Materials Literature
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Organic-inorganic mesoporous materials of the MCM-41 type are important materials that can be prepared by either post-synthesis or one-pot synthesis procedures. A complete control of the characteristics at a local level is of the utmost importance in view of the applications of such materials. However, there are not m…
Since most chemists, biochemists, and chemical engineers are now involved in some phase of polymer science or technology, some have called this the polymer age. Actually, we have always lived in a polymer age. The ancient Greeks classified all matter as animal, vegetable, and mineral. Minerals were emphasized by the a…
Several aspects of half-metallic magnetism at finite temperature are discussed. Since NiMnSb is the simplest half-metal and the longest known it will be used as an example. Also it is a half-metal with remarkable little on-site Coulomb repulsion. Consequently it is a half-metal that is not notably corrupted by non-qua…
Half-metallic ferromagnets are universally believed to be of great importance for a multitude of spintronic applications, including non-volatile logic and memory, spin transistors and many other recently proposed devices. While many materials have been predicted to be half-metallic, experimental confirmation of this e…
A two-variable polynomial invariant of non-oriented doubly periodic structures is proposed. A possible application of this polynomial for the classification of textile structures is suggested.
A large part of statistical mechanics is concerned with the determination of condensed matter structure on the basis of known microscopic interactions. An increasing emphasis has been put on the opposite situation in the last decades as well, where structural data, e.g. pair-distance statistics, are known from diffrac…
The ferromagnetic ground states of the half-Heusler compounds AuMnX (X = In, Sn, Sb) have been calculated in the framework of the local spin-density approximation (LSDA) to density functional theory (DFT). AuMnSn is computed to be a half-metallic ferromagnet, whereas AuMnIn and AuMnSb are not half-metallic, due to the…
In most silicon-oxygen compounds, the silicon atom is 4-fold coordinated. Exceptionally, silicon is found in 6-fold coordination, as in the mineral thaumasite, which also may be formed in the degradation, and sometimes subsequent weakening, of certain concretes. The connection between coordination number and chemical…
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Previous photoelectron spectroscopy studies of CrO2 have found either no density of states or a very low density of states at the Fermi level, suggesting that CrO2 is a semiconductor or a semi-metal. This is in contradiction to calculations that predict that CrO2 should be a half-metallic ferromagnet. Recently, techni…
From the electron energy loss spectroscopy (EELS) study of plasmon excitation of Bi nanorods, we find that as the diameter and length of Bi nanorods decrease below ∼10 and ∼35 nm, respectively, the quantum confinement effect drastically increases. Thus, such Bi nanorods would be extremely useful for thermoelectric dev…
The synthesis and self-assembly behaviour of porphyrin dodecamers 1H(2) and Zn-1, which consist of twelve porphyrins that are covalently attached to a central aromatic core, is described. According to STM, 1D and 2D NMR studies, and molecular modelling calculations, the porphyrin dodecamers have a yo-yo-shaped structu…
ADVERTISEMENT RETURN TO ISSUEPREVNoteMetal-Free Ring-Opening Polymerization of Glycidyl Phenyl Ether by Tetrabutylammonium FluorideHisatoyo Morinaga, Bungo Ochiai, and Takeshi EndoView Author Information Molecular Engineering Institute, Kinki University, 11-6 Kayanomori, Iizuka, Fukuoka 820-8555, Japan, and Department…
Since its introduction by de Groot and colleagues in the early 1980s [1], the concept of half metallic ferromagnetism has attracted great interest. Idealized, half-metals have only one spin channel for conduction: the spin-polarized band structure exhibits metallic behavior for one spin channel, while the other spin b…
Abstract The purpose of this research is to study the synthesis and characterization of stable aqueous dispersions of externally chain extended polyurethane/urea compositions terminated by hydrolyzable or hydrolyzed trialkoxysilane groups incorporated through secondary amino groups. These dispersions with excellent st…
The metallation of the core-modified phthalocyanine analogue dicarbahemiporphyrazine with manganese, iron, and cobalt results in the formation of low-coordinate metal(II) complexes. All three compounds are produced by the reaction of metal carbonyls with the free base macrocycle. As in many other carbaporphyrinoids, t…
A half-metal has been defined as a material with propagating electron states at the Fermi energy only for one of the two possible spin projections, and as such has been promoted as an interesting research direction for spin electronics. This review details recent advances on manganite thin film research within the fie…
The local structure of the low-temperature ordered phase of the negative thermal expansion (NTE) material ZrW(2)O(8) has been investigated by reverse Monte Carlo (RMC) modelling of neutron total scattering data. The local structure is described using the instantaneous distributions of bond lengths and angles obtained…
Low-temperature (23 ≤ T ≤ 150 K) dielectric properties of Pr1−xCaxMnO3 (PCMO) (0.1 ≤ x ≤ 0.9) were investigated systematically.A thermally activated relaxation was found in both charge-ordered and no-charge-ordered samples with localized charge carriers, but it was not detected in samples with free carriers. The diele…
The transition metal (TM) chalcogenides of the form TMX(2) (X = S or Se) have been studied for decades due to their interesting electronic and magnetic properties such as metamagnetism and metal-insulator transitions. In particular, the Co(1-x)Fe(x)S(2) alloys were the subject of investigation in the 1970s due to gene…