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Modification of graphene‐oxide surface in nitrogen and argon glow discharge plasma

M. Mohai、I. Bertóti2016-01-18Surface and Interface Analysis

We performed glow discharge N 2 or Ar plasma treatments of thin layers of graphene oxide (GO) deposited from slurry in alcohol onto stainless steel substrates. The treatment was performed in the preparation chamber of the x‐ray photoelectron spectrometer, allowing reliable in situ characterization of the treated surfa…

Graphene research and applicationsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Water‐ and Temperature‐Triggered Reversible Structural Transformation of Tetranuclear Cobalt(II) Cores Sandwiched by Polyoxometalates

Yosuke Kuriyama、Yuji Kikukawa、Kosuke Suzuki 等 5 位作者2016-01-18Chemistry - A European Journal

Although stimuli-responsive structural transformations of inorganic materials have attracted considerable attention because of their potential use as functional switchable materials, multinuclear metal cores frequently suffer from unexpected dissociation of metal cations and/or irreversible transformations into infini…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

The response of single-walled carbon nanotubes to NO2 and the search for a long-living adsorbed species

Jaap Kroes、Fabio Pietrucci、Kiran Chikkadi 等 6 位作者2016-01-18Applied Physics Letters

Contact-passivated sensor devices allow one to measure the response of individual ultraclean single-walled carbon nanotubes to 1 ppm NO2, and show that the activation energies for desorption from nanotubes of diameters in the 1.5–3.5 nm range are of the order of 1 eV. DFT calculations based on several exchange-correla…

Carbon Nanotubes in CompositesGas Sensing Nanomaterials and SensorsMechanical and Optical Resonators

Broadband metasurfaces enabling arbitrarily large delay-bandwidth products

Vincent Ginis、Philippe Tassin、Thomas Koschny 等 4 位作者2016-01-18Applied Physics Letters

Metasurfaces allow for advanced manipulation of optical signals by imposing phase discontinuities across flat interfaces. Unfortunately, these phase shifts remain restricted to values between 0 and 2π, limiting the delay-bandwidth product of such sheets. Here, we develop an analytical tool to design metasurfaces that…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

In vivo and in situ imaging of controlled‐release dissolving silk microneedles into the skin by optical coherence tomography

Ran Liu、Ming‐Tian Zhang、Cuiyun Jin2016-01-18Journal of Biophotonics

Nowadays, transdermal drug delivery has become a hot topic with regard to delivery. Also, the percutaneous microneedle patch made of water-soluble material makes this technique one step closer to clinical application. The process of the microneedle patch penetrates and dissolves in the animal skin can directly reflect…

Advancements in Transdermal Drug DeliveryOptical Coherence Tomography ApplicationsSilk-based biomaterials and applications

Magnetic MoS2 pizzas and sandwiches with Mnn (n = 1–4) cluster toppings and fillings: A first-principles investigation

Meng Zhang、Zhongjia Huang、Xiao Wang 等 8 位作者2016-01-18Scientific Reports

The inorganic layered crystal (ILC) MoS2 in low dimensions is considered as one of the most promising and efficient semiconductors. To enable the magnetism and keep intrinsic crystal structures, we carried out a first-principles study of the magnetic and semiconductive monolayer MoS2 adsorbed with the Mnn (n = 1-4) cl…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Vertical La0.7Ca0.3MnO3 nanorods tailored by high magnetic field assisted pulsed laser deposition

Kejun Zhang、Jianming Dai、Xuebin Zhu 等 13 位作者2016-01-18Scientific Reports

La0.7Ca0.3MnO3 (LCMO) thin films on (LaAlO3)0.3(Sr2AlTaO6)0.7 (001) [LSAT (001)] single crystal substrates have been prepared by high magnetic field assisted pulsed laser deposition (HMF-PLD) developed by ourselves. Uniformly sized and vertically aligned nanorod structures can be obtained under an applied high magneti…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsMagnetic Properties of Alloys

The morphology of graphene on a non-developable concave substrate

Yuli Chen、Yong Ma、Shengtao Wang 等 5 位作者2016-01-18Applied Physics Letters

The performances of graphene sheet in micro- and nano-electronics and devices are significantly affected by its morphology, which depends on the surface features of the supporting substrate. The substrates with non-developable concave surface are widely used with graphene sheet in applications but rarely studied. Ther…

Graphene research and applications2D Materials and ApplicationsAdvanced Sensor and Energy Harvesting Materials

An ultrafast terahertz probe of the transient evolution of the charged and neutral phase of photo-excited electron-hole gas in a monolayer semiconductor

Xue-Feng Liu、Hongyi Yu、Qingqing Ji 等 9 位作者2016-01-182D Materials

We investigate the dynamical formation of an exciton from photo-excited electron-hole plasma and its subsequent decay dynamics in monolayer MoS 2 grown by chemical vapor deposition (CVD) using ultrafast pump and terahertz probe spectroscopy. Different photo-excited electron-hole states are resolved based on their dist…

Semiconductor Quantum Structures and Devices2D Materials and ApplicationsStrong Light-Matter Interactions

Single Droplet on Micro Square-Post Patterned Surfaces – Theoretical Model and Numerical Simulation

Y. Q. Zu、Yuying Yan2016-01-18Scientific Reports

In this study, the wetting behaviors of single droplet on a micro square-post patterned surface with different geometrical parameters are investigated theoretically and numerically. A theoretical model is proposed for the prediction of wetting transition from the Cassie to Wenzel regimes. In addition, due to the limit…

Surface Modification and SuperhydrophobicityNanomaterials and Printing TechnologiesFluid Dynamics and Thin Films

Synthesis, characterization, and thin‐film properties of 6‐oxoverdazyl polymers prepared by ring‐opening metathesis polymerization

