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High-temperature electrical transport behaviors of the layered Ca2Co2O5-based ceramics

Jinle Lan、Yuan‐Hua Lin、Guojing Li 等 7 位作者2010-05-10Applied Physics Letters

Textured Bi-substituted Ca2Co2O5 ceramics have been prepared using a coprecipitation method combined with spark plasma sintering. The Bi substitution is effective in increasing the grain orientation of the Ca2Co2O5-based ceramics (from 0.46 to 0.85). Electrical conductivity increases obviously with partial substitutio…

Advanced Thermoelectric Materials and DevicesAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Interface effect on the photocurrent: A comparative study on Pt sandwiched (Bi3.7Nd0.3)Ti3O12 and Pb(Zr0.2Ti0.8)O3 films

Dawei Cao、Jie Xu、Liang Fang 等 6 位作者2010-05-10Applied Physics Letters

We investigated and compared the photoelectric behavior of the Pt sandwiched (Bi3.7Nd0.3)Ti3O12 (BNT) and Pb(Zr0.2Ti0.8)O3 (PZT) films deposited by sol-gel method. Based on the analysis of the photocurrent and I-V characteristics, the top and bottom Pt/film interface Schottky barriers are found to be more symmetric in…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Aqueous‐Phase Synthesis of Single‐Crystal Ceria Nanosheets

Taekyung Yu、Byungkwon Lim、Younan Xia2010-05-10Angewandte Chemie

Die Schichtmorphologie von etwa 2.2 nm dicken und bis zu 4 μm breiten einkristallinen Ceroxidnanoblättern (siehe Bild) entsteht durch zweidimensionale Selbstorganisation anfänglich gebildeter CeO2-Nanokristalle und nachfolgende Umkristallisation. Die geringe Dicke der Nanoblätter führt zu Größenquantelungseffekten und…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

Transport properties of LaTiO3/SrTiO3 heterostructures

Reiji OHTSUKA、M. Matvejeff、Kazunori Nishio 等 5 位作者2010-05-10Applied Physics Letters

Resistivity measurements show that SrTiO3/LaTiO3/SrTiO3 heterostructures remain metallic even for single unit cell LaTiO3 layers. Hall resistances of all heterostructures are nonlinear functions of the applied field. The Hall data is analyzed in terms of a two-layer model, indicating that a low-mobility layer exists a…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Nanostructured Praseodymium Oxide: Correlation Between Phase Transitions and Catalytic Activity

Patrick Sonström、Johannes Birkenstock、Yulia V. Borchert 等 9 位作者2010-05-10ChemCatChem

Abstract Praseodymia gives rise to a rich phase diagram with a large number of phases between the limiting stoichiometries Pr 2 O 3 and PrO 2 that differ only slightly in oxygen content (Pr n O 2 n −2 ). This chemical and crystallographic variability allows the system to release or incorporate lattice oxygen easily at…

Luminescence Properties of Advanced MaterialsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Dipolar glass phase in ferrielectrics: CuInP2S6 and Ag0.1Cu0.9InP2S6 crystals

A. Dziaugys、J. Banys、J. Macutkevič 等 5 位作者2010-05-10physica status solidi (a)

Abstract The dielectric properties of CuInP 2 S 6 and Ag 0.1 Cu 0.9 InP 2 S 6 crystals were investigated in wide frequency (20 Hz–3 GHz) and temperature ranges (25–360 K). The low frequencies dielectric spectra at high temperatures are highly influenced by the high ionic conductivity. The temperature dependences of th…

Glass properties and applicationsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Functionalization of Polyester Fabric by Ar/N 2 Plasma and Silver

Marija Gorenšek、Marija Gorjanc、V. Bukošek 等 6 位作者2010-05-10Textile Research Journal

The objective of this research was to use Ar/N 2 (50%:50%) plasma to increase the adhesion of nano silver particles to raw polyester fabric. RUCO-BAC AGP was applied using the exhaust method. X-ray photoelectron spectroscopy revealed differences in surface composition between the Ar/N 2 plasma-treated and untreated ra…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Mesoscale Modeling of Polyelectrolyte Brushes with Salt

