Materials Literature
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An operation range of the figure of merit (FoM) that reflects the trade-off between Q factor and resonance intensity of the Fano resonance is provided. The structural asymmetry parameter α = (l1 − l2)/(l1 + l2) × 100% in the resonator determines the FoM that has an optimized band of operation for asymmetry ranging fro…
Bright, long-lived emission from first-row transition-metal complexes is very challenging to achieve. Herein, we present a new strategy relying on the rational tuning of energy levels. With the aid of the large N-Cr-N bite angle of the tridentate ligand ddpd (N,N'-dimethyl-N,N'-dipyridine-2-ylpyridine-2,6-diamine) and…
The dispersion state or degree of agglomeration of graphene is known to have a significant influence on the percolation threshold and electrical conductivity of graphene-based polymer nanocomposites. In addition, an imperfectly conducting interface and tunneling-assisted interfacial conductivity can also affect the ov…
AIM: To investigate the size-dependent lymphatic uptake of nanoparticles in mice with rapidly growing syngeneic tumors. MATERIALS & METHODS: Mice were inoculated subcutaneously with EL4 lymphoma cells and on day 5 or day 6 of tumor growth, injected peritumorally with either 29 nm or 58 nm of ultra-small superparamagne…
Abstract The study focused on the material behavior of two commercial polylactide grades affected by structural changes due to exposure to humid environment. Additionally, the impact of temperature and environment humidity on the moisture uptake and drying process of polymer granulate was examined to evaluate the nece…
In this second paper, we introduce a chemical kinetic model that investigates the dynamics of the experimental Ni(2+)/NH3-OH(-) Liesegang system characterized by a pattern of β-nickel hydroxide bands led by a growing pulse of α-nickel hydroxide. The model is based on a system of reaction-diffusion equations describing…
Abstract Chain architecture is an influential parameter in melt processing of polymeric material. In this study effect of different chain structures on polylactide (PLA) film blowing process and on the final film properties was investigated. Blends of linear PLA with three branched poly(L-lactide)s with 4-arms star sh…
In the present work, we have reported a simple approach for the functionalization of single-walled carbon nano-horns by using acids at room temperature conditions. Interaction of acid molecules with the horn was examined by Raman spectroscopy. It was observed that the up-shifting of D and G Raman bands due to intercal…
Three different amyloid targeting ligands, previously shown to exhibit amyloid specific properties, have been used to develop amyloid -targeted nanoliposomes (AT-NLs. For this a MAb against Aβ-peptides (Aβ-MAb (immobilized on NLs at 0.015 and 0.05 mol %, and two different curcumin-lipid derivatives were attached to th…
Abstract To improve the impact resistance and reduce the product cost, poly(lactic acid) (PLA) blends containing varying mass fraction of waste rubber powder (WRP) were fabricated via melt compounding. The effects of WRP contents on the mechanical properties, morphologies and thermal stabilities of PLA/WRP blends were…
Highly regular step and terrace structures have been produced on surfaces of single crystalline MgO, miscut from the low‐index (001) plane, upon annealing in air. Here, the evolution of the surface morphology of such surfaces is investigated. We demonstrate that the periodicity of these structures can be widely tuned…
Poly(succinimide) (PSI) is a polymer of aspartic acid with interesting properties and numerous possible uses. Application areas include agriculture, cleaning agents, metallurgy, the building industry, wastewater treatment, medicine, pharmaceuticals, bioengineering, and many more. Therefore, the particular structure an…
Neutron absorbers are elements with a high neutron capture cross section that are employed at nuclear reactors to control excess fuel reactivity. If these absorbers are converted into materials of relatively low absorption cross section as the result of neutron absorption, they consume during the reactor core life and…
A model for predicting supersaturation, crystal growth rate, crystal size distribution, and aspect ratio is presented. The model applies to isothermal anti‐solvent crystallization where crystal growth is the dominant phenomena and for systems where crystal habit can be characterized by two‐dimensional variables. A par…
In this paper, the amorphous carbon‐based coatings containing F and Si (a‐C:F:Si) are successfully fabricated using a plane hollow cathode plasma‐enhanced chemical vapor deposition method. The results show that the mechanical properties of these coatings, such as hardness, elastic modulus, friction and wear, are close…
Upconversion (UC) emission spectra of Y2O3:Er3+ (3 mol. %), Gd3+ (0, 10, 20, and 40 mol. %) microcrystals were studied under 1.55 μm excitation. Ultraviolet (UV) UC from the L15/22, H9/22, D1/24, D3/24, D7/24, D5/24, D5/22, P1/22, P3/22, G11/24, and G9/22 levels in Er3+ and from the D1/26 and P7/2…
The growth morphology and structure of ceria nano-islands on a stepped Au(788) surface has been investigated by scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED). Within the concept of physical vapor deposition, different kinetic routes have been employed to design ceria-Au inverse model c…
This article presents synthesis, photophysical, electrochemical, thermal, and morphological properties of the crosslinked polyurethanes (CLPUs). CLPUs were synthesized in two main steps. In the first step, aldehyde functionalized polyurethane prepolymer was synthesized using 2,4-dihydroxy benzaldehyde and hexamethylen…
Three sterically-enhanced 2-imino-6-(1-naphthyl)pyridines, 2-{CMe=N(Ar)}-6-(1-C10H7)C5H3N [Ar = 2,6-i-Pr2C6H3 (L1dipp), 2,4,6-i-Pr3C6H2 (L1tripp), 4-Br-2,6-i-Pr2C6H2 (L1Brdipp)], differing only in the electronic properties of the N-aryl group, have been prepared in high yield by the condensation reaction of 2-{CMe=O}-…
A simple procedure, which enables accurate measurement of transmission electron microscopy (TEM)/STEM probe currents using an energy loss spectrometer drift tube is described. The currents obtained are compared with those measured on the fluorescent screen to enable the losses due to secondary and backscattered electr…