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Measuring Macrodiffusion Coefficients in Microbicide Hydrogels via Postphotoactivation Scanning

Anthony R. Geonnotti、Matthew J. Furlow、Tianshi David Wu 等 7 位作者2008-01-15Biomacromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTMeasuring Macrodiffusion Coefficients in Microbicide Hydrogels via Postphotoactivation ScanningAnthony R. Geonnotti*†, Matthew J. Furlow†, Tianshi Wu†, Michael G. DeSoto†, Marcus H. Henderson†, Patrick F. Kiser‡, and David F. Katz†§View Author Information Department of Biomedic…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesTissue Engineering and Regenerative Medicine

Volume dependence of the Curie temperatures in diluted magnetic semiconductors

Lars Bergqvist、B. Belhadji、Silvia Picozzi 等 4 位作者2008-01-15Physical Review B

Using electronic structure methods and statistical methods, we have studied theoretically the volume dependence of the exchange interactions and Curie temperatures in the diluted magnetic semiconductors. In both Mn-doped GaAs and Mn-doped InAs, the calculated Curie temperatures from numerical exact Monte Carlo simulat…

Physics of Superconductivity and MagnetismZnO doping and propertiesQuantum and electron transport phenomena

Double-gap superconducting proximity effect in armchair carbon nanotubes

Karyn Le Hur、Smitha Vishveshwara、Cristina Bena2008-01-15Physical Review B

We theoretically explore the possibility of a superconducting proximity effect in single-walled metallic carbon nanotubes due to the presence of a superconducting substrate. An unconventional double-gap situation can arise in the two bands for nanotubes of large radius wherein the tunneling is (almost) symmetric in th…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Transformation of ancient Chinese and model two-phase bronze surfaces to smooth adherent patinas

Michelle Taube、Alexander H. King、W. T. Chase2008-01-15Phase Transitions

Many ancient Chinese bronze mirrors have survived with a patina that leaves the delicate surface decorations intact. The microstructure of these mirrors is two-phase: Cu-rich α and Sn-rich δ. Although the mirrors have been labeled ‘corrosion-resistant’, the smooth surface includes a corroded layer up to 100 µm thick.…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsNanoporous metals and alloys

Isoprenoid Glycosides from Liriosma ovata

Patrizia Picerno、Teresa Mencherini、Luca Rastrelli 等 5 位作者2008-01-15Journal of Natural Products

A methanol extract of the dried bark of Liriosma ovata afforded two new isoprenoid glycosides, a eudesmane sesquiterpene, 1alpha(beta- d-glucopyranosyloxy)eudesma-3alpha,4beta, 11-triol ( 1), and a C 13-norisoprenoid, 3alpha,6alpha-dihydroxymegastigman-7-en-9-one 3- O-beta- d-apiofuranosyl-(1-->6)-beta- d-glucopyranos…

Natural product bioactivities and synthesisPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

The effective medium approximation for annealed magnetoelectric polycrystals

Y. Y. Liu、Shuhong Xie、Jiangyu Li2008-01-15Journal of Applied Physics

Magnetoelectric polycrystals usually possess antiferromagnetic domains with oppositive magnetoelectric coefficients, and have to be annealed under the appropriate electric and magnetic fields to make the polycrystals macroscopically magnetoelectric. In this paper, we developed an effective medium approximation to calc…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Segmented Polyimides with Poly(ethylene oxide) Blocks Exhibiting Liquid Crystallinity

G. Costa、G.C. Eastmond、J. Patrick A. Fairclough 等 6 位作者2008-01-15Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTSegmented Polyimides with Poly(ethylene oxide) Blocks Exhibiting Liquid CrystallinityG. Costa, G. C. Eastmond, J. P. A. Fairclough, J. Paprotny, A. J. Ryan, and P. StagnaroView Author Information Institute for Macromolecular Studies, ISMAC−CNR, Via De Marini 6, 16149 Genova, It…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Engineering tissue tubes using novel multilayered scaffolds in the rat peritoneal cavity

Yang Cao、Bing Zhang、Tristan I. Croll 等 8 位作者2008-01-15Journal of Biomedical Materials Research Part A

Our aim was to develop novel scaffolds to engineer tissue tubes of smooth muscle-like cells for autologous grafting. Small diameter tubular poly(lactic acid) scaffolds with randomly distributed, interconnected pores up to 100 mum were produced using a thermally induced phase separation method. The scaffolds were surfa…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Effect of phase transition in shock-recovered silicon

Hiroaki Kishimura、Hitoshi Matsumoto2008-01-15Journal of Applied Physics

A series of shock-recovery experiments on a single crystal of silicon up to 38 GPa and characterizations of the recovered samples by x-ray diffraction analysis, Raman spectroscopy, and microscopic observations were performed for a better understanding of residual effects after shock loading by using a propellant gun.…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdvanced Surface Polishing Techniques

Generalized rate-equation analysis of excitation exchange between silicon nanoclusters and erbium ions

Anthony J. Kenyon、M. Wojdak、Iftikhar Ahmad 等 5 位作者2008-01-15Physical Review B

We discuss the use of rate equations to analyze the sensitization of erbium luminescence by silicon nanoclusters. In applying the general form of second-order coupled rate-equations to the Si nanocluster-erbium system, we find that the photoluminescence dynamics cannot be described using a simple rate equation model.…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Electronic structure of the organic semiconductor copper phthalocyanine: Experiment and theory

