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Photoelectrochemical and photosensing behaviors of hydrothermally grown ZnO nanorods

Tanmoy Majumder、Jehova Jire L. Hmar、Kamalesh Debnath 等 7 位作者2014-07-21Journal of Applied Physics

ZnO nanorods have been grown on indium-tin-oxide coated glass substrates by a low cost chemical process. Current-voltage characteristics have been studied using ZnO nanorods as photoanode in an electrochemical cell. The flat band voltage shift and depletion width of ZnO nanorods/electrolyte interface have been estimat…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Transferrin surface-modified PLGA nanoparticles-mediated delivery of a proteasome inhibitor to human pancreatic cancer cells

Manuela F. Frasco、Gabriela M. Almeida、Filipe Santos‐Silva 等 5 位作者2014-07-21Journal of Biomedical Materials Research Part A

The aim of this study was to develop a drug delivery system based on poly(lactic-co-glycolic acid) (PLGA) nanoparticles for an efficient and targeted action of the proteasome inhibitor bortezomib against pancreatic cancer cells. The PLGA nanoparticles were formulated with a poloxamer, and further surface-modified with…

Nanoparticle-Based Drug DeliveryUbiquitin and proteasome pathwaysGraphene and Nanomaterials Applications

Electric toroidal metamaterial for resonant transparency and circular cross-polarization conversion

Linyan Guo、Minhua Li、Xiaojun Huang 等 4 位作者2014-07-21Applied Physics Letters

Electric toroidal dipolar response has been achieved by metamaterial based on sun-like aperture element at microwave frequency. It is confirmed numerically by scattered powers that the electric toroidal dipolar moment dominates over other moments at the corresponding resonance. This proposed metamaterial exhibits reso…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Organic light emitting diodes with environmentally and thermally stable doped graphene electrodes

Arun Kuruvila、Piran R. Kidambi、Jens Kling 等 7 位作者2014-07-21Journal of Materials Chemistry C

We present a comparative study of the environmental and thermal stability of graphene charge transfer doping using molybdenum–trioxide (MoO3), vanadium–pentoxide (V2O5) and tungsten–trioxide (WO3). Our results show that all these metal oxides allow a strong and stable p-type doping of graphene, as well as functioning…

Graphene research and applicationsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Directing Vascular Cell Selectivity and Hemocompatibility on Patterned Platforms Featuring Variable Topographic Geometry and Size

Yonghui Ding、Zhilu Yang、Cathy W.C. Bi 等 9 位作者2014-07-21ACS Applied Materials & Interfaces

It is great challenge to generate multifunctionality of vascular grafts and stents to enable vascular cell selectivity and improve hemocompatibility. Micro/nanopatterning of vascular implant surfaces for such multifunctionality is a direction to be explored. We developed a novel patterned platform featuring two typica…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesAdvanced Materials and Mechanics

Physical Aging, the Local Dynamics of Glass-Forming Polymers under Nanoscale Confinement

Amit Shavit、Robert A. Riggleman2014-07-21The Journal of Physical Chemistry B

The glass transition temperature marks a point below which a material's properties change significantly, and it is well-established that confinement to the nanoscale modifies the properties of glass-forming materials. We use molecular dynamics simulations to investigate the dynamics and aging behavior of model glass-f…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesGlass properties and applications

Energy conservation by oxidation of formate to carbon dioxide and hydrogen via a sodium ion current in a hyperthermophilic archaeon

Jae Kyu Lim、Florian Mayer、Sung Gyun Kang 等 4 位作者2014-07-21Proceedings of the National Academy of Sciences

Thermococcus onnurineus NA1 is known to grow by the anaerobic oxidation of formate to CO2 and H2, a reaction that operates near thermodynamic equilibrium. Here we demonstrate that this reaction is coupled to ATP synthesis by a transmembrane ion current. Formate oxidation leads to H(+) translocation across the cytoplas…

Hydrogen Storage and MaterialsMicrobial Fuel Cells and BioremediationMetalloenzymes and iron-sulfur proteins

Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section

Jonas A. Sellberg、Sarp Kaya、Vegard H. Segtnan 等 9 位作者2014-07-21The Journal of Chemical Physics

The effect of crystal growth conditions on the O K-edge x-ray absorption spectra of ice is investigated through detailed analysis of the spectral features. The amount of ice defects is found to be minimized on hydrophobic surfaces, such as BaF2(111), with low concentration of nucleation centers. This is manifested thr…

Advanced Chemical Physics StudiesMaterial Dynamics and PropertiesAtmospheric Ozone and Climate

Preparation of functionalized porous nano-γ-Al2O3 powders employing colophony extract

Ángela B. Sifontes、Brenda Gutiérrez、Andrea Lo Monaco 等 9 位作者2014-07-21Biotechnology Reports

This study reports the synthesis of porous nano alumina employing carboxylato-alumoxanes [Al(O)x(OH)y(O2CR)z]n as precursors for controlling the pore size, pore size distribution and porosity of the alumina, using a new process ecofriendly. The carboxylato-alumoxanes was prepared by the reaction of boehmite with carbo…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisAerogels and thermal insulation

Removal of Azo Dyes: Intercalation into Sonochemically Synthesized NiAl Layered Double Hydroxide

Madhavi N. Pahalagedara、Milinda Samaraweera、Saminda Dharmarathna 等 7 位作者2014-07-21The Journal of Physical Chemistry C

A sonochemical method was employed in the synthesis of nickel aluminum layered double hydroxides (NiAl-LDH) and the materials were used as adsorbents for the removal of the reactive azo dye, Remazol Brilliant Violet (RBV-5r). The experimental data obtained for microstructure were compared and both the arrangement and…

