Materials Literature
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Le système Cu/H3PO4 présente un comportement rythmique en liaison avec la zone d’instabilité située au début du palier de polissage. Le phénomène existe dans les conditions usuelles du polissage électrolytique du cuivre mais également lorsque certaines conditions expérimentales sont modifiées (concentrations, températ…
Polymethylene sulfides and related compounds possessing interesting properties are obtained when the highly reactive intermediate (2) (diradical or zwitterion?) arising from tetrameric thioformaldehyde (1) and boron trifluoride-diethyl ether is allowed to act upon trimeric thioformaldehyde, or substituted oligomeric t…
Sintering of alumina has been carried out in presence of two eutectic glass compositions, viz. CAS (1): CaO–23.0, Al2O3–15.0, SiO2–62.0 and CAS (2): CaO–52.0, Al2O3–41.5, SiO2–6.5. 10, 15, 20 and 25 per cent by weight glass were used with different particle sizes of Al2O3 and sintered at 1400° and 1460°C. Effect of pa…
Abstract Three-terminal dielectric bridge measurements (in the range 20 Hz to 100 kHz between — 5 ° C and —90 to — 120 ° C) have been made of ice doped with (a) conductivity-enhancing ionic impurities (HCl, HF, NaCl, KF, NH 4 F) and (b) conductivity-depressing solutes (NH 4 OH, NH 4 Cl, NH 5 CO 3 , NaHCO 3 ). Blocking…
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Abstract Recent trends in fabric composition, choice of raw materials, and government regulations are placing new demands on the use and utility of antiredeposition additives.
The reversible thermal reaction of the photoisomer of 6,7,14,15-tetrahydro-15,16[1′,2′]8,13[1″,2″]-dibenzenodibenzo [a,g]cyclododencene(bi[anthracene-9,10-dimethylene]) in the solid state has been investigated. The reaction mechanism was studied using differential thermal analysis and optical spectroscopy and was foun…
Abstract Dipole moments and their temperature dependence have been measured in p ‐dioxane for fractionated novolac phenol–, o ‐cresol–, and p ‐cresol–formaldehyde polymers. The phenol–formaldehyde fractions covered a molecular weight range of 200 to 6100, and the limiting dipole moment ratio 〈μ 2 〉/ xm 2 is 1.48. The…
The diffusivity and solubility of hydrogen in both annealed and cold worked polycrystalline nickel were determined in the temperature range of 10 to 60°C by means of an electro-chemical permeation technique. The following results are obtained. The diffusivity increases slightly with increase in grain size, whereas the…
This study was an attempt to discover whether a deficiency in hepatic oxaloacetate can explain the acceleration of ketogenesis observed after the ingestion of medium-chain triglycerides (MCT, constituent fatty acids from C8 to C12). The method of investigation used consisted in supplying oxaloacetate (by intraperitone…
The stress sensitivity of rotational-power loss in silicon iron has been investigated. The loss increases with tensile stress applied parallel to the rolling direction and decreases with compression. The opposite occurs when the stress is applied perpendicular to the rolling direction. The loss varies in a similar fas…
The conventional air-dried alkyd resin is generally used with 30% to 40% of some organic solvent which dissipates into atmosphere after painting and becomes a factor of air pollution. A reactive diluent was investigated to reduce the content of the organic solvent and to manufacture a high-solid or superhigh-solid pai…
The damage of austenitic stainless steels heated at high temperature and high pressures of hydrogen was investigated with reference to the metallurgical factors. Main results obtained are as follows:1) The solubility of hydrogen (wtppm) in 304 steel hydrogenated at T: 473-723 (K) under P: 10-300 (atm) is given by the…
The yield stress and work-hardening of copper base-iron alloy single crystals, which contained coherent γ-iron particles, were examined over a wide range of particle sizes to clarify the hardening mechanism by the γ-iron particles.The yield stress and the extent of the easy glide region in the stress-strain curves inc…
Fracture surfaces, produced by sustained load gaseous hydrogen assisted cracking of 18Ni maraging steel, were examined by scanning electron microscopy. Cracking developed along boundaries associated with the maraging steel microstructure. The specific crack path depended on test temperature and correlated with the inf…
The reaction of [PW12O40]3–, [BW12O40]5–, and [H2W12O40]6–(1.5 × 10–5 mol dm–3) with excess of hydroxrde ion at an ionic strength of 1.0 mol dm–3 MCI (M = K, Na, or Li). to form [WO4]2–, phosphate, and borate, has been studied. The rate, and in some instances the mechanism, of the reactions is dependent on the cation…
In order to investigate some properties of a medium with a low number of particles in a Debye sphere, the electrical conductivity of high-pressure ionized Argon has been measured. A special emphasis is laid on the so-called "non-ideality" effects in the collective behaviour of charged particles. A kind of threshold fo…
It is shown that in alkali halides the increase of the static dielectric constant ε with temperature is exclusively due to anharmonic effects. A simple formula is given which permits the calculation of ε at any temperature if we know : (i) the dielectric constant at room temperature and (ii) the thermal variation of b…
Article Diffusion Coefficient of Carbon in Fe-Ni Austenite in the Temperature Range 950 — 1100° C was published on January 1, 1978 in the journal International Journal of Materials Research (volume 69, issue 1).
The electric dipole moments of derivatives of fourteen classes of mesoionic compounds have been measured. Vector analysis gives heterocyclic ring moments whose magnitude and direction provide support for the mesoionic formulations.