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Combustion synthesis and properties of fine-particle rare-earth-metal zirconates, Ln2Zr2O7

N. Arul Dhas、Kashinath C. Patil1993-01-01Journal of Materials Chemistry

Fine-particle rare-earth-metal zirconates, Ln2Zr2O7, where Ln = La, Ce, Pr, Nd, Sm, Gd and Dy having the pyrochlore structure have been prepared using a novel combustion process. The process employs aqueous solutions of the corresponding rare-earth-metal nitrate, zirconium nitrate and carbohydrazide/urea in the requir…

Advanced Condensed Matter PhysicsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Adsorption sites on polymorphic zirconia

Karl‐Heinz Jacob、Erich Knözinger、Sigrid Benier1993-01-01Journal of Materials Chemistry

Surface models of monoclinic and tetragonal zirconia are presented. They are derived from the respective lattice structures of both modifications. In contrast to previous investigations structural deviations of both phases from the ideal CaF2 structure are taken into account. The existence of trigonally and tetrahedra…

nanoparticles nucleation surface interactionsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Two-step approach towards the accelerated synthesis of dendritic macromolecules

R. Spindler、Jean M. J. Fréchet1993-01-01Journal of the Chemical Society Perkin Transactions 1

The accelerated synthesis of regular dendritic poly (ether-urethane) macromolecules through growth of two generations in a single synthetic operation has been explored. This procedure requires the use of two AB2 monomers such as 3,5-diisocyanatobenzyl chloride and 3.5-dihydroxybenzyl alcohol that can react pairwise in…

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

A calculation method and some features of transient field under polarity reversal voltage in HVDC insulation

Ke Wen、Yao Zhou、Jin Fu 等 4 位作者1993-01-01IEEE Transactions on Power Delivery

Mathematical equations are derived for the transient electric field in insulation media with permittivity and resistivity during boundary excitation due to changing from one steady state to another, such as a polarity reversal voltage imposed on the insulation of HVDC apparatus. The equations are solved by the finite…

High voltage insulation and dielectric phenomenaThermal Analysis in Power TransmissionHigh-Voltage Power Transmission Systems

Stabilization of a cobalt(II) phthalocyanine oxidation catalyst by intercalation in a layered double hydroxide host

Malama Chibwe、Thomas J. Pinnavaia1993-01-01Journal of the Chemical Society Chemical Communications

Cobalt(II) phthatocyaninetetrasulfonate [Co(pcts)]4– intercalated into a MgsAl2.5-layered double hydroxide (LDH) sxhibited greatly enhanced catalytic stability compared to the homogeneous catalyst for the autoxidation of 2,6-di-tert-butylphenol to the corresponding diphenoquine at 35 ± 2 °C; under homogeneous reaction…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry Reactions

Phase Reactions and Chemical Stability of Ceramic Carbide and Solid Lubricant Particulate Additions within Sintered High Speed Steel Matrix

J. D. Bolton、A.J. Gant1993-01-01Powder Metallurgy

Efforts to improve the wear properties of sintered high speed steels have made use of the simultaneous addition of hard ceramic particles (TiC or NbC) alongside particles which might act as a solid lubricant (MnS or CaF 2 ). Preliminary investigations carried out to study interactions between such particles and a sint…

Advanced materials and compositesMetal Alloys Wear and PropertiesPowder Metallurgy Techniques and Materials

Investigation of the tissue equivalence of gells used for NMR dosimetry

Tomas Kron、Peter Metcalfe、J.M. Pope1993-01-01Physics in Medicine and Biology

The transition of Fe2+ to Fe3+ in Fricke solution after irradiation results in a change of NMR proton relaxation times in agarose gels which can be used for the dosimetry of ionizing radiation. The main advantage of this system is the possibility of observing dose distributions in 3 dimensions in a medium which is sup…

Advanced Radiotherapy TechniquesRadiation Dose and ImagingRadiation Shielding Materials Analysis

Structure and degradation of commercial poly(vinyl chloride) obtained at different temperatures

Mikael Rogestedt、Thomas Hjertberg1993-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and degradation of commercial poly(vinyl chloride) obtained at different temperaturesMikael Rogestedt and Thomas HjertbergCite this: Macromolecules 1993, 26, 1, 60–64Publication Date (Print):January 1, 1993Publication History Published online1 May 2002Published ini…

Polymer Science and PVC

Densification of Alkoxide‐Derived Fine Silica Powder Compact by Ultra‐High‐Pressure Cold Isostatic Pressing

Hidehiro Kamiya、Hisao Suzuki、Daisuke Kato 等 4 位作者1993-01-01Journal of the American Ceramic Society

Powder compacts of alkoxide‐derived fine silica powders were consolidated into a highly dense and uniform structure by ultra‐high‐pressure cold isostatic pressing of granules with controlled structure. The diameters of spherical and nearly monosized amorphous silica particles, prepared from metal alkoxide, were succes…

Material Dynamics and PropertiesGlass properties and applicationsMesoporous Materials and Catalysis

Pulse height analysis of partial discharges in air

B. Florkowska、R. Włodek1993-01-01IEEE Transactions on Electrical Insulation

The pulse height distribution (PHD) functions of partial discharges (PDs) generated by AC voltage in air are investigated. The electrode systems used allow the investigation of single-source PDs and/or multiple-source discharges. Because voltage and the electrode configuration alter the PHD functions of even a single…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Phylogenetic analysis of the Rapaninae (Neogastropoda: Muricidae)

Kool, Silvard P1993-01-01Zenodo (CERN European Organization for Nuclear Research)

(Uploaded by Plazi from the Biodiversity Heritage Library) No abstract provided.

