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Mesoporous transition metal dichalcogenide ME 2 (M = Mo, W; E = S, Se) with 2-D layered crystallinity as anode materials for lithium ion batteries

Yoon Yun Lee、Gwi Ok Park、Yun Seok Choi 等 9 位作者2016-01-01RSC Advances

Mesoporous transition metal dichalcogenides with 2D layered crystallinity, synthesized through a melting-infiltration assisted nano-replication, exhibit excellent electrochemical performances for lithium-storage.

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

g-C 3 N 4 /Bi 4 O 5 I 2 2D–2D heterojunctional nanosheets with enhanced visible-light photocatalytic activity

Na Tian、Yihe Zhang、Chengyin Liu 等 6 位作者2016-01-01RSC Advances

The 2D–2D heterojunctional g-C 3 N 4 /Bi 4 O 5 I 2 nanosheets were successfully constructed based on band gap engineering design. It exhibits high visible-light-driven photocatalytic activity for degradation of RhB and NO removal.

Advanced Photocatalysis TechniquesPerovskite Materials and ApplicationsCovalent Organic Framework Applications

Synthesis, characterization, thermal properties and antiproliferative potential of copper( ii ) 4′-phenyl-terpyridine compounds

Zhen Ma、Bian Zhang、M. Fátima C. Guedes da Silva 等 8 位作者2016-01-01Dalton Transactions

Reactions between 4'-phenyl-terpyridine (L) and several Cu(II) salts (p-toluenesulfonate, benzoate and o-, m- or p-hydroxybenzoate) led to the formation of [Cu(p-SO3C6H4CH3)L(H2O)2](p-SO3C6H4CH3) (1), [Cu(OCOPh)2L] (2), [Cu(o-OCOC6H4OH)2L] (3), [Cu(m-OCOC6H4OH)2L]4·MeOH (·MeOH) and [Cu(p-OCOC6H4OH)2L]5·2H2O (·2H2O), w…

Metal complexes synthesis and propertiesMagnetism in coordination complexesSynthesis and Characterization of Heterocyclic Compounds

Molten-salt treatment of waste biomass for preparation of carbon with enhanced capacitive properties and electrocatalytic activity towards oxygen reduction

Beihu Lu、Jing Zhou、Yuqiao Song 等 6 位作者2016-01-01Faraday Discussions

Carbon powders are building blocks for electrochemical energy storage/conversion devices. Green, cost-affordable and facile preparation of carbon with applicable electrochemical properties is therefore essential for effective utilization of fluctuating renewable energy. Herein, the preparation of carbon nanoflakes via…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Unravelling the nature, evolution and spatial gradients of active species and active sites in the catalyst bed of unpromoted and K/Ba-promoted Cu/Al 2 O 3 during CO 2 capture-reduction

Tsuyoshi Hyakutake、Wouter van Beek、Atsushi Urakawa2016-01-01Journal of Materials Chemistry A

Space- and time-resolved operando DRIFTS, XAFS, and XRD uncovered the involved surface chemical species and active sites, especially the unique functions of K and Cu, during the CO 2 capture-reduction process.

Catalytic Processes in Materials ScienceCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts

Excimer emission based on the control of molecular structure and intermolecular interactions

Jae‐Hyun Lee、Hyocheol Jung、Hwangyu Shin 等 8 位作者2016-01-01Journal of Materials Chemistry C

The wavelength of excimer formation and efficiency of an OLED device were controlled through the change of the center position of the triple-core chromophore.

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Multiscale study of mononuclear Co II SMMs based on curcuminoid ligands

Raúl Díaz‐Torres、Melita Menelaou、Olivier Roubeau 等 10 位作者2016-01-01Chemical Science

Two related single-molecule magnets, [Co(9Accm) 2 (py) 2 ] and [Co(9Accm) 2 (2,2′-bpy)], with cis and trans disposition of the CCMoid ligands were studied in solution, in the solid state and by deposition on different surfaces.

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Fluorine substitution influence on benzo[2,1,3]thiadiazole based polymers for field-effect transistor applications

Ming Wang、Michael J. Ford、Hung Phan 等 6 位作者2016-01-01Chemical Communications

Four conjugated copolymers with a donor/acceptor architecture comprising 4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b']dithiophene as the donor structural unit and benzo[2,1,3]thiadiazole fragments with varying degrees of fluorination as the acceptor structural units have been synthesized and characterized. It has been s…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Highly efficient extraction of actinides with pillar[5]arene-derived diglycolamides in ionic liquids via a unique mechanism involving competitive host–guest interactions

Caixia Li、Lei Wu、Lixi Chen 等 15 位作者2016-01-01Dalton Transactions

is used as the diluent. With high efficiency in the extraction of actinides and a quantitative back extraction outcome, the RTIL-based solvent systems containing pillar[5]arene-DGA ligands developed in this work hold potential as promising candidates for nuclear waste remediation in a more sustainable fashion.

Radioactive element chemistry and processingExtraction and Separation ProcessesLanthanide and Transition Metal Complexes

Synergistic luminescence enhancement of a pyridyl-substituted triarylmethyl radical based on fluorine substitution and coordination to gold

Yohei Hattori、Tetsuro Kusamoto、Tohru Sato 等 4 位作者2016-01-01Chemical Communications

A rational molecular design for open-shell molecules to enhance their luminescence efficiency was developed. Introduction of fluorine atoms and coordination of gold(i) to PyBTM, a highly stable fluorescent radical containing a pyridyl moiety, synergistically contributed to yield ten times increase of its fluorescence…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsNanocluster Synthesis and Applications

A ZnS nanocrystal/reduced graphene oxide composite anode with enhanced electrochemical performances for lithium-ion batteries

Yan Feng、Yuliang Zhang、Yu-Zhen Wei 等 6 位作者2016-01-01Physical Chemistry Chemical Physics

), excellent cycle stability over 100 cycles (71.3% retention), and good rate performance at 2C (51.2% of its capacity when measured at a 0.1C rate). To further investigate this ZnS/RGO anode for practical use in full Li-ion cells, we tested the electrochemical performance of the ZnS/RGO anode at different cut-off vol…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

New insights into Ag-doped BiVO 4 microspheres as visible light photocatalysts

Xuan Xu、Mao Du、Tian Chen 等 7 位作者2016-01-01RSC Advances

This study describes the synthesis of Ag–bismuth vanadate (Ag–BiVO 4 ) microspheres, a highly efficient visible light photocatalyst for the degradation of methylene blue, via a one-step hydrothermal method.

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Understanding the surface segregation behavior of transition metals on Ni(111): a first-principles study

Yanlin Yu、Wei Xiao、Jianwei Wang 等 4 位作者2016-01-01Physical Chemistry Chemical Physics

The surface composition of an alloying system has an important impact on its catalytic and chemical properties. The segregation behavior of 3d, 4d and 5d transition metals on an Ni(111) surface has been investigated by performing first-principles calculations in the framework of density-functional theory with the gene…

Advanced Chemical Physics StudiesCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Photocatalytic and Photoelectrochemical Water Splitting on TiO2via Photosensitization

Saji Thomas Kochuveedu2016-01-01Journal of Nanomaterials

The search for an alternative to replace conventional fuel has been going on for years due to the limited storage of fossil fuel and excess CO2emission from the fuel. Using H2as fuel has gained wide attention recently, as well as consequently splitting of water into hydrogen and oxygen. Seminal semiconductors such as…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis