Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Abstract The effect of the spherical shape of powder on the determination of oxide thickness in ESCA analysis in investigated. A theoretical model, which takes account of the angular dependence of the X‐ray flux, the photoelectron intensity and the etch rate, is outlined. The model agrees well with experimental depth…
Abstract Small additions of yttrium to NiAl result in a decreasing oxygen transport through the Al 2 O 3 scale on AiAl at 1270 K, as has been shown by nuclear reaction analysis ( 18 O(p, α) 15 N). A higher concentration, e.g. 0.5 wt%, has the opposite effect. Yttrium segregates to the grain boundaries in the alloy, an…
The supposedly primitive prasinophyte Pseudoscourfieldia marina has been established in culture and examined in detail. The cells swim by means of two unequal but parallel posterior flagella. Pseudoscourfieldia differs from other green flagellates in the structure of the flagellar root system, possession of a conspicu…
Abstract The use of the solvent mixture chloroform/hexafluoroisopropanol (98 : 2 vol %) in the GPC‐analysis of polyethylene terephthalate (PET) is described. PET‐samples of different molecular weight have been prepared and characterized by light scattering, viscometry, and improved techniques of osmometry and end grou…
Abstract A comprehensive XPS/XAES investigation of the dense 6:3 co‐ordinated SiO 2 polymorph stishovite in comparison with different SiO 4/2 samples and Si was carried out for the first time. By evaluation of initial state and final state shift contributions, effective charges and extra‐atomic relaxation energies wer…
The section method is applied to derive the Penrose pattern and related patterns with a ten- or fivefold axis. These are derived from a four-dimensional decagonal crystal or from a five-dimensional icosahedral crystal as a two-dimensional section. The two descriptions correspond to the three- and four-dimensional ones…
Abstract Quantitative Auger analysis is much more difficult to achieve than quantitative XPS, as the latter shows only one photoelectron peak when the former exhibits many relaxation peaks laying over a 100 ev range. A good way to check our understanding of the Auger process is to simulate spectra. For that we need to…
Abstract Processing plastics below their melting points has been shown to be an effective way to significantly enhance the mechanical, chemical, and physical properties of semi‐crystalline thermoplastics. A number of techniques have been developed that are capable of producing highly oriented fibers, films, and shapes…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidation of silver films by atomic oxygenWilliam M. Moore and Peter J. CodellaCite this: J. Phys. Chem. 1988, 92, 15, 4421–4426Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://doi.org/10.1021/j100326a035…
The thermodynamic properties of supercooled liquids are discussed and a phenomeno-logical model, capable of representing the most important experimental features, is presented. The most characteristic feature is the gradual decrease in entropy, by which the entropy of the liquid approaches that of a crystalline solid…
Abstract The principal scope of this work is to explore the capacity of XPS spectroscopy in the characterization of oxides through consideration of O 1s spectra. Several examples of oxides, analysed both separately and in the form of mechanical mixtures, are reviewed. The quantitative aspects involved in the XPS analy…
Theoretical spectroscopic constants are reported for the X 1Σ+ and a 3Δ states of the fluorides, chlorides, and bromides of scandium and yttrium. The calculated D0 values (eV) are ScF(6.00), ScC1(4.55), ScBr(3.90), YF(6.72), YC1(5.36), and YBr(4.74). All systems are predicted to have 1Σ+ ground states once the effect…
For pt.I see ibid., vol.3, no.3, p.923-30 (1988). An improved model for the calculation of statistical time lags in SF/sub 6/ insulated electrode arrangements for positive impulse voltage is presented. On the basis of physical considerations, the production rate of initial electrons is ascribed to the local density of…
Atoms and Molecules Structure of Solids Phase Transformations and Phase Equilibria Defects and Imperfections in Solids Rate Processes and Crystallization Surfaces and Interfacial Phenomena Mechanical Properties Metals Ceramics and Related Materials Polymers Electronic Properties Magnetic Properties Thermal Properties…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemistry and spectroscopy of magnesium phthalocyanine. Analysis of the absorption and magnetic circular dichroism spectraEdward Ough, Tebello Nyokong, Katherine A. M. Creber, and Martin J. StillmanCite this: Inorg. Chem. 1988, 27, 15, 2724–2732Publication Date (Print…
The tetragonal tungsten bronze ferroelectrics in the strontium barium niobate system have been extensively studied over many years. As for many of the bronzes, a crude interpretation of the experimental data has been attempted in the past using the simple Landau-Ginsburg-Devonshire expansion of the Gibbs free energy a…
Abstract This paper has described silicone rubber, its first commercial development in 1944, and its technological progress since then. Pioneering research on silicon opened the door to the development of silicone polymers and silicone rubber. The substitution of two methyl groups on silicon was present in the first e…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnesium anthracene systems and their application in synthesis and catalysisBorislav BogdanovicCite this: Acc. Chem. Res. 1988, 21, 7, 261–267Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://pubs.acs.org…
The electronic structures of two mixed-valence MnMn complexes, [LMnClBr]·HO (2) and [LMnBr]·1/2CHCl (3), and the Mn complex LMnCl (4) are probed. The L ligand is the dianion of the Schiff base condensation of 2 mol of 1,3-diaminopropane and 2 mol of 2,6-diformyl-4-tert-butylphenol. The X-ray structure of complex 4 has…
The effects of temperature on the assembly of collagen fibrils were examined in a system in which collagen monomers are generated de novo and in a physiological buffer by specific enzymic cleavage of type I pC-collagen, an intermediate in the normal processing of type I procollagen to type I collagen. Increasing the t…