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C2-symmetric chiral tetrathiafulvalene-bis(oxazolines) (TTF-BOX): new precursors for organic materials and electroactive metal complexes

François Riobé、Narcis Avarvari2009-01-01Chemical Communications

Chiral C(2)-symmetric electroactive bis(oxazolines) containing an EDT-TTF (ethylenedithio-tetrathiafulvalene) backbone, as promising multifunctional ligands and precursors for chiral molecular materials, were synthesized and structurally characterized, together with octahedral molybdenum and tungsten carbonyl complexe…

Magnetism in coordination complexesCrystallography and molecular interactionsOrganic and Molecular Conductors Research

The pyridinone-methide elimination

Rotem Perry‐Feigenbaum、Phil S. Baran、Doron Shabat2009-01-01Organic & Biomolecular Chemistry

The quinone-methide elimination is a common, efficient methodology used in linkers designed to undergo self-fragmentation. Here, for the first time, we demonstrate this elimination in a pyridine ring system. Under physiological conditions, a compound constructed of a pyridine core, a reporter, and an enzymatic trigger…

Chemical Synthesis and AnalysisClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

Chirally self-assembled porphyrin nanowires assisted by L-glutamide-derived lipid for excitation energy transfer

Hirokuni Jintoku、Takashi Sagawa、Makoto Takafuji 等 4 位作者2009-01-01Organic & Biomolecular Chemistry

An L-glutamide-functionalized tetraphenylporphyrin () has been newly synthesized and its self-assembling behavior in organic solvents is reported. forms nanofibrous assemblies in a dilute solution to show specific induced circular dichroism at the absorption band around the porphyrin moiety. It enables us to observe t…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical Studies

Development of Flashback Resistant Low-Emission Micro-Mixing Fuel Injector for 100% Hydrogen and Syngas Fuels

Howard Lee、S. Moreno Hernandez、Vincent McDonell 等 6 位作者2009-01-01OpenAlex

The present work extends previous efforts using “micro-mixing” fuel injectors operating on hydrogen fuel to elevated pressure and temperature and includes initial evaluation of a second injector concept. A micro-mixing fuel injector consists of multiple, small and closely spaced mixing cups, within which fuel and air…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCombustion and flame dynamics

Oxidation Behavior and Electrical Property of a Ni-Based Alloy in SOFC Anode Environment

Bin Hua、Fengshuang Lu、Jianfu Zhang 等 7 位作者2009-01-01Journal of The Electrochemical Society

The oxidation behavior and electrical property of a Ni–Mo–Cr alloy at in a simulated solid oxide fuel cell (SOFC) anode environment (humidified and diluted ) have been studied. The thermally grown oxide scale presents a multilayered structure, which is similar to that formed in air, with densely grown in between an un…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Solidification Microstructure, Thermal Properties and Hardness of Magnesium Alloy 20 mass% Gd Added AZ91D

Masaki Sumida、Sanghoon Jung、Toshimitsu Okane2009-01-01MATERIALS TRANSACTIONS

The solidification microstructure, the thermal property, and the hardness were investigated on AZ91D magnesium alloy and on AZ91D magnesium alloy with 20 mass% gadolinium addition. AZ91D and AZ91D + 20 mass% Gd were solidified by the furnace cooling technique starting from 700°C in an Ar flow atmosphere. The microstru…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesMetallurgical and Alloy Processes

Preparation and Luminescence Properties of Gd[sub 2]MoO[sub 6]:Eu[sup 3+] Nanofibers and Nanobelts by Electrospinning

Zhiyao Hou、Hongzhou Lian、Milin Zhang 等 7 位作者2009-01-01Journal of The Electrochemical Society

Gd 2 MoO 6 : Eu 3 + nanofibers and nanobelts have been prepared by a combination method of the sol–gel process and electrospinning. X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Methods and Software for Diffuse X-Ray Scattering from Protein Crystals

Michael E. Wall2009-01-01Methods in molecular biology

Proteins in thermal equilibrium are associated with conformational distributions rather than single, static structures. Although there are no experimental methods to measure the full protein conformational distribution, several methods exist to probe important aspects. Diffuse X-ray scattering is one such method. We h…

Protein Structure and DynamicsEnzyme Structure and FunctionX-ray Spectroscopy and Fluorescence Analysis

Load Transfer Analysis in Short Carbon Fibers with Radially-Aligned Carbon Nanotubes Embedded in a Polymer Matrix

M. C. Ray、Roberto Guzmán de Villoria、Brian L. Wardle2009-01-01DSpace@MIT (Massachusetts Institute of Technology)

A novel shortfiber composite in which the microscopic advanced fiber reinforcements are coated with radially aligned carbon nanotubes (CNTs) is analyzed in this study. A shear-lag model is developed to analyze the load transferred to such coated fibers from the aligned-CNT reinforced matrix in a hybrid composite appli…

Carbon Nanotubes in CompositesFiber-reinforced polymer compositesSmart Materials for Construction

Advances in polymer processing

Sabu Thomas、Yang Weimin2009-01-01Woodhead Publishing Limited eBooks

Part 1 Introduction: Recent advances in polymer processing: the state of the art, new challenges and opportunities Non-Newtonian fluid mechanics and polymer rheology Polymeric materials: elastomers, plastics, fibers, composites, nanocomposites and blends Compounding and mixing of polymers Screw extrusion in polymer pr…

Additive Manufacturing and 3D Printing TechnologiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Microporous and Mesoporous Materials

Landong Li、Naijia Guan2009-01-01OpenAlex

Metal cation (metal = Cu, In and La) ion exchanged ZSM-5 zeolites as catalysts for the NO selective reduction by propane and propene in excess oxygen. The surface reactions of HC-SCR over catalysts were investigated through in situ DRIFTS method. For C3H8-SCR, adsorbed nitrate species (–NO3) were observed as main reac…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Phase transition and thermodynamic properties of TiO 2 from first-principles calculations

