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Bernal’s road to random packing and the structure of liquids

John Finney2013-02-22The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Until the 1960s, liquids were generally regarded as either dense gases or disordered solids, and theoretical attempts at understanding their structures and properties were largely based on those concepts. Bernal, himself a crystallographer, was unhappy with either approach, preferring to regard simple liquids as ‘homo…

Material Dynamics and PropertiesTheoretical and Computational Physics

Electron backscatter diffraction investigation of local misorientations and orientation gradients in connection with evolution of grain boundary structures in deformed and annealed zirconium. A new approach in grain boundary analysis

Mariusz Jędrychowski、Jacek Tarasiuk、Brigitte Bacroix 等 4 位作者2013-02-22Journal of Applied Crystallography

The main aim of the present work is to study the relation between microstructural features – such as local misorientations, grain orientation gradients and grain boundary structures – and thermomechanical treatment of hexagonal zirconium (Zr702α). Electron backscatter diffraction (EBSD) topological maps are used to an…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

Competing structural phase transition scenarios in the giant tetragonality ferroelectric BiFeO3-PbTiO3: Isostructural vs multiphase transition

V. Kothai、Anatoliy Senyshyn、Rajeev Ranjan2013-02-22Journal of Applied Physics

A systematic x-ray and neutron powder diffraction study of the giant tetragonality multiferroic (1−x) BiFeO3-(x) PbTiO3 have revealed that the compositions close to the morphotropic phase boundary present two different structural phase transition scenarios on cooling from the cubic phase: (i) cubic → tetragonal (T2) +…

Ferroelectric and Piezoelectric MaterialsNumerical methods in engineeringMultiferroics and related materials

Low-loss NiCuZn ferrite with matching permeability and permittivity by two-step sintering process

Hua Su、Xiaoli Tang、Huaiwu Zhang 等 6 位作者2013-02-22Journal of Applied Physics

Magneto-dielectric materials with matched permeability and permittivity are promising candidates as loading materials to reduce the physical dimensions of low-frequency antennas. In this study, NiCuZn ferrites were prepared by both the traditional final-stage sintering process and the two-step sintering process to obt…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsFull-Duplex Wireless Communications

Luminescence properties of lutetium based red-emitting phosphor NaLu(WO_4)_2:Eu^3+

Zijun Wang、Jiuping Zhong、H. Liang 等 4 位作者2013-02-22Optical Materials Express

The compounds containing lutetium and tungsten atoms have large effective atomic number (Zeff) and high stopping ability for high energy radiation because both lutetium and tungsten atoms are heavy with large atomic number. In order to obtain a new red-emitting phosphor with high efficiency for X-ray detection, the tr…

Luminescence Properties of Advanced MaterialsCatalysis and Oxidation ReactionsSolid-state spectroscopy and crystallography

In Situ Raman Studies of Electrically Reduced Graphene Oxide and Its Field-Emission Properties

Satyaprakash Sahoo、Geetika Khurana、Sujit K. Barik 等 6 位作者2013-02-22The Journal of Physical Chemistry C

Electric-field-dependent in situ Raman studies have been carried out on chemically prepared graphene oxide. The Raman spectra show significant changes with increase in the applied electric field; in particular, the intensity of the G peak decreases with electric field. This behavior is typical for chemically or therma…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced Memory and Neural Computing

Development of sulphated and naphthylsulphonated carbosilane dendrimers as topical microbicides to prevent HIV-1 sexual transmission

Enrique Vacas Córdoba、Eduardo Arnáiz、Miguel Relloso 等 10 位作者2013-02-22AIDS

OBJECTIVES: For the last 20 years, the idea of alternative prevention strategies based on the use of topical vaginally products to inhibit HIV-1 infection in women has been established. The concept of a 'microbicide' product has been born out of the unavailability of a vaccine against HIV-1 and the problems of women i…

Polymer Surface Interaction StudiesDendrimers and Hyperbranched PolymersAntimicrobial agents and applications

