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High Catalytic Activity and Chemoselectivity of Sub-nanometric Pd Clusters on Porous Nanorods of CeO2 for Hydrogenation of Nitroarenes

Sai Zhang、Chun‐Ran Chang、Zheng‐Qing Huang 等 9 位作者2016-02-01Journal of the American Chemical Society

Sub-nanometric Pd clusters on porous nanorods of CeO2 (PN-CeO2) with a high Pd dispersion of 73.6% exhibit the highest catalytic activity and best chemoselectivity for hydrogenation of nitroarenes to date. For hydrogenation of 4-nitrophenol, the catalysts yield a TOF of ∼44059 h(-1) and a chemoselectivity to 4-aminoph…

Catalytic Processes in Materials ScienceNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries

Guoxing Li、Jinhua Sun、Wenpeng Hou 等 6 位作者2016-02-01Nature Communications

Sulfur is a promising cathode material for lithium-sulfur batteries because of its high theoretical capacity (1,675 mA h g(-1)); however, its low electrical conductivity and the instability of sulfur-based electrodes limit its practical application. Here we report a facile in situ method for preparing three-dimensiona…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Influence of Solutionizing Parameters on the Structure and Corrosion Resistance of the ZnAl40Cu3 Alloy

A. Tomaszewska、R. Michalik、Magdalena Jabłońska2016-02-01Diffusion and defect data, solid state data. Part B, Solid state phenomena/Solid state phenomena

The purpose of carried out examination was to determine the effect of solution heat treatment on the structure and corrosion resistance of the ZnAl40Cu3 alloy in the "acid rain" environment. The scope of the test included Brinell hardness tests, structural tests and galvanostatic and potentiodynamic tests. The examina…

Material Properties and ApplicationsEngineering Applied ResearchMetallurgy and Material Science

Nonlinear model of Ni-Ti wire actuator: Modeling for control purposes

Peter Drahoš2016-02-01OpenAlex

The paper deals with the modeling and simulation of a Ni-Ti alloy wire actuator heated by an electrical resistance and cooled by natural air. In general, the model consists of non-linear static and dynamic parametric differential equations and dominant thermal hysteresis with memory. The paper deals with a modificatio…

Shape Memory Alloy TransformationsPiezoelectric Actuators and ControlIterative Learning Control Systems

Electrical Properties of Carbon Nanotube-Reinforced Polymer Composites

S.M. Lebedev、O.S. Gefle、E. T. Amitov 等 5 位作者2016-02-01Key engineering materials

Novel electrically conductive SWCNT-reinforced composites were studied in this work. Incorporating SWCNT into CB/polymer composites provides lowering the percolation threshold. Adding a small quantity of single-walled carbon nanotubes into CB/polymer composites allows reducing CB content in electrically conductive com…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesConducting polymers and applications

Electroclinic effect in a chiral paranematic liquid-crystal layer above the bulk nematic-to-isotropic transition temperature

Ian R. Nemitz、Emmanuelle Lacaze、Charles Rosenblatt2016-02-01Physical review. E

Electroclinic measurements are reported for two chiral liquid crystals above their bulk chiral isotropic-nematic phase transition temperatures. It is found that an applied electric field E induces a rotation θ [∝Ε] of the director in the very thin paranematic layers that are induced by the cell's two planar-aligning s…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationMolecular spectroscopy and chirality

Synthesis and Electrochemical Properties of Functionalized Graphene Oxide/ZnO Composites

Fang Ding、Na Zhang、Cheng Zhang2016-02-01Key engineering materials

ZnO quantum dots (QDs) are anchored on graphene oxide (GO) by a wet chemical self-assembling technique. Firstly, GO are functionalized with thiol (f-GO) by a series of chemical reactions and the ZnO alcogel are prepared by a sol–gel process. Secondly, the f-GO/ZnO composite is obtained by a self-assembling technique.…

Supercapacitor Materials and FabricationConducting polymers and applicationsGraphene and Nanomaterials Applications

Nanodiamonds: Nanodiamond‐Embedded p‐Type Copper(I) Oxide Nanocrystals for Broad‐Spectrum Photocatalytic Hydrogen Evolution (Adv. Energy Mater. 4/2016)

Zhaoyong Lin、Jun Xiao、Lihua Li 等 6 位作者2016-02-01Advanced Energy Materials

The use of nanodiamonds to improve the photocatalytic hydrogen evolution reaction of Cu2O by nanocomposition is demonstrated for the first time by Guowei Yang and co-workers in article number 1501865. Compared with pure Cu2O, this nanocomposite shows a tremendous improvement in performance. It is also established that…

Copper-based nanomaterials and applications

Plastic deformation and fracture of masonry under biaxial stresses

Oleg Kabantsev2016-02-01Vestnik MGSU

Masonry is a complex multicomponent composite composed of dissimilar materials (brick / stone and mortar). The process of masonry deformation under load depends on the mechanical characteristics of the basic composite materials, as well as of the parameters belonging to the elements, which define the link between bric…

Building materials and conservationInnovations in Concrete and Construction MaterialsStructural mechanics and materials

Preparation, Structure and Thermolysis Characteristics of Ammonia Borane

Jian Li、Hai Yan Cao、Xiao Xia Zhang 等 4 位作者2016-02-01Key engineering materials

Ammonia borane (NH3BH3, AB) is an excellent source of hydrogen(19.6 wt %) for fuel cell applications. In this paper, pure ammonia borane is successfully prepared by using amino complex for ammonia complex Ag(NH3)2Cl as new ammonia source, and sodium borohydride (NaBH4) as boron source. The composition and constitution…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionChemical Synthesis and Characterization