V. Yu. Aristov、О. В. Молодцова、Volodymyr V. Maslyuk 等 9 位作者2008-01-15The Journal of Chemical Physics

The electronic structure of the organic semiconductor copper-phthalocyanine (CuPc) has been determined by a combination of conventional and resonant photoemission, near-edge x-ray absorption, as well as by the first-principles calculations. The experimentally obtained electronic valence band structure of CuPc is in ve…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Structure and electronic properties of Mg-dopedβ-rhombohedral boron constructed from icosahedral clusters

Hiroshi Hyodo、S. Araake、S. Hosoi 等 7 位作者2008-01-15Physical Review B

High-${T}_{C}$ superconductivity is possible upon metallic-element doping into $\ensuremath{\beta}$-rhombohedral boron $(\ensuremath{\beta}\text{\ensuremath{-}}{\mathrm{B}}_{105})$, which is one of the boron icosahedral cluster solids. We attempted magnesium (Mg) doping into $\ensuremath{\beta}\text{\ensuremath{-}}{\m…

Rare-earth and actinide compoundsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Synthesis and Excited‐state Photodynamics of a Chlorin–Bacteriochlorin Dyad—Through‐space Versus Through‐bond Energy Transfer in Tetrapyrrole Arrays

C. Muthiah、Hooi Ling Kee、James R. Diers 等 8 位作者2008-01-15Photochemistry and Photobiology

Understanding energy transfer among hydroporphyrins is of fundamental interest and essential for a wide variety of photochemical applications. Toward this goal, a synthetic free base ethynylphenylchlorin has been coupled with a synthetic free base bromobacteriochlorin to give a phenylethyne-linked chlorin-bacteriochlo…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Search for spin-lattice coupling mediated by itinerant electrons: Synchrotron x-ray diffraction and Raman scattering fromGdAl3

A. F. García‐Flores、Ângelo Malachias、E. Granado 等 4 位作者2008-01-15Physical Review B

The coupling among the spin degree of freedom and the atomic displacements in intermetallic $\mathrm{Gd}{\mathrm{Al}}_{3}$ was investigated by means of synchrotron x-ray diffraction and polarized Raman scattering. In this compound, the $\mathrm{Gd}\phantom{\rule{0.2em}{0ex}}4{f}^{7}$ shell is spherical and the spin-la…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Magnetic properties and magnetic domains of Nd–Fe–B thin films

S. L. Chen、W. Liu、Z. D. Zhang 等 4 位作者2008-01-15Journal of Applied Physics

Anisotropic Nd–Fe–B thin films are fabricated by direct current magnetron sputtering on Si substrates heated to temperatures over a wide range. Surface morphology and magnetic domains of the Nd–Fe–B thin films prepared at different sputtering temperatures (25–600 °C) are observed by a scanning probe microscopy. The ma…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Benzoyl peroxide as a novel oxidizing agent in a polyaniline dispersion: Synthesis and characterization of a pure polyaniline–poly(vinyl pyrrolidone) composite

S. Palaniappan、M. Sairam2008-01-15Journal of Applied Polymer Science

Abstract Benzoyl peroxide was used as a novel oxidizing agent in the preparation of a polyaniline (PANI) dispersion. Aniline was oxidized by benzoyl peroxide into a PANI dispersion in the presence of poly(vinyl pyrrolidone) (PVP) as a stabilizer. A pure PANI dispersion in water was prepared by the dispersion of the is…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Experimental and Theoretical Studies of the Photoreduction of Copper(II)−Dendrimer Complexes

Haiying Wan、Shenggang Li、Tatyana A. Konovalova 等 6 位作者2008-01-15The Journal of Physical Chemistry C

Zero valent Cu polyamidoamine (PAMAM) dendrimer nanocomposites were synthesized using UV irradiation starting from the aqueous Cu(II)/dendrimer system. The size of the nanoparticles is strongly dependent on the generation of the dendrimers and the pH of the solution. Larger nanoparticles are obtained with higher gener…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

SFGP 2007 - Investigation of a Novel Principle of Chemical Grafting for Modification of Cellulose Fibers

Sophie Berlioz、Camelia Stinga、Jean Condoret 等 4 位作者2008-01-15International Journal of Chemical Reactor Engineering

Natural cellulose fibres have been employed for packaging applications for a long time. Their use, however, has been hampered by their high hydrophilicity and their moisture sensitivity. It has, thus, been proposed to circumvent this problem through the hydrophobic modification of their surface thanks to the use of mo…

Advanced Cellulose Research StudiesBiosensors and Analytical DetectionMaterial Properties and Processing

Effects of stoichiometry on defect formation in ZnO epilayers grown by molecular-beam epitaxy: An optically detected magnetic resonance study

Xingjun Wang、I. A. Buyanova、Weimin Chen 等 5 位作者2008-01-15Journal of Applied Physics

Photoluminescence (PL) and optically detected magnetic resonance are employed to study effects of nonstoichiometry during the growth on defect formation in ZnO epilayers grown by molecular-beam epitaxy (MBE). Several defects are revealed via monitoring the yellow PL emission (∼2.17eV) and their magnetic resonance sign…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesElectronic and Structural Properties of Oxides

Blue luminescent silicon nanocrystals prepared by nanosecond laser ablation and stabilized in electronically compatible spin on glasses

Vladimír Švrček、Takeshi Sasaki、Yoshiki Shimizu 等 4 位作者2008-01-15Journal of Applied Physics

We investigated the blue luminescent silicon nanocrystal (Si-nc) preparation in liquid spin on glass (SOG) by nanosecond laser ablation of the Si target in SOG. The confinement of laser-generated plasma in liquids significantly enhanced the formation of Si-nc. Furthermore, the silicon-dioxide-based SOG inhibited Si-nc…

Diamond and Carbon-based Materials ResearchSilicon Nanostructures and PhotoluminescenceLaser-Ablation Synthesis of Nanoparticles