Y-Shaped mPEG-PLA Cabazitaxel Conjugates: Well-Controlled Synthesis by Organocatalytic Approach and Self-Assembly into Interface Drug-Loaded Core–Corona Nanoparticles

Fethi Bensaid、Olivier Thillaye Du Boullay、Abderrahmane Amgoune 等 10 位作者2013-02-22Biomacromolecules

A well-defined poly(ethylene glycol) methyl ether-b-poly(lactic acid) copolymer (mPEG-PLA) featuring a new, Y-shaped, architecture with a hydroxyl functional group between the two blocks has been prepared and thoroughly characterized. The functional copolymer was then readily coupled to diglycolyl-cabazitaxel. The res…

Nanoparticle-Based Drug Deliverybiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

Organo-Modified Hydrotalcite-Quantum Dot Nanocomposites as a Novel Chemiluminescence Resonance Energy Transfer Probe

Shichao Dong、Fang Liu、Chao Lu2013-02-22Analytical Chemistry

In this work, we fabricate an oriented luminescent quantum dot (QD)-layered double hydroxide (LDH) nanocomposite material by the highly orderly and alternate assembly of trace CdTe QDs in dodecylbenzene sulfonate bilayer bunches on the organo-modified LDH exterior surfaces. Interestingly, the novel QD-LDH nanocomposit…

Luminescence Properties of Advanced MaterialsMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Self-Assembled via Metal–Ligand Coordination AzaBODIPY–Zinc Phthalocyanine and AzaBODIPY–Zinc Naphthalocyanine Conjugates: Synthesis, Structure, and Photoinduced Electron Transfer

Venugopal Bandi、Mohamed E. El‐Khouly、Vladimir N. Nesterov 等 6 位作者2013-02-22The Journal of Physical Chemistry C

Using near-IR emitting photosensitizers, viz., zinc phthalocyanine (ZnPc), zinc naphthalocyanine (ZnNc), and BF 2 -chelated azadipyrromethene (azaBODIPY), donor–acceptor conjugates have been newly formed using the well-known metal–ligand axial coordination approach. To accomplish this task, the electron-deficient azaB…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Carboxymethyl Cellulose Produced at Different Mercerization Conditions and Characterized by NIR FT Raman Spectroscopy in Combination with Multivariate Analytical Methods

Heléne Almlöf Ambjörnsson、Karla Schenzel、Ulf Germgård2013-02-22BioResources

Carboxymethyl cellulose (CMC) is produced commercially in a two-stage process consisting of a mercerization stage followed by an etherification stage. In this work, extended mercerization stages were used when producing CMC from a spruce dissolving pulp. Near infra-red (NIR) Fourier transform (FT) Raman spectroscopy w…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Nanocapsules with specific targeting and release properties using miniemulsion polymerization

Katharina Landfester、Volker Mailänder2013-02-22Expert Opinion on Drug Delivery

INTRODUCTION: The field of application for nanosized materials ranges from mere technical purposes to a growing field of applications in biomedicine. Among the different techniques and processes to produce these materials for encapsulation of reporter molecules and drugs, the miniemulsion process has been proven to be…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationSurfactants and Colloidal Systems

Different biokinetics of nanomedicines linking to their toxicity; an overview

Sara Mostafalou、Hamidreza Mohammadi、Ali Ramazani 等 4 位作者2013-02-22DARU Journal of Pharmaceutical Sciences

In spite of the extreme rise to the knowledge of nanotechnology in pharmaceutical sciences, there are currently limited experimental works studying the interactions between nanoparticles (NPs) and the biological system. Adjustment of size and surface area plays the main role in the reaction between NPs and cells leadi…

Nanoparticles: synthesis and applicationsInhalation and Respiratory Drug DeliveryNanotechnology research and applications

Stress Corrosion Cracking of Current Structural Materials in Commercial Nuclear Power Plants

