Materials Literature
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The reaction of (NO2 )(CF3 SO3 ) and elemental palladium in oleum (65 % SO3 ) leads to violet single crystals of Pd(HS2 O7 )2 (monoclinic, P21 /c, Z=2, a=927.80(9), b=682.58(7), c=920.84(9) pm, β=117.756(2)°, wR2 =0.0439). In the crystal structure, the Pd(2+) ions show an uncommon octahedral coordination of six oxygen…
The synthesis of star-shaped discotic liquid crystal trimers using Co2(CO)8-catalyzed terminal alkyne [2 + 2 + 2] cycloaddition reaction is reported. The trimers consist of three triphenylene discotic units linked to a central 1,2,4-trisubstituted benzene ring via flexible spacers. The trimers were synthesized in the…
A procedure is proposed to prepare electrically conductive epoxy resin composites exploiting in situ reduction of graphene oxide (GOx) during the epoxy thermal curing in presence of amine. The optimum curing conditions are evaluated, and the efficiency of the reduction process of GOx induced by amine is confirmed by X…
Detonation nanodiamond powders produced by different manufacturers were surface modified to reduce the amount of surface impurities and impart to the particles a high colloidal stability in aqueous suspensions. Modified DNDs (MDNDs) were separated into fractions and evaluated by the zeta potential, particles size dist…
Rare-earth stabilized bismuth oxides are known for their excellent ionic conductivity at intermediate temperatures. However, previous studies have shown that their conductivity deteriorates during extended heat treatments at 500-600 °C, although the fluorite phase is maintained. In this study, the enthalpies of format…
Using the first principle methods, we proposed a series of three-chain boron cages B6n+14 (n = 1-12) which are mainly built by fusing three boron semi-double-rings. Their simple geometric structures (approximate D3 or C3 symmetry) facilitate their bottom-up syntheses from the hexagonal B7 and the double-chain boron cl…
The search for efficient inhibitors to mitigate the corrosion of oil-well steels requires more experimental investigations of the performance of ecofriendly nontoxic organic inhibitors. With this objective, the inhibitive action of a selected inhibitor, furfuryl alcohol (FAL), on the corrosion resistance of 13Cr L80 s…
A model is presented that integrates the critical path approximation with percolation theory to describe the dependence of electrical conductivity upon volume fraction in nanofiber-based composites. The theory accounts for clustering and correlation effects that reflect non-randomness in the spatial distribution of th…
A glycosylated polyamine is synthesized using a straightforward route in aqueous solution. An optimum of grafting is obtained when equimolar amounts of gluconolactone and NaOH are added to an aqueous solution of poly(allylamine hydrochloride), PAH. Under these conditions, up to 60% of gluconolactone is grafted onto th…
Shape memory NR/PCL bio-based blends, where NR served as the reversible phase and PCL served as the switching phase, were prepared using a melt blending process. Peroxide, besides its role as a cross-linking agent to NR, was used to enhance the compatibility between NR and PCL, which was confirmed via Fourier transfor…
Amide and ester type polyols were synthesized from different kinds of tall oil and two types of ethanolamine (diethanolamine and triethanolamine). Poly(urethane amides) and polyester urethanes based on the synthesized polyols were prepared. The influence of the chemical structure of the obtained polyurethanes on densi…
A novel approach to enhance the catalytic performances in one-pot hydroxylation of phenol into catechol and hydroquinone was examined using core–shell type catalysts which consist of Pd nanoparticles (NPs) for direct synthesis of H 2 O 2 from H 2 and O 2 and Fe-containing mesoporous silica (Fe-MS) for hydroxylation of…
A comparative study of Raman scattering and low temperature specific heat capacity has been performed on samples of B2O3, which have been high-pressure quenched to go through different glassy phases having growing density to the crystalline state. It has revealed that the excess volume characterizing the glassy networ…
Polypropylene nanocomposites with a different amount of styrene-ethylene-butylene-styrene block copolymer (SEBS)/clay were prepared via a melt mixing technique. To improve the dispersion of commercial organoclay (denoted as OMMT), various amounts of SEBS were incorporated. At a fixed content of OMMT, the mechanical pr…
A systematic characterization of Cu2O nanoclusters using classical electrodynamics and time-dependent density functional theory (TDDFT) is performed to investigate their response to light with the alteration of size and symmetry. Absorption and scattering play a crucial role in tuning the surface plasmon resonance (SP…
This study aimed to investigate the influence of raw material moisture content on the properties of charcoal from fast-growing Eucalyptus benthamii wood. For that, three treatments were performed with 0, 30, and 50% in relation to the wet basis moisture of the wood samples. The carbonization process used an electric k…
Room temperature ferromagnetic ordering has been observed in a rutile TiO 2 polycrystalline sample after 4 MeV Ar 5+ ion irradiation. The sheet resistance of the irradiated sample decreases from 10 7 to 3 × 10 3 Ω cm −2 . Ab initio calculation in the density-functional theory indicates that both oxygen vacancy (V O )…
The crystal-liquid interfacial free energy γ has been calculated as a function of the crystal orientation in a molecular dynamics experiment in a system of Lennard-Jones (LJ) particles with a cutoff radius of the potential rc(*)=rc/σ=6.78 at a triple-point temperature Tt(*)=kBTt/ε=0.692 and temperatures above (in the…
Directed self-assembly of a block copolymer is successfully employed to fabricate device-oriented graphene nanostructures from CVD grown graphene. We implemented mussel-inspired polydopamine adhesive in conjunction with the graphoepitaxy principle to tailor graphene nanoribbon arrays and a graphene nanomesh located be…
Derivatives of thymine have been extensively used to promote supramolecular materials assembly. Such derivatives can be synthetically challenging to access and may be susceptible to degradation. The current article uses a conformer-independent acceptor-donor-acceptor array (ureidopyrimidine) which forms moderate affin…