Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of molecular architecture on the adsorption of copolymersAnna C. Balazs, Michael Gempe, and Christopher W. LantmanCite this: Macromolecules 1991, 24, 1, 168–176Publication Date (Print):January 1, 1991Publication History Published online1 May 2002Published inissue 1 Ja…
Optical probe-beam deflection signals, together with cyclic voltammograms, have been used to analyse the electron-transfer process at electrodes coated with [Ru(bpy)2ClPVP]Cl, polyaniline and poly(1-hydroxyphenazine). With this technique it is possible to determine if anions or cations are used as the charge-compensat…
Tensile, fracture toughness, and high cycle fatigue tests were done at 293, 77, and 4 K for Ti-6Al-4V alloys with three levels of oxygen content. The alloys were investigated both in as-forged condition and in the rolled condition. Rolling did not necessarily make α grains finer, but changed the shape from plate-like…
Enzymes acting on pyruvate as a parameter of the ATP regeneration system were studied as a cause of metronidazole resistance in Bacteroides fragilis NCTC 11295. The resistant strain had higher lactate dehydrogenase activity and produced more lactate than susceptible strains, suggesting that the enzyme is more active i…
Abstract X-ray diffraction (XRD) line-broadening analysis has been used to determine dislocation densities in zirconium alloys with hexagonal closepacked (hep) crystal structures and a complex distribution of dislocations reflecting the plastic, anisotropy of the material. The validity of the technique has been assess…
Novel surfactants with two long-chain alkyl groups and two sulfonate groups were synthesized by reactions of oligo (ethyleneglycol) diglycidyl ethers or bis (2, 3-epoxypropyl) ether with long-chain fatty alcohols, followed by reaction with propanesultone. The double-chain compounds showed good water solubility, excell…
Attempts were made to produce fatigue tolerant α-β titanium alloys by the blended elemental (BE) P/M method using extra low chlorine (ELCL) titanium powder. The study was conducted in two stages. In the first stage, the effect of microstructural modification on the high cycle fatigue strength of ELCL BE Ti-6A1-4V was…
We compare vanadium-deficient (nonstoichiometric) and titanium-doped vanadium sesquioxide through measurements of the electrical resistivity at a series of hydrostatic pressures, the magnetic susceptibility, and the low-temperature specific heat: all as a function of T. The pressure dependence of the critical temperat…
Beta-SiC specimens possessing 13% stacking fault density were annealed at various temperatures for various time periods in an Ar or a N2 atmosphere, and the changes in microstructure and the annihilation of stacking faults were investigated. Stacking fault annihilation was found to occur parallel with the grain growth…
Short-circuit losses were measured on a 213 MVA single-phase converter transformer at a number of frequencies between 60 Hz and 6 kHz. Using the results of these tests the harmonic losses during AC/DC converter operation were calculated. Variations of harmonic losses with transformer reactance, transformer winding str…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectroactive ladder polyquinoxalines. 1. Properties of the model compound 5,12-dihydro-5,7,12,14-tetraazapentacene and its complexesSamson A. JenekheCite this: Macromolecules 1991, 24, 1, 1–10Publication Date (Print):January 1, 1991Publication History Published online1 May…
Abstract The objective of this work was to study the obtaining of cationic starch by using a pilot scale twin‐screw extruder Clextral BC45 as a chemical reactor. The reagent was 3‐chloro 2‐hydroxypropyltrimethyl ammonium chloride (CHPTMA) and catalyst was sodium hydroxide (NaOH). In a first set of experiments extruded…
Abstract SIROQUANT is a suite of personal ccmputer programs which runs on an IBM-compatible 386 or 486 personal computer, and gives phase quantification of mineral samples hy Rietveld refinement using the full XRD profile. Eight phases can be quantified in a mineral with the 640 K RAM version and 11 in the EM version.…
The crystal structures of five hydrothermally synthesized representatives of the kieserite group Me(II)SO 4 •H 2 O [szmikite (Me=Mn), szomolnokite (Me=Fe), dwornikite (Me=Ni), gunningite (Me=Zn) and CoSO 4 •H 2 O] were refined in space group C2/c using single crystal X-ray data. The positions of the hydrogen atoms wer…
EDTA is a common additive to reduce the scale formation in industrial boilers. In the present paper, the effect of EDTA concentration on the nucleate boiling heat transfer coefficient of water has been determined with and without CaS04 present as a foulant. The effect of heat flux on the formation of scale deposits is…
Abstract Steam‐ and hydrogen‐induced effects on carbon monoxide oxidation at temperatures below 200°C were studied over an alumina‐supported Pt catalyst. These studies were complemented by measurements of rate expressions and IR spectroscopy. CO oxidation activity over alumina‐supported Pt, Pd and Rh catalysts was fou…
Aqueous molybdovanadates have been studied by 51V NMR spectroscopy over a wide range of metal-ion concentrations and temperatures in the range pH 1.4–7, and by potentiometry at 25°C. The structures of the anions cis-[Mo4V2O19]4–, cis-[HMo4V2O19]3–, [Mo5VO19]3–, [Mo4V5O27]5–, [HMo4V5O27]4– and β-[Mo7VO26]5– have been f…
The influence of the diameter on contamination flashover/withstand voltage of cylindrical insulators was investigated both for AC and DC. The increase in diameter of a cylindrical insulator significantly lowers the contaminated flashover/withstand voltage. The increase in diameter also lowers the contaminant deposit d…
Reactions of anhydrous CrCl3 with H2bpb and H2bpc [H2bpb = 1,2-bis(pyridine-2-carboxamido)benzene; H2bpc = 4,5-dichloro-1,2-bis(pyridine-2-carboxamido)benzene] in dimethylformamide and manganese(III) acetate with H2bpc in methanol, yielded the respective [CrIII(bpb)Cl]·xH2O, [CrIII(bpc)Cl]·H2O and [MnIII(bpc)(O2CMe)]…
Evidence is presented that faujasite-type zeolites with specific Si : Al framework ratios exchanged with Pd(NH3)42+ and Cu2+, catalyse the oxidation of ethylene into acetaldehyde, in exactly the same way as the homogeneous Wacker system [PdII and CuII in concentrated chloride solution]; the active centre is found to b…