Materials Literature
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A stimulus (vapour/heat)-responsive fluorescent dye as well as a luminescent conjugated polymer were readily generated using a reactive inkjet printing system.
Highly dispersed AuNPs of sizes 2–5 nm deposited onto third generation PAMAM dendrimers attached to XAD-4 for facile epoxidation of styrene.
A reusable and effective catalytic system has been developed for oxidation of pyridines catalyzed by Keplerate polyoxomolybdate ({Mo <sub>132</sub> }) at room temperature. Pyridine compounds could be oxidized in high yields under mild conditions.
Active SERS ultrathin films (UTFs) based on a two-dimensional architecture have been fabricated, and densely immobilized Au NPs leads to an enhanced electromagnetic field and improved SERS effect. These UTFs exhibit versatility and sensitivity in the detection in various analytes.
A conventional electrospinning setup cannot work without a plug (electricity supply). In this article, we report a self-powered electrospinning setup based on a hand-operated Wimshurst generator. The new device has better applicability and portability than a typical conventional electrospinning setup because it is lig…
One trinuclear and two tetranuclear cyanide-bridged Fe(III)-Ni(II) complexes were synthesized via treatment of a tricyanometallate with divalent Ni salts in the presence of 1-butylimidazole, 2,2-bipyrimidyl and 1,10-phenanthroline, respectively. Magnetic property studies demonstrated that the three complexes exhibit s…
A remarkably improved dissolution of cellulose in 40 wt% tetra- <italic>n</italic> -butylammonium hydroxide has been realized with a decrease of temperature to 16 °C.
Fatty-amide derivatives were evaluated to study the effect of the double bonds into the hydrocarbon chain (C18) on the corrosion behavior of carbon steel. Electrochemical impedance spectroscopy (EIS) and real-time corrosion measurements were used to evaluate the inhibition mechanism of the fatty-amides on carbon steel…
The PEG-polyester copolymers bearing disulfide groups were synthesized to serve as redox-responsive anticancer drug carriers with an enhanced efficacy.
There is a need for low cost, sensitive and chemical specific detectors for routine characterization of biomolecules. In this study, we utilize sheath-flow surface-enhanced Raman scattering (SERS) to analyze a mixture of eight biologically-active peptides separated by capillary zone electrophoresis (CZE). Analysis of…
Five new selenides, Cs[RE <sub>9</sub> Mn <sub>4</sub> Se <sub>18</sub> ] (RE = Ho–Lu), adopting the BaV <sub>13</sub> O <sub>18</sub> -structure type and the A/M-structure correlation are reported.
Glass forming systems are characterized by a stability against crystallization upon heating and by the easiness with which their liquid phase can be transformed into a solid lacking of long-range order upon cooling (glass forming ability). Here, we report the thickness dependence of the thermal phase transition temper…
Porous Mn3O4 hexagonal nanoplates were synthesized through annealing the hydrohausmannite precursor obtained by a one-pot hydrothermal process and by precisely controlling the concentrations of potassium hydroxide and glucose. The effect of potassium hydroxide and glucose on the growth of hexagonal nanoplates was inve…
Cu <sub>0.27</sub> Co <sub>2.73</sub> O <sub>4</sub> /MnO <sub>2</sub> hybrid hierarchical nanostructure arrays directly on pressed nickel foam, with thin MnO <sub>2</sub> nanoflakes homogeneously wrapped on Cu <sub>0.27</sub> Co <sub>2.73</sub> O <sub>4</sub> nanorod arrays, are successfully synthesized by a simple h…
The central composite design-response surface methodology provided theoretical guidance for development of co-processed excipients based on calcium carbonate and HPMC.
Ionic liquids (ILs) were screened on the basis of solubility of ethylene diamine bisborane (EDAB) using the COSMO-SAC model and LUMO–HOMO calculations. Thereafter, thermal dehydrogenation of EDAB was conducted with imidazolium-acetate based ILs.
We review briefly the concept of colloidal dispersions, their general properties, and some of their most important applications, as well as the basic molecular interactions that give rise to their properties in equilibrium. Similarly, we revisit Brownian motion and hydrodynamic interactions associated with the concept…
Manipulating the band gap of ZrNiSn (half-Heusler) alloys through isoelectronic substitutions at Ti/Zr and Sn/Ge sites, and nanostructuring afford a simultaneous enhancement of thermopower and reduction in thermal conductivity leading to a significant increase in the <italic>ZT</italic> value.
Dual photoluminescence peaks observed during the synthesis of colloidal PbS nanosheets reveal their growth mechanism - two-dimensional attachments of the quantum dots. Well-grown nanosheets show the photoluminescence linewidth of 95 meV at room temperature. Aged nanosheets in toluene have enhanced photoluminescence wi…
Fast detection and identification of thiram, a kind of well-known pesticide, presents a great challenge to environmental researchers. This work developed a kind of oleate-modified Fe3O4@Ag core@shell composite microsphere as a magnetic separable SERS substrate for quick selective sensing of thiram. In the synthesis pr…