Jing-Xin Yu、Min Fu、Guang‐Fu Ji 等 4 位作者2009-01-01Chinese Physics B

The pressure induced phase transitions of TiO 2 from anatase to columbite structure and from rutile to columbite structure and the temperature induced phase transition from anatase to rutile structure and from columbite to rutile structure are investigated by ab initio plane-wave pseudopotential density functional the…

Luminescence Properties of Advanced MaterialsHigh-pressure geophysics and materialsThermal and Kinetic Analysis

Water Vapour Resistance of Knitted Fabrics under Different Environmental Conditions

Zenun Skenderi、I. Salopek-Čubrić、Miroslav Srdjak2009-01-01Fibres and Textiles in Eastern Europe

The comfort of textile materials has been the focus of many investigations since the concern for personal well-being and improving the quality of life started to become an important issue. The aim of this paper is to simulate water vapour transfer through knitted fabrics under different environmental conditions. In th…

Textile materials and evaluationsErgonomics and Musculoskeletal Disorders

Phosphorus Fractions of Selected Calcareous Soils of Qazvin Province and their Relationships with Soil Characteristics

M Mostashari、M. Ardalan、N. Karimian 等 5 位作者2009-01-01American-Asian-Journal of agricultural & environmental sciences/American-Eurasian journal of agricultural & environmental sciences

Informations of phosphorus fractions are important for evaluation of their status in soil and understanding of soil chemistry that influence soil fertility. To obtain such information, amount and distribution of P in different fractions of 20 soil samples of Qazvin province, Iran were determined by sequential extracti…

Soil Carbon and Nitrogen DynamicsPlant Micronutrient Interactions and EffectsClay minerals and soil interactions

Towards a general organogelator: combining a versatile scaffold and an efficient linking process

Giacomo Ghini、Luisa Lascialfari、Claudia Vinattieri 等 9 位作者2009-01-01Soft Matter

A new organogelating moiety, 1, is proposed as a suitable and versatile building block for the production of other gelling compounds. Linking 1 with several different molecular fragments afforded new gels with different properties. A detailed investigation of the ferrocene substituted gelator is reported in this study.

Carbohydrate Chemistry and SynthesisSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Forgeability and Flow Stress of Mg-Zn-Y Alloys with Long Period Stacking Ordered Structure at Elevated Temperatures

Ryo Matsumoto、Michiaki Yamasaki、Masaaki OTSU 等 4 位作者2009-01-01MATERIALS TRANSACTIONS

To develop a forging process for high strength Mg-Zn-Y alloys with a long period stacking ordered (LPSO) structure, the forgeability and flow stress of Mg97Zn1Y2 (at%) alloys were investigated with the upsettability test at an initial strain rate of 0.55 s−1. As-cast and extruded Mg97Zn1Y2 alloys can be successfully f…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesHydrogen Storage and Materials

A “reverse interrupter”: the novel molecular design of a fluorescent photochromic DTE-based bipyridine

Vincent Aubert、Eléna Ishow、Fatima Ibersiene 等 10 位作者2009-01-01New Journal of Chemistry

An original design of a fluorescent dithienylethene (DTE)-based bipyridine, where donor (D) and acceptor (A) groups are located on the same thiophene ring of the DTE unit, is reported; in non-polar solvents, UV or visible excitation triggers a photochromic reaction, disrupting the conjugation and quenching the fluores…

Photochromic and Fluorescence ChemistryPhotoreceptor and optogenetics researchSynthesis of Indole Derivatives

Facile synthesis of highly uniform octahedral LuVO4 microcrystals by a facile chemical conversion method

Guang Jia、Hongpeng You、Lihui Zhang 等 7 位作者2009-01-01CrystEngComm

Uniform octahedral LuVO4 microcrystals have been successfully prepared through a designed two-step hydrothermal method. One-dimensional lutetium precursor was first prepared through a simple hydrothermal route. Subsequently, a well-shaped octahedral LuVO4 sample was synthesized at the expense of the wirelike precursor…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsQuantum Dots Synthesis And Properties

Speciation of gadolinium in gadolinium-based magnetic resonance imaging agents by high performance liquid chromatography inductively coupled plasma optical emission spectrometry

Chethaka Kahakachchi、Dennis A. Moore2009-01-01Journal of Analytical Atomic Spectrometry

A highly sensitive and robust method for the determination of six gadolinium species by reversed-phase liquid chromatography coupled with inductively coupled plasma optical emission spectrometry (HPLC-ICP-OES) has been developed. The gadolinium(III) complexes, Gd–DTPA2−, Gd–DOTA1−, Gd–HP–DO3A, Gd–DTPA–BMA and Gd–DTPA–…

Analytical chemistry methods developmentRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Enhancement of Luminescence Properties by Sr[sup 2+] Substituting Ba[sup 2+] in Red-Emitting Phosphors: Ba[sub 1−y]Sr[sub y]La[sub 2−x]ZnO[sub 5]:xEu (x=0–1, y=0–0.7)

Chih-Hao Liang、Yee-Cheng Chang、Yee‐Shin Chang2009-01-01Journal of The Electrochemical Society

Enhancement of Luminescence Properties by Sr2 + Substituting Ba2 + in Red-Emitting Phosphors: Ba1 − y Sr y La2 − x ZnO5 : xEu ( x = 0 – 1 , y = 0 – 0.7 ) , Liang, Chih-Hao, Chang, Yee-Cheng, Chang, Yee-Shin

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGa2O3 and related materials