Subterranean biodiversity and taxonomyDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Decomposition of Chlorinated Hydrocarbons in Aqueous Solutions by Ultrasonic Irradiation

Koji Inazu、Yoshio Nagata、Yasuaki Maeda1993-01-01Chemistry Letters

Abstract Trichloroethylene, tetrachloroethylene, 1,1,1-trichloroethane, chloroform and carbon tetrachloride in dilute aqueous solutions were rapidly decomposed to chloride anions, hydrogen, carbon monoxide and carbon dioxide by ultrasonic irradiation.

Ultrasound and Cavitation PhenomenaEnvironmental and Industrial SafetyChemical Reactions and Isotopes

High Power Rare Earth Magnetostrictive Materials

Arthur E. Clark1993-01-01Journal of Intelligent Material Systems and Structures

Magnetic materials capable of producing strains greater than 10 -3 have received con siderable attention over the last few years. This is partly due to recent interest in fields such as de formable surfaces, active vibration control, and precision machining, where large forces and small displacements are required, and…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Analysis and design of transparent conductive coatings and filters

Margaret Kohin1993-01-01Optical Engineering

Four types of transparent electrically conductive filters commonly used for a variety of applications are (1) a free-standing conducting inductive mesh, (2) a substrate coated with a conducting inductive mesh, (3) a conducting substrate, and (4) a substrate coated with a continuous conducting coating. Each can be desi…

Semiconductor materials and devicesThin-Film Transistor TechnologiesCopper Interconnects and Reliability

Crystallinity of Partially N -Acetylated Chitosans

Kozo Ogawa、Toshifumi Yui1993-01-01Bioscience Biotechnology and Biochemistry

In order to search for a chitosan with low crystallinity, partially N-deacetylated chitins (PDC) and partially N-acetylated chitosans (PAC) with a low degree of N-acetylation (DAc) were examined by X-ray powder diffraction measurements. Three PDC samples, having less than 30% DAc and prepared by solid-state deacetylat…

Nanocomposite Films for Food PackagingPolydiacetylene-based materials and applications

Mechanism of interfacial interactions in particulate filled composites

Béla Pukánszky、György Vörös1993-01-01Composite Interfaces

A stress analysis was carried out in order to determine the local stress distribution around spherical particles in particulate filled composites. The results were introduced into the criteria for micromechanical deformations and the conditions for the initiation of each mechanism were calculated. Results of the calcu…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Paraelectric and ferroelectric phases of betaine phosphite: Structural, thermodynamic, and dielectric properties

I. Fehst、M. Paasch、S. L. Hutton 等 10 位作者1993-01-01Ferroelectrics

The paraelectric and ferroelectric phases of betaine phosphite [BPI: (CH3)3 NCH2COO H3PO3] single crystals have been studied. The structure of BPI was determined at room temperature using x-ray and elastic neutron diffraction. Details of the ferroelectric transition and various low temperature properties were investig…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

An upgrading process through cavitation and surfactant

Jiunn Ren Lin、Teh Fu Yen1993-01-01Energy & Fuels

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn upgrading process through cavitation and surfactantJiunn Ren Lin and Teh Fu YenCite this: Energy Fuels 1993, 7, 1, 111–118Publication Date (Print):January 1, 1993Publication History Published online1 May 2002Published inissue 1 January 1993https://pubs.acs.org/doi/10.1021…

Ultrasound and Cavitation Phenomena

Estimation of Delayed Fracture Property of Steels

Nobukazu Suzuki、Nobuyuki Ishii、Toshio Miyagawa 等 4 位作者1993-01-01鐵と鋼 : 日本鐡鋼協會々誌

高力ボルトの高強度化の必要性は大きいのであるが,その遅れ破壊はいまだ理論的な解明がなされておらず,その必要十分な予測ができない現状にある。そのために,実験室的に耐遅れ破壊特性の優れた高強度高力ボルトであっても,容易に実用化できない。本研究は,この課題解決のために行ったもので,得た結論の要点は以下のものである。鋼中の微量水素の定量化を可能にし,試験片中の水素量とその遅れ破壊との関連を求め,一定の応力状態(P/Pf=一定)では各鋼材固有の限界水素量HTが存在することを確かめた。この試験で求められる対象鋼材の限界水素量HTは,別途水素モニターによる対象鋼材の使用環境における侵入水素量あるいは侵入の容易さを知ることによって,対象鋼材の実環…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

Evaluation of digital filters for rejecting discrete spectral interference in on-site PD measurements

V. Nagesh、Bharathi Gururaj1993-01-01IEEE Transactions on Electrical Insulation

A critical study of the performance of several digital filters for rejecting discrete spectral interference (DSI) in partial-discharge (PD) testing is reported. The filters are evaluated with particular reference to distortion introduced on successive PD pulses. A digital filtering method based on a cascaded second-or…

High voltage insulation and dielectric phenomenaAdvanced Electrical Measurement TechniquesElectrostatic Discharge in Electronics