Joseph A. Paquette、Sabastine Ezugwu、Vishal Yadav 等 5 位作者2016-01-18Journal of Polymer Science Part A Polymer Chemistry

ABSTRACT Redox‐active 6‐oxoverdazyl polymers were synthesized via ring‐opening metathesis polymerization (ROMP) and their solution, bulk, and thin‐film properties investigated. Detailed studies of the ROMP method employed confirmed that stable radical polymers with controlled molecular weights and narrow molecular wei…

Fuel Cells and Related MaterialsConducting polymers and applicationsSynthetic Organic Chemistry Methods

Effect of Peripheral Substitution on the Performance of Subphthalocyanines in DSSCs

Maxence Urbani、Fatma Aslihan Sarı、Michaël Grätzel 等 6 位作者2016-01-18Chemistry - An Asian Journal

A series of six new subphthalocyanines (SubPcs) bearing an ethynylcarboxyphenyl anchoring unit and decorated with a variety of substituents at the peripheral position of the macrocycle have been synthesized in order to investigate the effect of the peripheral substituent on the performance of dye-sensitized solar cell…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesPorphyrin and Phthalocyanine Chemistry

The Fabrication of ZrO 2 –ZrC Microspheres by Internal Gelation and Carbothermal Reduction Process

Yong Gao、Jingtao Ma、Xingyu Zhao 等 6 位作者2016-01-18Journal of the American Ceramic Society

ZrO 2 –ZrC (ZrCO) ceramic microspheres were fabricated by combination of internal gelation and carbothermal reduction process. The internal gelation broth containing carbon powders was prepared and stored at room temperature of 25°C to form a precursor of microspheres. By dropping droplets of the broth into hot silico…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceAerogels and thermal insulation

Functional Reactive Polymer Electrospun Matrix

Vipul Agarwal、Dominic Ho、Diwei Ho 等 20 位作者2016-01-18ACS Applied Materials & Interfaces

Synthetic multifunctional electrospun composites are a new class of hybrid materials with many potential applications. However, the lack of an efficient, reactive large-area substrate has been one of the major limitations in the development of these materials as advanced functional platforms. Herein, we demonstrate th…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

A first-order antiferromagnetic-paramagnetic transition induced by structural transition in GeNCr3

Lin Zu、S. Lin、Yu Liu 等 9 位作者2016-01-18Applied Physics Letters

A first-order antiferromagnetic (AFM)-paramagnetic (PM) phase transition has been confirmed by systematic magnetic measurements in GeNCr3, and it does not depend on the applied magnetic fields. Interestingly, a structural transition from space group P-421m to I4/mcm without breaking tetragonal symmetry appears around…

Magnetic and transport properties of perovskites and related materialsInorganic Chemistry and MaterialsThermal Expansion and Ionic Conductivity

Influence of multiwall carbon nanotube alignment on vibration damping of nanocomposites

Sasidhar Jangam、S. Raja、B. Uma Maheswar Gowd2016-01-18Journal of Reinforced Plastics and Composites

In the present work, the damping behavior of multiwall carbon nanotubes/polymer nanocomposites has been studied by aligning the carbon nanotubes (CNTs) in the matrix using DC electric field during the curing of composite. Nanocomposite specimens have been fabricated for three different CNT loadings (0.1, 0.2, and 0.3…

Carbon Nanotubes in CompositesDielectric materials and actuatorsSmart Materials for Construction

Enhanced sheet conductivity of Langmuir–Blodgett assembled graphene thin films by chemical doping

Aleksandar Matković、Ivana Milošević、Marijana Milićević 等 13 位作者2016-01-182D Materials

Enhanced sheet conductivity of Langmuir–Blodgett assembled graphene thin films by chemical doping, Matković, Aleksandar, Milošević, Ivana, Milićević, Marijana, Tomašević-Ilić, Tijana, Pešić, Jelena, Musić, Milenko, Spasenović, Marko, Jovanović, Djordje, Vasić, Borislav, Deeks, Christopher, Panajotović, Radmila, Belić,…

Graphene research and applicationsQuantum and electron transport phenomenaAdvanced Memory and Neural Computing

Effects of nitrogen plasma treatment on the electrical property and band structure of few-layer MoS2

Ting-Hong Su、Yow-Jon Lin2016-01-18Applied Physics Letters

Few-layer MoS2 prepared by the chemical vapor deposition method was treated with nitrogen plasma under different radio-frequency (rf) power conditions in order to experimentally study the change in the electrical property. Control of the rf power could change the work function of MoS2 from 5.40 eV to 5.06 eV. It is sh…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Acid–Base Properties of Nanoconfined Volumes of Anodic Aluminum Oxide Pores by EPR of pH-Sensitive Spin Probes

Elena G. Kovaleva、Л. С. Молочников、Umamaheswari Venkatesan 等 8 位作者2016-01-18The Journal of Physical Chemistry C

Anodic aluminum oxide (AAO) ceramic membranes with macroscopically aligned and hexagonally packed nanopore architecture are attractive substrates for forming nanotubular lipid bilayers as well as sorption and catalytic media because of a tunable pore diameter, robust pore structure, and low fabrication cost. Here we e…

Electrocatalysts for Energy ConversionConducting polymers and applicationsAnodic Oxide Films and Nanostructures

Selective swelling induced pore generation of amphiphilic block copolymers: The role of swelling agents

Nina Yan、Yong Wang2016-01-18Journal of Polymer Science Part B Polymer Physics

Swelling of block copolymers by selective solvents has emerged as an extremely simple and efficient process to produce nanoporous materials with well-controlled porosities. However, the role of the swelling agents in this pore-making process remains to be elucidated. Here we investigate the evolution of morphology, th…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly