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Ultrathin Cellulose Films of Tunable Nanostructured Morphology with a Hydrophobic Component

Laura Nyfors、Miro Suchy、Janne Laine 等 4 位作者2009-04-01Biomacromolecules

In recent years, a wide range of different methods to implant nanosized patterns on surfaces have been developed. Spin coating immiscible binary polymer blends is a straightforward method to prepare micro- and nanostructures on thin films. This study utilizes binary blends to effortlessly prepare stable, surface-funct…

Advanced Cellulose Research StudiesBlock Copolymer Self-AssemblyFluid Dynamics and Thin Films

Thermoluminescence behavior of magnesium oxide exposed to gamma and ultraviolet radiations

C. Soliman2009-04-01Radiation effects and defects in solids

Magnesium oxide (MgO) has been investigated as a possible candidate for gamma (γ) dosimetry. One thermoluminescence (TL) peak was observed in the red emission band around 372 °C in the pristine sample. The glow curves indicate that the main TL peaks appear at nearly the same temperatures after γ and ultraviolet irradi…

Luminescence Properties of Advanced MaterialsThermal and Kinetic AnalysisNuclear materials and radiation effects

Diffusion in diamond. I. Carbon isotope mapping of natural diamond

John Craven、B. Harte、David Fisher 等 4 位作者2009-04-01Mineralogical Magazine

Abstract Recent advances in ion microprobe instrumentation and techniques have enabled the mapping of C isotope ratios across the whole of a polished plate of a natural diamond from Guaniamo, Venezuela. The resultant map of C isotope variation closely matches the cathodoluminescence image of the growth structure of th…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Solid electrolytes with predominant chloride conductivity

I. V. Murin、Oleg V. Glumov、N. A. Mel’nikova2009-04-01Russian Journal of Electrochemistry

The ionic transport features were studied in PbCl 2 and SnCl 2 single crystals and in KPb 2 Cl 5 , K 2 PbCl 4 , PbCl 2 -Al 2 O 3 , CsSnCl 3 , and SnCl 2 - 6 mol % MCl (M = Li, Na, Ag, K, Tl, Rb, Cs) ceramic materials. A reference data review on electroconductivity of chloride-conducting solid electrolytes was made. A…

Glass properties and applicationsMicrowave Dielectric Ceramics SynthesisOptical properties and cooling technologies in crystalline materials

Suppression of the spectral selectivity of two-layer phase-relief diffraction structures

Grigoriy I. Greisukh、Evgeni A. Bezus、Dmitry A. Bykov 等 5 位作者2009-04-01Optics and Spectroscopy

The method and results of studying the effect of relief depth on the attainable degree of reducing the spectral selectivity of two-layer diffraction structures based on plastics and glass. The possibilities of suppressing the spectral selectivity of double- and single-relief structures are compared.

Photonic Crystals and ApplicationsAdvanced optical system designOptical Coatings and Gratings

Recent developments in the synthesis of homo- and heteroarrays of porphyrins and phthalocyanines

Ana M. V. M. Pereira、Ana R. M. Soares、Mário J. F. Calvete 等 4 位作者2009-04-01Journal of Porphyrins and Phthalocyanines

Here, we report the progress in the chemistry of porphyrin-phthalocyanine and phthalocyanine-phthalocyanie multinuclear systems being developed by the organic chemistry groups of Cavaleiro and Torres.

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Grain-boundary source/sink behavior for point defects: An atomistic simulation study

Paul C. Millett、Dilpuneet S. Aidhy、Tapan Desai 等 5 位作者2009-04-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The grain-boundary source and sink strengths for both vacancies and self-interstitials have been determined for columnar nanocrystalline structures of Mo using molecular-dynamics simulation. The microstructures, which are initialized to contain either an over-saturation or under-saturation of one particular p…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAdvanced materials and composites

Electron beam irradiation induced transformations in the electro-optical and dielectric properties of a twisted-nematic display material 4′-pentyl-4-cyanobiphenyl (5CB)

Rohit Verma、Ravindra Dhar、R. Dąbrowski 等 7 位作者2009-04-01Journal of Physics D Applied Physics

Changes in the electro-optical and dielectric properties of 4'-pentyl-4-cyanobiphenyl (5CB) due to electron beam irradiation up to 20 kGy dose have been studied. Dielectric spectroscopy for planar and homeotropic aligned samples has been carried out in the frequency range 100 Hz–35 MHz. Threshold and switching voltage…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsPhotochemistry and Electron Transfer Studies

Chemostratigraphic correlation of sediments containing expandable clay minerals based on ion exchange with Cu(II) triethylenetetramine

Tomáš Matys Grygar、Jaroslav Kadlec、Anna Žigová 等 7 位作者2009-04-01Clays and Clay Minerals

Abstract Copper(II) triethylenetetramine [Cu(trien)] 2+ is an agent suitable for the 1-step determination of the cation exchange capacity (CEC) of many geomaterials using a procedure much less laborious than other, commonly used methods. It is also suitable for the determination of the composition of original exchange…

Hydrocarbon exploration and reservoir analysisRadioactive element chemistry and processingClay minerals and soil interactions

Influence of Silicon Doping on the Properties of Sputtered Ge2Sb2Te5 Thin Film

Seong‐Min Jeong、Kyung-Ho Kim、Soon‐Mok Choi 等 4 位作者2009-04-01Japanese Journal of Applied Physics

Ge 2 Sb 2 Te 5 is a promising candidate material for next-generation memory devices due to its fast phase-changing characteristics. The power consumption of an electronic device is a key factor in determining the working efficiency of next-generation memory devices. In this study, Si was doped on Ge 2 Sb 2 Te 5 thin f…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Oral bioavailability enhancement of a hydrophilic drug delivered via folic acid-coupled liposomes in rats