Peter L. Andresen2013-02-22CORROSION

This paper summarizes the structural materials used in light water reactors (LWR), their historical degradation evolution vs. time, improvements and subsequent vulnerabilities discovered, and possible future degradation phenomena over long-term operation. Little was known about high-temperature water environments 50+…

Nuclear reactor physics and engineeringHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

An updated metabolic view of the Bacillus subtilis 168 genome

Eugeni Belda、Agnieszka Sekowska、François Le Fèvre 等 9 位作者2013-02-22Microbiology

Continuous updating of the genome sequence of Bacillus subtilis, the model of the Firmicutes, is a basic requirement needed by the biology community. In this work new genomic objects have been included (toxin/antitoxin genes and small RNA genes) and the metabolic network has been entirely updated. The curated view of…

Microbial Metabolic Engineering and BioproductionEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Nucleation Kinetics of Lithium Metasilicate in Z r O 2 ‐Bearing Lithium Disilicate Glasses for Dental Application

S. Krüger、Joachim Deubener、Christian Ritzberger 等 4 位作者2013-02-22International Journal of Applied Glass Science

The effect of Z r O 2 on the nucleation of lithium metasilicate crystals in lithium disilicate‐based multicomponent glasses of composition in wt% x Z r O 2 + (1 − ( x /100)) (73.82 S i O 2 + 3.99 K 2 O + 15.33 L i 2 O + 3.51 A l 2 O 3 + 3.35 P 2 O 5 ) with x = 0, 3, 4, 6, 8, and 12 was studied by combining the results…

Material Dynamics and PropertiesGlass properties and applicationsPigment Synthesis and Properties

Splitting of the Zero-Energy Landau Level and Universal Dissipative Conductivity at Critical Points in Disordered Graphene

Frank Ortmann、Stephan Roche2013-02-22Physical Review Letters

We report on robust features of the longitudinal conductivity (σ(xx)) of the graphene zero-energy Landau level in the presence of disorder and varying magnetic fields. By mixing an Anderson disorder potential with a low density of sublattice impurities, the transition from metallic to insulating states is theoreticall…

Graphene research and applicationsLow-power high-performance VLSI designQuantum and electron transport phenomena

Design of ultrathin plasmonic quarter-wave plate based on period coupling

Biao Yang、Weimin Ye、Xiaodong Yuan 等 5 位作者2013-02-22Optics Letters

Based on an analysis of the surface admittance of a plasmonic film with a substrate, we propose an ultrathin quarter-wave plate consisting of a periodic plane array of symmetrical L-shaped plasmonic antennas. The period, which determines the coupling among L-shaped antennas, is an important parameter for optimizing th…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

Effect of both protective and reducing agents in the synthesis of multicolor silver nanoparticles

Pedro J. Rivero、Javier Goicoechea、Aitor Urrutia 等 4 位作者2013-02-22Nanoscale Research Letters

In this paper, the influence of variable molar ratios between reducing and loading agents (1:100, 1:50, 1:20, 1:10, 1:5, 1:2, 1:1, 2:1) and between protective and loading agents (0.3:1, 0.75:1, 1.5:1, 3:1, 7.5:1, 30:1, 75:1) in the synthesis of silver nanoparticles by chemical reduction has been evaluated to obtain mu…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles

Multistimuli-Responsive Luminescent Material Reversible Switching Colors via Temperature and Mechanical Force

Xiao-Chen Shan、Huabin Zhang、Lian Chen 等 6 位作者2013-02-22Crystal Growth & Design

A new multistimuli-responsive luminescent material, [Cu 8 I 8 (4-dpda) 6 ] n ( 1 ) (4-dpda=4-(diphenylphosphino)- N,N -dimethylaniline), has been obtained by combining inorganic Cu 8 I 8 clusters and organic ligands 4-dpda, providing a novel in-/organic hybrid approach as an interesting alternative to all-organic appr…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsNanocluster Synthesis and Applications