Effect of inhibitors on carbon steel corrosion in foaming solutions

A. A. Kostyaev、А. В. Балмасов、Liana N. Inasaridze2016-02-01Russian Journal of General Chemistry

The corrosion behavior of carbon steel in PO-6TS-M foaming solution was studied. Several kinds of inhibiting additives were tested for their ability to reduce the corrosion rate of steel. The antipyrene additive to the foaming solution was shown to be the most effective in reducing corrosion rate of carbon steel. The…

Material Properties and Applications

The influence of nanodisperse iron(III) oxide on the morphology of microsized alumina fibers

В. И. Михайлов、Elena F. Krivoshapkina、V. A. Demin 等 5 位作者2016-02-01Russian Journal of General Chemistry

The influence of fine-disperse iron oxide particles on the structure of alumina fibers prepared via the template synthesis has been studied. The template (fibers of bleached cotton cellulose) has been impregnated with mixed aqueous dispersions of aluminum and iron(III) hydroxides prepared via the sol–gel route. Therma…

Advanced Cellulose Research StudiesIron oxide chemistry and applicationsBauxite Residue and Utilization

Finite Element Analysis of ECAP, TCAP, RUE and CGP Processes

Deepak C. Patil、Vinayak Kallannavar、Prabhakar M. Bhovi 等 5 位作者2016-02-01IOP Conference Series Materials Science and Engineering

A finite element method was applied to study the various severe plastic deformation processes like, Equal Channel Angular Pressing (ECAP), Tubular Channel Angular Pressing (TCAP), Repetitive Upsetting and Extrusion (RUE) and Constrained Groove Pressing (CGP), considering aluminum AA-390 alloy as specimen material for…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesAluminum Alloys Composites Properties

Specific features of magnetic states of impurity iron ions in the perovskite La0.75Sr0.25Co0.98 57Fe0.02O3

В. С. Покатилов、В. С. Покатилов、V. S. Rusakov 等 7 位作者2016-02-01Physics of the Solid State

Single-phase polycrystalline La0.75Sr0.25Co0.98 57Fe0.02O3 samples have been prepared by solidstate ceramic technology. The samples have the rhombohedral structure (space group $$R\bar 3c$$ ). The studies of perovskite La0.75Sr0.25Co0.98 57Fe0.02O3 by Mössbauer spectroscopy on impurity 57Fe nuclei in the temperature r…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Study of Mechanical Properties of Electroless Nickel-Phosphorus Coatings with Influence of Surfactant on AZ91 Magnesium Alloy

Mohd. Imran Ansari、D. G. Thakur2016-02-01Advanced engineering forum

Electroless Nickel-Phosphorus (ENi-P) coating is well-known in surface engineering techniques and is preferred in various mechanical, chemical and electronic industries view its extraordinary resistance to wear and corrosion. The paper summerizes the effect of surfactant on the mechanical properties of electroless Nic…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsElectrodeposition and Electroless Coatings

Manipulating fluorescence color and intensity with regular metal nanoparticle-based composite materials

Andrey G. Nikitin2016-02-01Applied Physics Letters

The Editor and publisher have retracted “Manipulating fluorescence color and intensity with regular nanoparticle-based composite materials” Appl. Phys. Lett.108, 051112 (2016). Because of a legal issue related to the publication of work covered under a confidentiality agreement, the electronic version of the paper has…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranosticsPolydiacetylene-based materials and applications

Structural and magnetic characterization of the new GdMn1-xFexO3perovskite material

Jorge Andres Cardona Vasquez、D.A. Landı́nez Téllez、Carlos Collazos 等 4 位作者2016-02-01Journal of Physics Conference Series

In this paper we presents the synthesis process of the GdMn 1-x Fe x O 3 perovskite material by conventional solid state reaction method. Crystalline phase evolution during the synthesis was studied by X-ray Diffraction (XRD) in powder of the materials, observing that the chemical reaction of the precursor oxides was…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Solid-phase synthesis of intermetallic compounds Al13Co4, Al13Fe4, and Al13Co2Fe2

V. A. Artukh、Г. Д. Нипан、V. S. Yusupov2016-02-01Doklady Chemistry

Intermetallic compounds Al 13 Co 4 , Al 13 Fe 4 , and Al 13 Co 2 Fe 2 were obtained by solid-phase synthesis in air at temperatures below 600°C using precursor metals subjected to mechanochemical preactivation. The phase composition of the synthesized aluminides and composites Al 13 Co 4 /SiO 2 and Al 13 Fe 4 /SiO 2 w…

Aluminum Alloys Composites PropertiesIntermetallics and Advanced Alloy PropertiesQuasicrystal Structures and Properties

First-principle investigation on the thermodynamics of X 2 N 2 O ( X = C, Si, Ge) compounds

Qingyun Xiong、Qi-Xia Shen、Ruizi Li 等 5 位作者2016-02-01Chinese Physics B

The structures under different pressures, elastic properties, electronic structures and lattice vibrations of the X 2 N 2 O ( X = C, Si, Ge) compounds are investigated by using the first-principle method. Based on the phonon density of state, the thermodynamic properties of the present compounds are studied under diff…

High-pressure geophysics and materialsBoron and Carbon Nanomaterials ResearchThermal Expansion and Ionic Conductivity