk triboelectric nanogenerators in contact and non-contact modes

Tao Jiang、Xiangyu Chen、Keda Yang 等 6 位作者2016-02-09Nano Research

The triboelectric nanogenerator (TENG) has emerged as a new and effective mechanical energy harvesting technology. In this work, a theoretical model for a rotary-sliding disk TENG with grating structure was constructed, including the dielectric-to-dielectric and conductor-to-dielectric cases. The finite element method…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsInnovative Energy Harvesting Technologies

CASP 11 statistics and the prediction center evaluation system

Andriy Kryshtafovych、Bohdan Monastyrskyy、Krzysztof Fidelis2016-02-09Proteins Structure Function and Bioinformatics

We outline the role of the Protein Structure Prediction Center (predictioncenter.org) in conducting the CASP11 and CASP ROLL experiments, discuss the experiment statistics, and provide an overview of the present CASP infrastructure. The biggest changes compared to the previous CASPs are the implementation of the evalu…

Protein Structure and DynamicsAdvanced Proteomics Techniques and ApplicationsEnzyme Structure and Function

Flash melting of tantalum in a diamond cell to 85 GPa

Amol Karandikar、R. Boehler2016-02-09Physical review. B./Physical review. B

We demonstrate a new level of precision in measuring melting temperatures at high pressure using laser flash heating in a diamond cell followed by an analysis using scanning electron microscopy and focused ion beam milling. The new measurements on tantalum put unprecedented constraints on its highly debated melting sl…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Graphene Nanosheets Suppress the Growth of Sb Nanoparticles in an Sb/C Nanocomposite to Achieve Fast Na Storage

Hong‐Yan Lü、Fang Wan、Li‐Hua Jiang 等 5 位作者2016-02-09Particle & Particle Systems Characterization

Presently, graphene incorporation is one of the most effective strategies to develop superior electrode materials for sodium‐ion batteries (SIBs). Herein, it is excitingly found that an incorporated graphene nanosheet in the preparation processes can not only completely protect all the Sb nanoparticles in an Sb/C comp…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Ionic Liquid Activation of Amorphous Metal‐Oxide Semiconductors for Flexible Transparent Electronic Devices

Pushpa Raj Pudasaini、Joo Hyon Noh、Anthony T. Wong 等 9 位作者2016-02-09Advanced Functional Materials

Amorphous metal‐oxide semiconductors offer the high carrier mobilities and excellent large‐area uniformity required for high performance, transparent, flexible electronic devices; however, a critical bottleneck to their widespread implementation is the need to activate these materials at high temperatures which are no…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs)

Minghui Zhang、Liangliang Zhang、Zhenyu Xiao 等 7 位作者2016-02-09Scientific Reports

The assembly of a fluorescent pentiptycene-based ligand with copper ion resulted in the formation of a 3D porous metal-organic framework (UPC-21) based on well-known paddlewheel SBUs. UPC-21 exhibits selective adsorption of CO2 over CH4 and N2 at 273 K and 295 K, C2H2 over CH4 at 273 K. The most significant performanc…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

Enzymes of yeast polyphosphate metabolism: structure, enzymology and biological roles

Rūta Gerasimaitė、Andreas Mayer2016-02-09Biochemical Society Transactions

Inorganic polyphosphate (polyP) is found in all living organisms. The known polyP functions in eukaryotes range from osmoregulation and virulence in parasitic protozoa to modulating blood coagulation, inflammation, bone mineralization and cellular signalling in mammals. However mechanisms of regulation and even the id…

Fungal and yeast genetics researchbiodegradable polymer synthesis and propertiesCoagulation, Bradykinin, Polyphosphates, and Angioedema

Controlled Formation of Surface Patterns in Metal Films Deposited on Elasticity-Gradient PDMS Substrates

Senjiang Yu、Yadong Sun、Yong Ni 等 5 位作者2016-02-09ACS Applied Materials & Interfaces

Controlled surface patterns are useful in a wide range of applications including flexible electronics, elastomeric optics, fluidic channels, surface engineering, measurement technique, biological templates, stamps, and sensors. In this work, we report on the controlled formation of surface patterns in metal films depo…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

A comparative study on the in vivo degradation of poly(L-lactide) based composite implants for bone fracture fixation

Zongliang Wang、Yu Wang、Yoshihiro Ito 等 5 位作者2016-02-09Scientific Reports

Composite of nano-hydroxyapatite (n-HAP) surface grafted with poly(L-lactide) (PLLA) (g-HAP) showed improved interface compatibility and mechanical property for bone fracture fixation. In this paper, in vivo degradation of n-HAP/PLLA and g-HAP/PLLA composite implants was investigated. The mechanical properties, molecu…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastybiodegradable polymer synthesis and properties