Adsorption and biosorption for pollutant removalLayered Double Hydroxides Synthesis and ApplicationsNanomaterials for catalytic reactions

Polymer-Grafted Lignin Surfactants Prepared via Reversible Addition–Fragmentation Chain-Transfer Polymerization

Chetali Gupta、Newell R. Washburn2014-07-21Langmuir

Kraft lignin grafted with hydrophilic polymers has been prepared using reversible addition-fragmentation chain-transfer (RAFT) polymerization and investigated for use as a surfactant. In this preliminary study, polyacrylamide and poly(acrylic acid) were grafted from a lignin RAFT macroinitiator at average initiator si…

Fermentation and Sensory AnalysisLignin and Wood ChemistryPickering emulsions and particle stabilization

High carrier mobility in ultrapure diamond measured by time-resolved cyclotron resonance

Ikuko Akimoto、Yushi Handa、Katsuyuki Fukai 等 4 位作者2014-07-21Applied Physics Letters

We have performed time-resolved cyclotron resonance measurements in ultrapure diamond crystals for the temperature range of T=7.3–40 K and obtained the temperature-dependent momentum relaxation times based on the cyclotron resonance widths for optically generated electrons and holes. The relaxation time follows a T−3/…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchAdvancements in Semiconductor Devices and Circuit Design

Volcano-like Behavior of Au-Pd Core-shell Nanoparticles in the Selective Oxidation of Alcohols

Tiago A. G. Silva、Érico Teixeira‐Neto、Núria López 等 4 位作者2014-07-21Scientific Reports

Gold-palladium (AuPd) nanoparticles have shown significantly enhanced activity relative to monometallic Au and Pd catalysts. Knowledge of composition and metal domain distributions is crucial to understanding activity and selectivity, but these parameters are difficult to ascertain in catalytic experiments that have p…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Reentrant spin-glass state and magnetodielectric effect in the spiral magnetBiMnFe2O6

Somnath Ghara、Byung‐Gu Jeon、Kyongjun Yoo 等 5 位作者2014-07-21Physical Review B

The complex oxide $\mathrm{Bi}\mathrm{Mn}{\mathrm{Fe}}_{2}{\mathrm{O}}_{6}$ crystallizing in a centrosymmetric orthorhombic structure ($Pbcm$) is known to exhibit a spiral antiferromagnetic ordering at ${T}_{N}\ensuremath{\sim}212$ K and an anomaly in magnetization at low temperature (${T}_{P}\ensuremath{\sim}34$ K).…

Multiferroics and related materialsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Tuning of optical bandgap and magnetization of CoFe2O4 thin films

Deepanshu Sharma、Neeraj Khare2014-07-21Applied Physics Letters

Single phase CoFe2O4 thin films are deposited on quartz substrates at 400 °C using ultrasonic assisted chemical vapor deposition, and the tuning of optical bandgap and saturation magnetization of films is demonstrated by varying the post deposition annealing temperature. The optical band gap varies from 1.58 to 1.41 e…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Competition between Molecular Adsorption and Diffusion: Dramatic Consequences for SERS in Colloidal Solutions

Brendan L. Darby、Eric C. Le Ru2014-07-21Journal of the American Chemical Society

This study highlights a crucial but often overlooked consideration during sample preparation involving surface-adsorbing species: the competition between analyte adsorption and analyte diffusion/mixing strongly affects the distribution of analytes throughout the sample. In cases of fast analyte adsorption, we argue th…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchElectrochemical Analysis and Applications

A polarization-independent broadband terahertz absorber

Cheng Shi、Xiaofei Zang、YiQiao Wang 等 6 位作者2014-07-21Applied Physics Letters

A highly efficient broadband terahertz absorber is designed, fabricated, and experimentally as well as theoretically evaluated. The absorber comprises a heavily doped silicon substrate and a well-designed two-dimensional grating. Due to the destructive interference of waves and diffraction, the absorber can achieve ov…

Metamaterials and Metasurfaces ApplicationsTerahertz technology and applicationsSuperconducting and THz Device Technology

Revealing Carbon Nanodots As Coreactants of the Anodic Electrochemiluminescence of Ru(bpy)32+

Yanmin Long、Lei Bao、Jingya Zhao 等 5 位作者2014-07-21Analytical Chemistry

Recently, research on carbon nanodots (C-dots), a new type of luminescent nanoparticles with superior optical properties, biocompatibility, and low cost, has been focused on exploring novel properties and structure-related mechanisms to extend their scope. Herein, electrochemiluminescence, a surface-sensitive tool, is…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Preventing Corona Effects: Multiphosphonic Acid Poly(ethylene glycol) Copolymers for Stable Stealth Iron Oxide Nanoparticles

V. Torrisi、A. Graillot、L. Vitorazi 等 7 位作者2014-07-21Biomacromolecules

When dispersed in biological fluids, engineered nanoparticles are selectively coated with proteins, resulting in the formation of a protein corona. It is suggested that the protein corona is critical in regulating the conditions of entry into the cytoplasm of living cells. Recent reports describe this phenomenon as ub…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesDiatoms and Algae Research

Trajectory-dependent energy loss for swift He atoms axially scattered off a silver surface

C. A. Ríos Rubiano、G. A. Bocan、J. I. Juaristi 等 4 位作者2014-07-21arXiv

Angle- and energy-loss- resolved distributions of helium atoms grazingly scattered from a Ag(110) surface along low indexed crystallographic directions are investigated considering impact energies in the few keV range. Final projectile distributions are evaluated within a semi-classical formalism that includes dissipa…

Materials Science