Materials Literature
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Abstract A poly(4‐bromoaniline) (PBA) film is electrochemically synthesized on a gold electrode for the recognition of amino acids enantiomers. Scanning electron microscopy measurements show that the porous PBA films are made up of nano‐ribbons. At the PBA modified Au electrode differential pulse voltammograms of L ‐…
Poly(ethylene- co-vinyl acetate), acrylonitrile butadiene copolymer, and their blend (50/50 wt%) loaded with different concentrations of high-abrasion furnace were prepared. Mechanical, thermal, and electrical properties as well as the morphology and the swelling behavior have been investigated in view of filler loadi…
ABSTRACT The synergistic mechanism of tetrabutyl titanate (TBT) in the intumescent flame‐retardant polypropylene (PP) composites was investigated in this work. The intumescent flame‐retardant was composed of pentaerythritol (PER) as a carbonizing agent ammonium polyphosphate (APP) as a dehydrating agent and blowing ag…
Electrically‐active nanoporous membranes are prepared by coating the surface of anodized alumina with electroactive polymers using vapor phase polymerization with four combinations of conjugated polymers and doping ions: poly(3,4‐ethylenedioxythiophone) and polypyrrole, FeCl 3 and FeTs 3 . The permeability of the poly…
The calculation of the 3d-intrashell excitations in coordination compounds by means of the Effective Hamiltonian Crystal Field (EHCF) method is generalized to their polynuclear analogues to properly describe several open d-shells and their magnetic interactions. This challenge requires improving the precision of ca. 1…
A test set-up in intermediate scale was conceived to investigate the structural integrity of materials under fire. The task was to develop a realistic test scenario targeting component-like behaviour. Carbon-fibre-reinforced sandwich specimens (500 × 500 × 20 mm) were used to examine failure mechanisms, times to failu…
Prior to its use for microwave absorption, NiZn ferrite with certain compositions and with ultrafine microstructures (submicron/nanoscale) have been fabricated to investigate the best chemical composition and microstructure for such absorption. A mixture of iron oxide$({\rm Fe}_{2}{\rm O}_{3})$, nickel oxide (NiO) and…
Abstract Surface functionalization plays a crucial role in the design of biosensors. For this purpose, a novel functional monomer, 6‐(4,7‐bis(2,3‐dihydrothieno[3,4‐ b ][1,4]dioxin‐5‐yl)‐2 H ‐benzo[ d ][1,2,3]triazol‐2‐yl)hexan‐1‐amine (BEDOA‐6), was designed and synthesized. Poly(BEDOA‐6) was utilized as an immobiliza…
We have measured the reflectivity spectra of the LiFeAs ( T c = 17.6 K) single crystal in the temperature range from 4 to 300 K. In the superconducting (SC) state ( T < T c ), the clean opening of the optical absorption gap was observed below 25 cm −1 , indicating an isotropic full gap formation. In the normal state (…
We study the variations of electron-phonon coupling and their spectroscopic consequences in response to the sliding of two layers in bilayer graphene using first-principles calculations and a model Hamiltonian. Our study shows that the long wavelength optical phonon modes change in a sensitive and unusual way dependin…
The refractive index profile of one-dimensional gradient-index (GRIN) samples can be measured using the incident and exit beam angles of multiple beams passing through the sample at different positions along the index gradient. Beginning from a region of known refractive index, the collective angular deflection measur…
Walkable dual emissions, in which the emission bands of the walker reversibly cross or leave those of the stationary ones depending on temperature and concentration, have been demonstrated in cyclic dimeric lanthanide complexes [Ln(hfac)3(PAnPO2)]2 (Ln = Eu(III), Tb(III); hfac(-) = hexafluoroacetylacetonate; PAnPO2 =…
This paper is devoted to the analysis of thermoelectric cooling phenomena in semiconductors containing potential barriers (p-n-junction). The formulation of an adequate self-consistent theoretical model describing the effect is presented. The role of the recombination rate in lineal approximation of the electric curre…
Graphene oxide (GO) is successfully exploited as support, loading titanium for catalytic propylene epoxidation. By means of DFT exploration, it is found that atomic Ti has thermodynamical tendency to coordinate with multiple hydroxyl, replacing hydrogen and forming stable tripodal configuration above the GO basal plan…
Five one-dimensional bimetallic W(V)Mn(III) complexes 1-5, consisting of [W(CN)6(bpy)](-) anions and [Mn(Schiff base)](+) cations, were prepared. The central coordination geometry around each W atom is determined as a distorted dodecahedron (DD) for 1 and 2, and a distorted square antiprism (SAPR) for 3-5. Magnetic an…
ABSTRACT Experiments investigating dynamic tensile fracture were performed on the extruded rods of 2024‐T4 and 7075‐T6 aluminum alloys under varying loading conditions. The initial yield stress and fracture strain of 7075‐T6 alloy obtained in spilt Hopkinson tension bar tests are higher than that of 2024‐T4 alloy. But…
ZnO nanorod arrays were synthesized by chemical bath deposition. After heat treatment in hydrogen or air, Ag nanoparticles were deposited on ZnO nanorod arrays by photo-reduction method. The size of Ag nanoparticles as well as the surface morphology, structure, composition, and optical property of ZnO nanorod arrays b…
Reported here are measurements of the penetration depth and spatial distribution of photoelectron (PE) damage excited by 18.6 keV X-ray photons in a lysozyme crystal with a vertical submicrometre line-focus beam of 0.7 µm full-width half-maximum (FWHM). The experimental results determined that the penetration depth of…
Abstract A series of Ru II ‐based photosensitizers were synthesized and extensively characterized. The ligand utilized to coordinate ruthenium was a pyridine–quinoline hybrid bearing an anthracene moiety, and it was combined with commercially available 2,2′‐bipyridine (bpy) for the heteroleptic complexes. The produced…
We report on single-particle dynamics of strongly interacting filamentous fd virus particles in the liquid-crystalline columnar state in aqueous solution. From fluorescence microscopy, we find that rare, discrete events take place, in which individual particles engage in sudden, jumplike motion along the main rod axis…