Cyrille Ibergay、Patrice Malfreyt、Dominic J. Tildesley2010-05-10The Journal of Physical Chemistry B

We report dissipative particle dynamics (DPD) simulations of a polyelectrolyte brush under athermal solvent conditions. The electrostatic interactions are calculated using the particle-particle particle-mesh (PPPM) method with charges distributed over the particles. The polymer beads, counterions, co-ions, and solvent…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Exchange bias in single-crystalline CuO nanowires

C. Dı́az-Guerra、María Vila、J. Piqueras2010-05-10Applied Physics Letters

Exchange anisotropy has been observed and investigated in single-crystalline CuO nanowires grown by thermal oxidation of Cu. The exchange bias field decreases by increasing temperature and can be tuned by the strength of the cooling field. A training effect has also been observed. The obtained results can be understoo…

Magnetic properties of thin filmsZnO doping and propertiesCopper-based nanomaterials and applications

Bridged Photochromic Diarylethenes Investigated by Ultrafast Absorption Spectroscopy: Evidence for Two Distinct Photocyclization Pathways

Stéphane Aloïse、Michel Sliwa、Zuzanna Pawlowska 等 11 位作者2010-05-10Journal of the American Chemical Society

Two photochromic diarylethenes blocked by alkyl bridges in an ideal conformation for photocyclization are studied by stationary and femtosecond transient spectroscopy in order to depict the photocyclization processes: the bistable 1,2-dicyano[2.n]metacyclophan-1-ene with n = 2, abbreviated as [2.2], and its non-bistab…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Enhanced Dielectric Constant for Efficient Electromagnetic Shielding Based on Carbon-Nanotube-Added Styrene Acrylic Emulsion Based Composite

Yong Li、Changxin Chen、Jiangtao Li 等 7 位作者2010-05-10Nanoscale Research Letters

An efficient electromagnetic shielding composite based on multiwalled carbon nanotubes (MWCNTs)-filled styrene acrylic emulsion-based polymer has been prepared in a water-based system. The MWCNTs were demonstrated to have an effect on the dielectric constants, which effectively enhance electromagnetic shielding effici…

Electromagnetic wave absorption materialsDielectric materials and actuatorsAdvanced Energy Technologies and Civil Engineering Innovations

Isoelectronic Ru substitution at the iron site inSmFe1−xRuxAsO0.85F0.15and its effects on structural, superconducting, and normal-state properties

M. Tropeano、M. R. Cimberle、C. Ferdeghini 等 13 位作者2010-05-10Physical Review B

In this work we present a systematic experimental and theoretical study of the structural, transport, and superconducting properties of $\text{Sm}({\text{Fe}}_{1\ensuremath{-}x}{\text{Ru}}_{x})\text{As}({\text{O}}_{0.85}{\text{F}}_{0.15})$ polycrystalline samples as a function of Ru content $(x)$ ranging from 0 to 1.…

Rare-earth and actinide compoundsIron-based superconductors researchIntellectual Capital and Performance Analysis

Piezoelectric activity of relaxor-PbTiO3 based single crystals and polycrystalline ceramics at cryogenic temperatures: Intrinsic and extrinsic contributions

Fei Li、Shujun Zhang、Zhuo Xu 等 6 位作者2010-05-10Applied Physics Letters

The piezoelectric activity in [001] poled Pb(In(12)Nb(12))O(3)-Pb(Mg(13)Nb(23))O(3)-PbTiO(3) crystals was investigated as a function of composition and temperature. The level of intrinsic andor extrinsic contribution to the total piezoelectric activity was analyzed using Rayleigh method. The results revealed that thou…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Carbon clusters: From ring structures to nanographene

