Materials Literature
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We predict the existence of a three-dimensional quantum Hall effect plateau in a graphite crystal subject to a magnetic field. The plateau has a Hall conductivity quantized at 4e2/variant Planck's over 2pi 1/c0 with c0 the c-axis lattice constant. We analyze the three-dimensional Hofstadter problem of a realistic tigh…
In this Brief Report, we report on the observation of a giant positive (inverse) magnetic entropy change (about $28.6\phantom{\rule{0.3em}{0ex}}\mathrm{J}\phantom{\rule{0.2em}{0ex}}{\mathrm{K}}^{\ensuremath{-}1}\phantom{\rule{0.2em}{0ex}}{\mathrm{kg}}^{\ensuremath{-}1}$ at $5\phantom{\rule{0.3em}{0ex}}\mathrm{T}$ magn…
We report a facile method to synthesize poly(3,4-ethylenedioxythiophene) (PEDOT) films at room temperature in a waterproof ionic liquid, 1-ethyl-3-methylimidazolium bis(perfluoroethylsulfonyl)imide (EMIPFSI), by electropolymerization. The ionic liquid leads to the formation of randomly oriented nanofibers and particle…
The mathematical background, based on a variation of the principal component analysis (PCA) method, is developed for the understanding of fluctuating multiple analyte single-molecule (SM) surface enhanced Raman scattering (SERS) signals; with emphasis on the bianalyte SERS technique developed recently. The method and…
Blends of poly(vinylidene fluoride)/nylon-6 (PVDF/N6) 30:70 were melt compounded with various organoclays directly or sequentially. The morphology, thermal, and mechanical properties of the blend nanocomposites were investigated. It was determined that the degree of compatibilization induced by the nanoclay particles…
A novel approach has been developed to calculate the temperature dependence of the optical response of a semiconductor. The dielectric function is averaged over several thermally perturbed configurations that are extracted from molecular dynamic simulations. The calculated temperature dependence of the imaginary part…
Nuclear polarization dynamics are measured in the nuclear spin bi-stability regime in a single optically pumped InGaAs/GaAs quantum dot. The controlling role of nuclear spin diffusion from the dot into the surrounding material is revealed in pump-probe measurements of the non-linear nuclear spin dynamics. We measure n…
Blackman's diagram of two dimensionless ratios of elastic constants is frequently used to correlate elastic properties of cubic crystals with interatomic bondings. Every's diagram of a different set of two dimensionless variables was used by us for classification of various properties of such crystals. We compare thes…
At zero magnetic field, a series of five phase transitions occur in Co3V2O8. The Neel temperature, TN=11.4 K, is followed by four additional phase changes at T1=8.9 K, T2=7.0 K, T3=6.9 K, and T4=6.2 K. The different phases are distinguished by the commensurability of the b-component of its spin density wave vector. We…
Solid State Nuclear Magnetic Resonance (NMR) experiments allow characterizing the local structure and dynamics of oxide glasses and melts. Thanks to the development of new experiments, it now becomes possible to evidence not only the details of the coordination state of the network formers of glasses but also to chara…
Here we present evidence for an oxidation-driven structural conversion of quasi-alloy PdAu dendrimer-encapsulated nanoparticles (DENs) to a Au-core/Pd-shell configuration. The initial quasialloy was prepared by co-complexation of PdCl 4 2− and AuCl 4 − within a sixth-generation, poly(amidoamine) dendrimer template fol…
Abstract Fluorescent microspheres are widely used as biological tracers. In this study, uniformly sized chitosan microspheres crosslinked with glutaraldehyde (CG microspheres) and formaldehyde (CF microspheres) are successfully prepared by the Shirasu Porous Glass (SPG) membrane emulsification technique. Selectively r…
A systematic study of the role of KCl on the electrodeposition of ZnO nanowire arrays from the reduction of oxygen in ZnCl 2 solutions was performed. Besides its role as a supporting electrolyte, other major effects were found. An increase of KCl concentration ([KCl]) considerably decreased the rate of O 2 reduction.…
The elastic properties of boron nitride nanotubes have been calculated using the Tersoff–Brenner potential which is a bond order potential used successfully previously for carbon nanotubes. In the present calculation, the same form of potential is used with adjusted parameters for hexagonal boron nitride. The Young's…
We propose a set of thermodynamic guidelines aimed at facilitating more robust screening of hydrogen-storage reactions. The utility of the guidelines is illustrated by reassessing the validity of reactions recently proposed in the literature and through vetting a list of more than 20 candidate reactions based on desta…
We derive an expression for the 4-point conductance of a general quantum junction in terms of the density response function. Our formulation allows us to show that the 4-point conductance of an interacting electronic system possessing either a geometrical constriction and/or an opaque barrier becomes identical to the…
We present a new high-resolution angle-resolved photoemission study of 1T-TiSe2 in both its room-temperature, normal phase and its low-temperature, charge-density wave phase. At low temperature the photoemission spectra are strongly modified, with large band renormalizations at high-symmetry points of the Brillouin zo…
We present a first principle, theoretical study of MoS 2 nanoparticles that provides a unified explanation of measured photoluminescence spectra and recent STM measurements as a function of size. In addition, our calculations suggest ways to engineer the electronic properties of these systems so as to obtain direct ba…
Nanoscale building blocks are individually exceptionally strong because they are close to ideal, defect-free materials. It is, however, difficult to retain the ideal properties in macroscale composites. Bottom-up assembly of a clay/polymer nanocomposite allowed for the preparation of a homogeneous, optically transpare…
We have performed a comprehensive first-principles investigation of native point defects in ZnO based on density functional theory within the local density approximation (LDA) as well as the $\mathrm{LDA}+U$ approach for overcoming the band-gap problem. Oxygen deficiency, manifested in the form of oxygen vacancies and…