Materials Literature
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Pentaerythritol [2,2-bis(hydroxymethyl)-1,3-propanediol], C(CH 2 OH) 4 , tetragonal, I4, Z = 2, a = 6.0752 (8), c = 8.733(2)A at T=291K and 0.1 MPa, has been studied at high pressures by X-ray diffraction. The pressure dependence of the unit-cell dimensions has been measured to 1.15 GPa, and the crystal structure has…
The structure of the orientational wetting layer of semiflexible polymers in the vicinity of a hard-wall surface is investigated based on an inhomogeneous free energy functional. A mean-field approximation is used for the system of semiflexible polymers obeying the Saito-Takahashi-Yunoki description and interacting vi…
Based on the experimental observation of cubic-to-tetragonal transition of low-carbon martensite, we perform a long-wavelength approximation for the stress-induced elastic interaction in the theory of microscopic elasticity. Taking into account the elastic anisotropy and the tetragonal character of the octahedral inte…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of Nanosize Latexes by Reverse Micelle PolymerizationA. Hammouda, Th. Gulik, and M. P. PileniCite this: Langmuir 1995, 11, 10, 3656–3659Publication Date (Print):October 1, 1995Publication History Published online1 May 2002Published inissue 1 October 1995https://pub…
Polymer reference interaction site model (PRISM) theory with the Percus–Yevick closure approximation has been applied to investigate the intermolecular correlations, effective chi-parameters, and spinodal phase separation of athermal binary polymer blends. These model mixtures are composed of structurally asymmetric s…
Abstract The esterification of the hydroxyl group of starch with DuPont Surlyn was considered as pretreatment method of starch before blending with polyolefins. In treating starch with Surlyn, two different raction conditions were taken to optimize reaction conditions. First, the esterification reaction was carried ou…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural and Thermodynamic Properties of Charged Silica DispersionsJeanne Chang, Pierre Lesieur, Michel Delsanti, Luc Belloni, Cecile Bonnet-Gonnet, and Bernard CabaneCite this: J. Phys. Chem. 1995, 99, 43, 15993–16001Publication Date (Print):October 1, 1995Publication His…
Raman spectra of the oxidized and neutral forms of polypyrrole show a relative intensity shift from the high wave number region to the low wave number region as the source wavelength is increased from 514.5 to 1064 nm. Variations in band positions are also observed with changes in excitation source; particularly, two…
Abstract This paper reviews the numerical, self‐consistent field theory of block copolymers and blends in which they are a major component, and the relationship of this approach to analytic theories of the weak and strong segregation limits. The major topics of interest are microphase separation and, in blends, its in…
Abstract Deformation experiments on chiral smectic C elastomers show a significant influence of the layer structure. In contrast to nematic systems a deformation of the smectic polydomain does not lead to a uniform director orientation. Obviously, the smectic layers lock in the polydomain structure in a transient netw…
Cylindrical cavities, viewed through the side as they collapsed onto solid surfaces, were studied using high-speed streak and framing photography. The cavities were collapsed asymmetrically using shock waves of varying amplitude so that the rear surface formed a high-speed jet which crossed the cavity and interacted w…
highest thermal displacements of this species occur along directions perpendicular to the proposed direction of motion, approximately towards the neighboring partially occupied site.
We measured skin elastic properties (distension ability, retraction ability, and the skin elasticity) of 4 different body sites, finger, hand, forearm, and chest, in 191 normal individuals by means of a new suction device and investigated the correlation of skin elastic properties with sex, site, age, and the degree o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTQuantitative Kinetic Analysis by High-Resolution 29Si NMR Spectroscopy of the Initial Stages in the Sol-Gel Formation of Silica Gel from TetraethoxysilaneColin A. Fyfe and Patricia P. ArocaCite this: Chem. Mater. 1995, 7, 10, 1800–1806Publication Date (Print):October 1, 1995…
The efficiency of various imidazole derivatives as zinc corrosion inhibitors in hydrochloric acid (HCl) was investigated using electrochemical and gravimetric methods. A difference in efficiency (z) was observed with the introduction of different substituents into a imidazole skeleton. It was established that substitu…
Abstract Mechanical recycling of thermoplastics for high value applications is directly associated with restabilization. The state of the art of processing‐, long term heat‐ and light stabilization of recyclates in different polymers (e.g. PP, PP/EPDM, HDPE, LDPE, PS, PVC and various blends) with examples from packagi…
Abstract Cellulose derivatives with low degrees of substitution (i.e., DS < 1.5) often fail to reveal glass transition temperatures ( T g ) by virtue of their tenacious adherence to moisture, thus preventing systematic analysis of substituent effects (size and DS) on T g and T m transitions. On the other hand, cell…
A new rheometer is described. It consists of a transducer unit supplied with an electric impedance analyzing unit. The transducer unit converts a mechanical impedance into an electrical impedance by the piezoelectric effect. A detailed quantitative analysis of the interaction between the sample and the transducer is g…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermoelectric effects in electrochemical systemsJohn NewmanCite this: Ind. Eng. Chem. Res. 1995, 34, 10, 3208–3216Publication Date (Print):October 1, 1995Publication History Published online1 May 2002Published inissue 1 October 1995https://pubs.acs.org/doi/10.1021/ie00037a0…
The effects of recombinant human interleukin-1 beta (rhIL-1 beta) on alveolar bone resorptive activity in rats were examined. Continuous administration of rhIL-1 beta or phosphate-buffered saline (PBS) was given via osmotic pumps for 3, 7 and 14 days to rats with silk ligatures around second maxillary molars. Other an…