D. P. Kosimov、A.A. Dzhurakhalov、F. M. Peeters2010-05-10Physical Review B

The lowest-energy configurations of ${\text{C}}_{n}(n\ensuremath{\le}55)$ clusters are obtained using the energy-minimization technique with the conjugate gradient method where a modified Brenner potential is invoked to describe the carbon and hydrocarbon interaction. We found that the ground-state configuration consi…

Graphene research and applicationsFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

London penetration depth and superfluid density of single-crystallineFe1+y(Te1−xSex)andFe1+y(Te1−xSx)

Hyunsoo Kim、C. Martin、R. T. Gordon 等 12 位作者2010-05-10Physical Review B

The in-plane London penetration depth, $\ensuremath{\lambda}(T)$, was measured in single crystals of the iron-chalcogenide superconductors ${\text{Fe}}_{1.03}({\text{Te}}_{0.63}{\text{Se}}_{0.37})$ and ${\text{Fe}}_{1.06}({\text{Te}}_{0.88}{\text{S}}_{0.14})$ by using a radio-frequency tunnel diode resonator. Similar…

Iron-based superconductors research

Large-Scale Orientation in a Vulcanized Stretched Natural Rubber Network: Proved by In Situ Synchrotron X-ray Diffraction Characterization

Gengsheng Weng、Guangsu Huang、Liangliang Qu 等 5 位作者2010-05-10The Journal of Physical Chemistry B

In situ studies of strain-induced crystallization in unfilled and multiwalled carbon nanotube (MWCNT)-filled natural rubber (NR) were carried out by using synchrotron wide-angle X-ray diffraction (WAXD). Synchrotron WAXD results indicate that more nuclei appear in the MWCNT-filled NR sample, leading to higher crystall…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Modulated CO Oxidation Activity of M-Doped Ceria (M = Cu, Ti, Zr, and Tb): Role of the Pauling Electronegativity of M

Yi Liu、Cun Wen、Yun Guo 等 5 位作者2010-05-10The Journal of Physical Chemistry C

Many properties of dopants have been investigated to explore the key factor that influenced the CO oxidation activity of M-doped ceria (CeM). Nevertheless, these reports were controversial. Herein, the Pauling electronegativity (χ P ) of the M was presented as a convenient guide to screen a proper dopant for ceria. Ki…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Tunable band gap in Bi(Fe1−xMnx)O3 films

Xiaoshan Xu、Jon F. Ihlefeld、J. H. Lee 等 10 位作者2010-05-10Applied Physics Letters

In order to investigate band gap tunability in polar oxides, we measured the optical properties of a series of Bi(Fe1−xMnx)O3 thin films. The absorption response of the mixed metal solid solutions is approximately a linear combination of the characteristics of the two end members, a result that demonstrates straightfo…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagneto-Optical Properties and Applications

Nanoparticles Induce Changes of the Electrical Activity of Neuronal Networks on Microelectrode Array Neurochips

Alexandra Gramowski、Juliane Floßdorf、Kunal Bhattacharya 等 9 位作者2010-05-10Environmental Health Perspectives

BACKGROUND: Nanomaterials are extensively used in industry and daily life, but little is known about possible health effects. An intensified research regarding toxicity of nanomaterials is urgently needed. Several studies have demonstrated that nanoparticles (NPs; diameter < 100 nm) can be transported to the central n…

Nanoparticles: synthesis and applicationsHeavy Metal Exposure and ToxicityPesticide Exposure and Toxicity

Interplay between Ferroelastic and Metal−Insulator Phase Transitions in Strained Quasi-Two-Dimensional VO2 Nanoplatelets

Alexander Tselev、Evgheni Strelcov、Igor Lukyanchuk 等 10 位作者2010-05-10Nano Letters

Formation of ferroelastic twin domains in vanadium dioxide (VO(2)) nanosystems can strongly affect local strain distributions, and hence couple to the strain-controlled metal-insulator transition. Here we report polarized-light optical and scanning microwave microscopy studies of interrelated ferroelastic and metal-in…

Multiferroics and related materialsTransition Metal Oxide NanomaterialsGa2O3 and related materials