Materials Literature
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A series of neodymium complexes with various modified β-diketonates and their corresponding gadolinium complexes have been synthesized and characterized. The singlet and triplet energy levels of the coordinated ligands were measured and compared. These complexes emit characteristic Nd3+ light at about 880, 1060, 1330…
The electrode potential of a photochromic spiropyran-modified Au electrode could be reversibly modulated by UV/visible light irradiation in the presence of Zn2+, and a new molecular switch and an "AND" logic gate based on this electronic transduction of the optical signals were established.
The first example of assembling novel heteronuclear lanthanide–transition metal pseudorotaxanes where interpenetration of the lanthanide stoppered thread into the transition metal sensitiser containing macrocycle is signalled via sensitised near-infrared (NIR) lanthanide luminescence is described.
Scanning near-field optical microscopes enable optical measurements and observations with a spatial resolution far beyond the diffraction limit of light. This allows us to spatially resolve the positions in nanoparticles and at the same time to investigate spectroscopic characteristics point by point. In this feature…
The microstructure in 2.9 mol% Y2O3-stabilized tetragonal zirconia polycrystal (Y-TZP) sintered at 1100°-1650°C was examined to clarify the role of Y3+ ions on the cubic-formation and grain growth processes. The cubic phase in Y-TZP stared to appear at 1300°C and the fraction of the cubic phase increased with the incr…
Effects of Ca alone and Ca/Sr composite additions on microstructures, die castability, mechanical properties and creep properties of the Mg-Al based alloys are investigated for the purpose of the development of new Mg-Al-Ca-Sr alloy for automotive powertrain applications. Ca addition of more than about 1% to AM50 allo…
Oilseed flax fiber could be used as reinforcement for composites because it is readily available, environmentally friendly and possesses good mechanical properties. Flax fiber was mixed with high density polyethylene (HDPE) with fiber content from 10 to 30% by mass and processed by extrusion and injection molding to b…
Undoped and Eu-doped were synthesized by a solid-state reaction method at under nitrogen–hydrogen atmosphere. The solubility of in was determined. Nitrogen can be incorporated into by replacement of by , whose amount of solubility depends on the M cation. The solubility of is very low in and lattices ( and 0.045, resp…
We have used neutron reflectometry to characterize the swelling behaviour of brushes of poly[2-(diethyl amino)ethyl methacrylate], a polybase, as a function of pH. The brushes, synthesized by the "" method of atom transfer radical polymerization, were observed to approximately double their thickness in low pH solution…
In the body, vascular cells continuously interact with tissues that possess nanostructured surface features due to the presence of proteins (such as collagen and elastin) embedded in the vascular wall. Despite this fact, vascular stents intended to restore blood flow do not have nanoscale surface features but rather a…
Solid oxide fuel cells (SOFCs) that were capable of running on sour natural gas were fabricated and tested. The electrolyte of the SOFCs was yttria-stabilized zirconia (YSZ), the anode material was a strontium-doped lanthanum vanadate with a nominal composition of La 0.7 Sr 0.3 VO 3 (LSV), and the cathode was a porous…
Polyurethane as a functional material has a wide application in many areas. This paper is designed to the application of polyurethanes in biochemical and biotechnological fields, concerning its biocompatibility and stability. The synthesis of different kinds of polyurethanes , their application for the immobilization…
Nanotechnology is an emerging technology with enormous potential in information and communication technology, biology and biotechnology, medicine and medical technology. Novel nano- and bio-materials, and nanodevices are fabricated and controlled by nanotechnology tools and techniques, which investigate and tune the p…
Highly preorganized pyrazolate-based dinickel(II) systems are shown to constitute suitable building blocks for the targeted assembly of azido-bridged Ni4 complexes with rectangular arrangement of the metal ions. A set of such complexes has been prepared and structurally characterized. mu-1,1-Azide binding within the b…
Organosilicate glass (OSG) coatings with a range of compositions have been deposited using , He, and octamethylcyclotetrasiloxane as a precursor in a plasma-enhanced chemical vapor deposition process. Rutherford backscattering spectrometry and forward recoil spectrometry were used to determine the composition of the c…
Molecules, supramolecular structures and semiconductor nanocrystals are increasingly used as the active components in prototype opto-electrical devices with miniaturized dimensions and novel functions. Therefore, there is a strong need to measure the electronic structure of such single, individual nano-objects. Here,…
PURPOSE: A predictive method was proposed to predict solubility of drugs in water-ethanol mixtures at various temperatures based on the Jouyban-Acree model. The model requires the experimental solubility data of the drug in mono-solvent systems. METHODS: The accuracy of the proposed prediction method was evaluated usi…
A molecular gate attached on the pore outlet of a mesoporous material, which is opened and closed by redox system of thiol groups, effectively switched the progress of a catalytic reaction promoted by the acidic site in the pore void.
The mononuclear Pd(ii) complex cis-[PdCl(2)([9]aneS(3))]([9]aneS(3)= 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
Carbon nanotubes (CNTs) have been in the forefront of nanoscience and nanotechnology because of their remarkable electronic, mechanical and thermal properties and specific functions. CNTs have high potentials for possible applications in the fields of energy, electronics, IT and materials. However, because of the inso…