Materials Literature
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We report a study of attenuation spectra’ transformations in a couple of Cerium (Ce) doped alumino-phospho-silicate fibers (one of them codoped with gold (Au)), occurring under irradiation by a beam of high-energy β-electrons. The experimental data reveals an essential effect of β-irradiation upon the absorptive prope…
This work deals with the in‐situ mass spectrometric (MS) characterization of gases during the atmospheric pressure plasma‐enhanced chemical vapor deposition of propyl isobutyrate (PiB) and allylmethacrylate (AMA). By monitoring the fragments of interest, we are trying to understand the mechanisms involved in the plasm…
The infrared and Raman spectra of [N(CH3)4]2ZnCl4−yBry, where y = 0, 2 and 4, have been analyzed with ab initio calculations of the vibrational characteristics of constitutive polyhedra, tetramethylammonium [N(CH3)4]+ and [ZnCl4−xBrx]2− (x = 0, 1, 2, 3 and 4) tetrahedra. The optimized geometries, calculated vibrationa…
Multiphoton excited fluorescent probes with highly emissive, photostable, low cytotoxic properties are very important for photodynamic therapy, sensing, and bioimaging, etc., even though still challenging. Here, we report the synthesis and spectroscopic studies of two statistical Zn(II)-coordinated copolymers containi…
In this study, the sodium metaborate, which is applicable in various industrial areas, and its metastable zone width that is very important for its production by crystallization, and its nucleation are investigated to obtain the necessary thermodynamic parameters. The polythermal and isothermal method has been used fo…
La0.85(Na1−xKx)0.15MnO3 (0 ≤ x ≤ 1) ceramics were synthesized from the raw La(OH)3, NaOH, KOH, and MnO2 powders using Reactive Spark Plasma Sintering. All the compounds were obtained as pure, dense, and ultrafine grained pellets. The Rietveld refinement of the X-Ray powder diffraction shows that all our synthesized sa…
Abstract Triangularly shaped, contracted porphyrinoids belong to a group of molecules where the geometry significantly modifies the observed electronic properties. The need for a controllable, effective, and widely applicable approach to triphyrins drives extensive research towards macrocyclic materials that act as po…
We use a new technique that allows in situ variation of uniaxial stress to probe the polarization dependence of the optical reflectivity of the representative underdoped iron-arsenide $\text{Ba(}{\text{Fe}}_{1\ensuremath{-}x}{\text{Co}}_{x}{\text{)}}_{2}{\text{As}}_{2}$ through the tetragonal-to-orthorhombic structura…
Carbon microspheres with mean particle sizes of 0.7–1.2 μm were prepared by polymerization of furfuryl alcohol (FA) in H 2 SO 4 solution droplets without any surfactant, followed by pyrolysis. FA was introduced by diffusion from FA-containing oil phase into the droplets formed in an interdigital micromixer. The oil to…
Water stable plasma polymerized acrylic acid/methylene-bis-acrylamide (ppAA/MBA) thin films have been deposited with an atmospheric pressure air plasma jet, a fast technique to grow organic thin films. To increase the stability of the coatings, a cross-linking agent (MBA) was added to the precursor (AA), which was int…
The upper critical field of ${\text{NaFe}}_{1\ensuremath{-}x}$${\text{Co}}_{x}$As was measured from $x=0$ to $x=0.08$, with the magnetic field applied parallel (${H}_{\mathrm{c}2}^{\ensuremath{\parallel}}$) and normal (${H}_{\mathrm{c}2}^{\ensuremath{\perp}}$) to the planes. The data were fitted using one-band and two…
High Resolution Image Download MS PowerPoint Slide We report on the method of fabrication of a photonic microstructure that contains a single magnetic ion. Exactly one manganese ion was introduced into a self-assembled CdTe quantum dot, which was located in a ZnTe based micropillar cavity. The multistep fabrication pr…
We have investigated in the framework of the Ising-like model, by means of Monte Carlo Metropolis method with open boundary condition, the architecture effect on the cooperativity of spin transition coordination polymers. We have analyzed the influence of several physical parameters (size, pressure, and edge effects)…
Piperazine spirocyclic phosphoramidate (PSP), a novel halogen‐free intumescent flame retardant, was synthesized and used to improve the flame retardancy and dripping resistance of polypropylene (PP) combined with ammonium polyphosphate (APP) and a triazine polymer charring‐foaming agent (CFA). The optimum flame‐retard…
Abstract Diarylethenes (DAEs) have rarely been used in the design of photoresponsive supramolecular assemblies with a well‐defined morphology transition owing to rather small structural changes upon photoisomerization. A supramolecular design based on the parallel conformation of DAEs enables the construction of photo…
Fluorine-19 magnetic resonance imaging (19F MRI) could be a promising approach for imaging amyloid deposition in the brain. However, the required features of a 19F MRI probe for amyloid detection remain unclear. In the present study, we investigated a series of compounds as potent 19F probes that could prevent the red…
A nonlocal sinusoidal plate model for micro/nanoscale plates is developed based on Eringen’s nonlocal elasticity theory and sinusoidal shear deformation plate theory. The small-scale effect is considered in the former theory while the transverse shear deformation effect is included in the latter theory. The proposed m…
Cadmium sulfide/organic nanocomposites, which were based on long nanowires, were synthesized by a simple reaction between cadmium nitrate and thioglycolic acid ( TGA ) at room temperature. The products were characterized by X ‐ray diffraction ( XRD ), scanning electron microscopy ( SEM ), transmission electron microsc…
A series of seven dynamic covalent networks based on pentaerythritol tetra(benzohydrazide) and 1,10‐decanediol dibenzaldehyde were prepared in N , N ‐dimethylformamide ( DMF ). The equilibrium degree of swelling in DMF and the sol fraction displayed a minimum at or near the hydrazide–benzaldehyde stoichiometric ratio.…
Sandwich panels were fabricated with nanoclay-filled polyurethane foams and glass fiber-reinforced polyamide and polypropylenes face sheets. Nanoclay-filled foam cores, with organophilic montmorillonite loadings of 0–10 wt%, were synthesized through polyaddition of the polyol premix with 4,4'-diphenylmethane diisocyan…