Materials Literature
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In analogy to atoms which are connected by bonds to form molecules and complexes, quantum dots (QDs) can be combined together to form larger ensembles for evoking a collective function. To this end, the development of a controlled self-assembly method for the construction of well-defined structures of the ensembles is…
Multiferroics, as the medium with more than one order parameter, have become a subject of great interest in the past decade. We present here a summary of the properties of a multiferroic, mostly a ferromagnet and a ferroelectric. They appear in three different forms; proper where the system is ferroelectric at high te…
Abstract The kinetics of the ethoxylation of fatty alcohols catalyzed by potassium hydroxide was studied to obtain the rate constants for modeling of the industrial process. Experimental data obtained in a lab‐scale semibatch autoclave reactor were used to evaluate kinetic and equilibrium parameters. The kinetic model…
Objectives: The effect of ceramics construction (press- able, machinable) and corrosion on flexural strength and micro-hardness was studied. Materials & Methods: Two types of ceramics were tested: IPS e-max Press and IPS e-max CAD. Forty samples were constructed and divided into 2 groups according to the type of ceram…
1,3-Bis[4,4′-(trimellitimido) phenoxy] propane (6) as a new monomer containing a trimethylene moiety was synthesized using a three-step reaction. First 1,3-bis[4,4′-nitrophenoxy] propane (3) was prepared by reaction of 4-nitrophenol 1 with 1,3-dibromo propane (2) in DMF. Then dinitro (3) was reduced to 1,3-bis[4,4′-am…
The magnetization and demagnetization processes in the 11 types of Dy-free Nd-Fe-B sintered magnets based on the NEOMAX-50 type magnets were investigated using the step method that is our original method of measurements and analyses of minor loops with step by step increased maximum applied fields. With the decrease i…
Time-resolved in situ x-ray diffraction measurements were used to study the room-temperature recrystallization kinetics of electroplated copper thin films with thicknesses between 400 and 1000 nm. The thinnest films exhibited limited recrystallization and subsequent growth of grains, while recrystallized grains in the…
Self-assembled single-phased stacked-pyramid zinc sulfide architectures were fabricated using a facile two-step thermal evaporation method. This novel architecture consists of a single phase hexagonal wurtzite structured stacked-pyramids architected on wire-like trunks. Direct evidence is presented to determine their…
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Effect of excess CuO on the sintering behaviour and piezoelectric properties of Bi0.5(Na82K0.18)0.5TiO3 ceramics was investigated. The addition of small amount of excess CuO as low as 0.01 mol was quite effective to lower the sintering temperature (Ts) of BNKT ceramics down to 975°C which is 200°C lower than the Ts of…
Germanium films several micrometers in thickness were electrochemically deposited on silicon wafers for the first time without catalysts and at room temperature from a solution containing Ge species that have been electrochemically dissolved from Ge target. The films were investigated using scanning electron microscop…
Innovative Tb(3+) antenna complexes employing two different substituted 2-hydroxyphthalamide ligands (HxOH-IAM and bis-HxOH-IAM) acting simultaneously as coordinating sites and light collector units have been synthesized and successively anchored in silica layers by the sol-gel technique. The complexes show remarkable…
Based on linear optical transformation method, a diamond shaped reciprocal cloak with perfect invisibility in a certain direction is proposed. Compared with traditional cloaks, the object hidden inside the reciprocal cloak is not blind and can receive information from the outer region. Moreover, the reciprocal cloak i…
A facile strategy to correlate the thermal decomposition of inorganic–organic hybrid with the Kirkendall effect appearing during the oxidation process of sulfides into oxides has been developed to synthesize hierarchical-porous-structured metal oxide microspheres by using ceria as the model system. The as-prepared hie…
A nanocomposite material combining an organic molecular gelator and oleate-coated iron oxide nanoparticles in proportions which range from one to fifty weight percent of the inorganic material has been prepared via the gel state. The proportion of nanoparticles and organic gelator in this mixed colloidal system gives…
The electro-optical characteristics of a composite film based on a polymer containing dispersed nematic liquid crystal (NLC) doped with an ionic surfactant have been studied. The threshold character of the reorientation of NLC droplets as well as the dependence of the modulation amplitude of light transmission on the…
In this study, Escherichia coil DH5alpha (ATCC 35218) were exposed to 0-100 microg/mL chromium oxide nanoparticles (Cr2O3, Nps) for 15-120 min to study the internalization of Nps by flowcytometry. A concentration-duration dependent increased side scatter (SSC) confirmed the internalization of Cr2O3 NPs by the E. coli.…
The activity of tin in Ti-Sn alloy has been determined at 1400 K by Knudsen effusion method with electrobalance. The activity of titanium was calculated by applying the Gibbs-Duhem relation to the Ti-Sn binary system. The standard Gibbs energy of the formation of intermetallic compound such as Ti3Sn, Ti2Sn, Ti5Sn3 and…
Au tipped ultranarrow PbS nanorods are synthesized. DFT electronic structure calculations and transport studies show that Au probes modify the nature and energies of PbS nanorod orbitals creating efficient electron conduction channels for enhanced conductance even at low applied bias.
The anisotropic alignment of boron nitride (BN) nanosheets was performed in polysiloxane/BN nanosheet composite film under a DC electric field with a change in polarity. The hexagonal BN nanosheets were dispersed by sonication in a prepolymer mixture of polysiloxane followed by high-speed mixing. The homogeneous suspe…