Materials Literature
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The pdxK and pdxY genes have been found to code for pyridoxal kinases, enzymes involved in the pyridoxal phosphate salvage pathway. Two pyridoxal kinase structures have recently been published, including Escherichia coli pyridoxal kinase 2 (ePL kinase 2) and sheep pyridoxal kinase, products of the pdxY and pdxK genes,…
With the aim of understanding the elementary steps governing the oxidation of CO catalyzed by dispersed or supported gold nanoclusters, the adsorption of molecular species, such as O2 and CO, on model neutral and positively charged clusters (Au(n)(m+) n = 1, 9, and 13; m = 0, 1, and 3) has been studied using an ab ini…
The objective of this work was to develop a pre-treatment (cleaning) procedure for a wide range of apparel fabrics and to determine whether differences observed in the properties of fabrics which had and had not been pre-treated were significant. Properties relevant to the manufacture and/or performance of apparel inc…
By using the spectral moments method, we calculate the infrared spectra of chiral and achiral single-walled carbon nanotubes (SWCNTs) of different diameters and lengths. We show that the number of the infrared modes, their frequencies, and intensities depend on the length and chirality of the nanotubes. Furthermore, t…
Heat transfer at nanoscales differs significantly from that in macroscales because of size effects on the phonon and electron transport. Nanoscale heat transfer effects have significant implications for the microelectronic and microphotonic industries, from the thermal management, the device design and reliability, an…
ABSTRACT: Fish skins are rich in collagen and can be used to produce food‐grade gelatin. Films cast from fish‐skin gelatins are stable at room temperature and can act as a barrier when applied to foods. Lysozyme is a food‐safe, antimicrobial enzyme that can also produce gels and films. When cold‐water, fish‐skin gelat…
We propose the local density approximation (LDA) plus an on-site Coulomb self-interaction-like correction (SIC) potential for describing sp-hybridized bonds in semiconductors and insulators. We motivate the present LDA+U SIC scheme by comparing the exact exchange (EXX) hole with the LDA exchange hole. The LDA+U SIC me…
The forces that arise between two iron particles in a nematic liquid crystal with a strong homeotropic anchoring were studied. For the first time, the short range repulsive force resulting from the presence of a hedgehog defect between two particles was precisely determined thanks to application of a small magnetic fi…
PhenHDO3A is a ditopic ligand featuring a tetraazacyclododecane unit substituted by three acetate arms and one 6-hydroxy-5,6-dihydro-1,10-phenanthroline group (PhenHDO3A = rel-10-[(5R,6R)-5,6-dihydro-6-hydroxy-1,10-phenantholin-5-yl)-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). This ligand was specially desig…
Abstract We report experimental results of a liquid crystal polarization grating (LCPG) modulating unpolarized light with high contrast for the first time. Striking results are observed: nearly ideal diffraction into the first orders at > 99%, contrast ratios of up to 600:1 for monochromatic light, switching times…
Abstract Natural structural biomaterials of marine origin including mollusc shells, sponges and corals not only provide an abundant source of novel bone and cartilage replacements but also inspire investigations to develop nano‐sized biomimetic composites. This study presents a characterisation of the ultrastructure o…
The electrical resistivity and X-ray oscillation photograph measurements for an MMX-chain complex, Pt2(dtp)4I (dtp = C2H5CS2-), under high pressure were performed. We observed the most stable metallic phase (TMI = 70 K, under 2.2 GPa) in the 1-D purely d-electronic conductors and pressure-induced metal-insulator trans…
In this study, polypropylene (PP)/nano-silica (nano-SiO 2 ) composites were prepared by a melt blending process. Here, a novel surface treatment method which uses combined dispersant and a coupling agent is developed to treat the nano-SiO 2 which is uniformly dispersed into the PP matrix. To treat the surface of nano-…
Electrical breakdown phenomena of barium titanate ceramic were studied. Sintered ceramic samples made from high purity BaTiO 3 powders with varying particle sizes were obtained by heat treatment in the range of 1280∼1400°C. The resulting average grain size value changed from 1.3 μ m to over 40 μ m. After applying gold…
The Brill transition in transcrystalline nylon-66 occurs at a temperature that is 15 K higher than in the parent spherulitic nylon-66. This difference is assigned to the high level of crystalline orientation and chain packing order in the former. The similarity of the influence of the orientated morphology on the Bril…
Tannic acid (TA), a high molecular weight polyphenol of natural origin, was assembled in alternation with chitosan (CH) using a layer-by-layer technique. The deposition of tannic acid and chitosan layers on flat supports was monitored by quartz crystal microbalance, UV-vis spectroscopy, and electrophoretic mobility me…
/spl beta/-SiC nanowires were synthesized by the way of high-frequency induction with diameter range between 10 to 25 nm and the length was up to 10 μm. Field-effect transistor was fabricated with those synthesized /spl beta/-SiC nanowires. The carrier mobilities of the n-type SiCFETs were 6.4 and 15.9 cm2/V/spl middo…
An effective approach is described for the synthesis of binary patterned polymer brushes using a combination of capillary force lithography and surface-initiated polymerization. First, the approach calls for an ultrathin polystyrene (PS) mask to be deposited, in a pattern, over a surface to which a layer of polymeriza…
Jute (Hessian cloth) reinforced polymer composites were prepared with a mixture of 2-hydroxy ethyl methacrylate (HEMA) and aliphatic urethane diacrylate oligomer (EB-204), and then cured under gamma radiation. Thick pure polymer films (2 mm thickness) were prepared by using the same monomer and oligomer at different w…
The hydrotalcite-like layered double hydroxide (LDH) of Mg with Al shows dramatic changes in the peaks arising from the (h0l)/(0kl) family of reflections in its powder X-ray diffraction pattern during thermal treatment. DIFFaX simulations show that these changes arise due to the transformation of the disordered 3R1 po…