Sharon Sheue Nee Ling、Kah Hay Yuen、Enrico Magosso 等 4 位作者2009-04-01Journal of Pharmacy and Pharmacology

Abstract Objectives A liposome preparation that is amenable to receptor-mediated endocytosis has been developed to enhance the oral bioavailability of poorly absorbable peptidomi-metic drugs by use of folic acid as the mediator of liposomal uptake. Methods Folic acid was physically coupled to the surface of the liposo…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorMonoclonal and Polyclonal Antibodies Research

Characterization of chromate conversion film on tinplate substrate by XPS and electrochemistry methods

Jie Sun、Guochao Qi、Yong Teck Tan 等 4 位作者2009-04-01Surface and Interface Analysis

Abstract The chromate conversion coating formed on commercial tinplate via a cathode electrolytic dichromate treatment has been studied by X‐ray photoelectron spectroscopy (XPS) and electrochemistry methods. Through the analysis of the XPS, it was shown that there existed Cr, O, and Sn in the chromate coating and the…

Corrosion Behavior and InhibitionMetal Extraction and BioleachingElectrodeposition and Electroless Coatings

Weak ferromagnetism in BiFeO3-based multiferroics

I. O. Troyanchuk、M. V. Bushinsky、А. Н. Чобот 等 5 位作者2009-04-01Journal of Experimental and Theoretical Physics Letters

The magnetic properties of the Bi1 − x Ln x FeO3 (Ln is a rare-earth ion), Bi1 − x A x FeO3 − x/2 (A is an alkali earth ion), and BiFe1 − x Ti x O3 + δ solid solutions in magnetic fields up to 14 T have been studied. The concentration ranges of the existence of the ferroelectric phase described by the space group R3c…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsUnderwater Acoustics Research

Conductance Enhancement Mechanisms of Printable Nanoparticulate Indium Tin Oxide (ITO) Layers for Application in Organic Electronic Devices

Michael J. Gross、Nicolas Linse、Ilja Maksimenko 等 4 位作者2009-04-01Advanced Engineering Materials

We present and discuss several methods to enhance the electrical properties of nanoparticle dispersion derived ITO-layers. A maximum conductance of 132 Ω−1 cm−1 was achieved and films with a sheet resistance down to 5 Ω/□ were produced. To demonstrate their applicability as electrodes in optoelectronic elements we ass…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsThin-Film Transistor Technologies

Thermopower of Co-doped FeSe

Evan L. Thomas、W. Wong‐Ng、Daniel Phelan 等 4 位作者2009-04-01Journal of Applied Physics

The effect of cobalt doping on the thermopower of the superconductor FeSe is investigated through electrical and thermal transport measurements. Our results point to the destruction of superconductivity at very low Co concentrations. Thermopower data suggest negative charge carriers along with a large enhancement of t…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Preparation of copper-doped CdSe nanocrystals

P. N. Tananaev、Sergey G. Dorofeev、Р.Б. Васильев 等 4 位作者2009-04-01Inorganic Materials

Sols of stabilized copper-doped CdSe nanocrystals in a nonpolar high-boiling solvent have been synthesized using cadmium oleate, copper stearate, and trioctylphosphine selenide as starting reagents. The average size of the nanocrystals is 2.8–2.9 nm, with a 10% variance, as evaluated from their absorption spectra. The…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Self-propagating high-temperature synthesis of ceramic materials based on the Mn + 1AX n phases in the Ti-Cr-Al-C system

Е. А. Левашов、Yu. С. Pogozhev、Dmitry V. Shtansky 等 4 位作者2009-04-01Russian Journal of Non-Ferrous Metals

Compact ceramic materials based on the Mn + 1AX n phases in the Ti-Cr-Al-C system are produced by forced self-propagating high-temperature synthesis (SHS) compaction. The mechanisms of the structure and phase formation in synthetic products, as well as the combustion macrokinetics of the SHS mixture, are studied. Comp…

Intermetallics and Advanced Alloy PropertiesMXene and MAX Phase MaterialsAdvanced materials and composites

Structure of glasses and melts in the Na2O-B2O3 system from high-temperature Raman spectroscopic data: I. Influence of temperature on the local structure of glasses and melts

A. А. Osipov、Л. М. Осипова2009-04-01Glass Physics and Chemistry

The local structure of glasses and melts in the Na2O-B2O3 system in the composition range 10–30 mol % Na2O is investigated by high-temperature Raman spectroscopy in the temperature range 20–1150°C. The recorded spectra are analyzed by simulating the experimental spectra in the form of a superposition of the set of Gau…

Glass properties and applicationsMineralogy and Gemology StudiesMaterial Science and Thermodynamics

Metalloporphyrins in the biomimetic oxidative valorization of natural and other organic substrates

Mário M.Q. Simões、Rodrigo De Paula、Maria G. P. M. S. Neves 等 4 位作者2009-04-01Journal of Porphyrins and Phthalocyanines

Cheap and abundant natural products can be transformed into products of higher commercial value. One of the approaches for the functionalization of organic compounds is their oxidation in the presence of an oxygen atom donor, under the influence of a suitable catalyst. Metalloporphyrins, with structures based on the w…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Control of recrystallisation texture and texture-related properties in industrial production of aluminium sheet

Olaf Engler、Jürgen Hirsch2009-04-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract The principles of recrystallisation texture formation upon hot rolling and annealing of industrial aluminium alloy sheets are presented. It is demonstrated how texture control is applied during industrial processing of aluminium sheet so as to improve texture-related properties. This is illustrated by way of…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties