Materials Literature
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We describe and analyze a cellular nonlinear network based on magnetic nanostructures for image processing. The network consists of magneto-electric cells integrated onto a common ferromagnetic film - spin wave bus. The magneto-electric cell is an artificial two-phase multiferroic structure comprising piezoelectric an…
The thickness of dendronized polymers can be tuned by varying their generation g and the dendron functionality X. Systematic studies of this effect require (i) synthetic ability to produce large samples of high quality polymers with systematic variation of g, X and of the backbone polymerization degree N, (ii) a theor…
We achieve epitaxial growth of graphene on the ferromagnetic substrate Co(0001) by chemical vapor deposition using propylene. Structural and electronic properties are revealed by means of low-energy electron diffraction, scanning tunneling microscopy, and spin- and angle-resolved photoelectron spectroscopy. The result…
We present an algorithm for generating all derivative superstructures of a nonprimitive parent lattice. The algorithm has immediate application in important materials design problems such as modeling hexagonal-close-packed (hcp) alloys. Extending the work of Hart and Forcade [Phys. Rev. B 77, 224115 (2008)] (which app…
Based on atomistic calculations of electron and phonon transport, we propose to use surface-decorated silicon nanowires for thermoelectric applications. Two examples of surface decorations are studied to illustrate the underlying ideas: nanotrees and alkyl functionalized silicon nanowires. For both systems we find (i)…
We develop a computational method for evaluating the damping of vibrational modes in mono-atomic metallic chains suspended between bulk crystals under external strain. The damping is due to the coupling between the chain and contact modes and the phonons in the bulk substrates. The geometry of the atoms forming the co…
Soft-x-ray photoemission and absorption spectroscopies are employed to investigate the electronic structures of Sr_{1-x}Rh_{2}O_{4}. Similarly to the layered cobaltates such as Na_{1-x}CoO_{2}, a valence-band satellite feature (VBS) occurs at higher binding energy to the O 2p band. We find that the VBS resonates at th…
Nano-technology has entered the field of medicine in recent decades and many of the nanomaterials developed have already had a high impact on health care. Among nanomaterials, gold nanoparticles (GNPs) and gold quantum dots (QDs) are receiving significant attention because their unique physical, chemical and biologica…
The dimethylaluminum compounds {3-tBu-2-(O)C 6 H 3 CH═N−R}AlMe 2 [R = C 6 H 5 ( 1 ); 2,6-iPr 2 C 6 H 3 ( 2 ); C 6 F 5 ( 3 )] were used as initiators in the ring-opening polymerization (ROP) of ε-caprolactone, l -lactide, and d, l -lactide. Compound 3, in combination with 1 equiv of methanol, exhibited a living behavio…
Abstract Hydrotalcite‐supported gold nanoparticles (Au/HT) were found to be a highly efficient heterogeneous catalyst for the aerobic oxidation of alcohols under mild reaction conditions (40 °C, in air). This catalyst system does not require any additives and is applicable to a wide range of alcohols, including less r…
Nanoceria was produced by an aqueous precipitation technique in the presence of an organic stabilizer. The stable suspensions were diafiltered to remove reaction byproducts. Particles were characterized by transmission electron microscopy with images used to size the particles, and selected-area electron diffraction w…
Calixarene-capped Co(32) clusters are constructed by a sodalite Co(II)(24) cage and an encapsulated Co(III)(8) cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units.
We report a simple, high-yield, method of producing homogeneous dispersions of unfunctionalized and nonoxidized graphene nanosheets in ortho-dichlorobenzene (ODCB). Sonication/centrifugation of various graphite materials results in stable homogeneous dispersions. ODCB dispersions of graphene avert the need for harsh o…
The elastic modulus of single microfibrils from tunicate ( Halocynthia papillosa ) cellulose was measured by atomic force microscopy (AFM). Microfibrils with cross-sectional dimensions 8 x 20 nm and several micrometers in length were obtained by oxidation of cellulose with 2,2,6,6-tetramethylpiperidine-1-oxyl radical…
Cu(2)ZnSnS(4) (CZTS) and Cu(2)ZnSnSe(4) (CZTSe) based solar cells are promising candidates for low cost solar cells due to the natural abundance and low toxicity of the constituent elements. Here, we present the first reported synthesis of colloidal CZTS nanocrystals using a simple solution-phase method. Solar cells f…
Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…
All four known xylazine hydrochloride polymorphous forms were obtained and their relative stabilities were compared directly at three different temperatures. At higher temperatures, it is possible to determine the relative stability of all forms directly by measuring the changes in the composition of the mixtures of t…
Thermal expansion behavior defined as the percentage of dimensional change upon heating for the blend systems of polystyrene/polyethyleneterephthalate has been investigated in this study. General purpose polystyrene (PS) and high impact polystyrene (HIPS) were blended with polyethyleneterephthalate (PET) at a weight r…
In this paper, we present a new tracking control method for holographic digital data storage systems. Holographic data storage systems that use disk media need a different tracking method from those that use optical and hard disk drives. Here, we present the design and implementation of the controller. Due to the inte…
By use of the structural parameters of the single crystal lithium indium orthoborate obtained by Penin et al. (Solid State Sci. 2001, 3, 461-468), from X- ray diffraction data, we present a first-principle study of the electronic structure and the linear optical properties for the novel lithium indium orthoborate Li3I…