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Nitrous Oxide Decomposition over Fe-ZSM-5 in the Presence of Nitric Oxide: A Comprehensive DFT Study

Andreas Heyden、Niels Hansen、Alexis T. Bell 等 4 位作者2006-08-01The Journal of Physical Chemistry B

A number of experimental studies have shown recently that ppm-level additions of nitric oxide (NO) enhance the rate of nitrous oxide (N(2)O) decomposition catalyzed by Fe-ZSM-5 at low temperatures. In the present work, the NO-assisted N(2)O decomposition over mononuclear iron sites in Fe-ZSM-5 was studied on a molecul…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions

Magnetic Properties of Lanthanide Chalcogenide Semiconducting Nanoparticles

Michelle D. Regulacio、K. Bussmann、Brad E. Lewis 等 4 位作者2006-08-01Journal of the American Chemical Society

To understand the importance of the band gap to the magnetic ordering in magnetic semiconductors, we have studied the effect of particle size on the ferromagnetic Curie temperature in semiconducting EuS. We have synthesized capped approximately 20 nm EuS nanoparticles using a single-source precursor, [Eu(S(2)CN(i)()Bu…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Decay of space charge in a glassy epoxy resin following voltage removal

L. A. Dissado、V. Griseri、W. Peasgood 等 6 位作者2006-08-01IEEE Transactions on Dielectrics and Electrical Insulation

The PEA technique is used to measure the distribution of space charge in an epoxy resin after polarisation for one week at an applied field of 7.14 kV/mm over a range of temperatures. The decay of the space charge is followed for times up to 114 h after removal of the voltage and analysed in terms of a number of alter…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrostatic Discharge in Electronics

Latex constituents from Calotropis procera (R. Br.) display toxicity upon egg hatching and larvae of Aedes aegypti (Linn.)

Márcio V. Ramos、Glaís de Paiva Bandeira、Cléverson D.T. Freitas 等 7 位作者2006-08-01Memórias do Instituto Oswaldo Cruz

Calotropis procera R. Br. (Asclepiadaceae) is a well-known medicinal plant with leaves, roots, and bark being exploited by popular medicine to fight many human and animal diseases. This work deals with the fractionation of the crude latex produced by the green parts of the plant and aims to evaluate its toxic effects…

Phytochemistry and Bioactive Compounds

A review of advances in processing and metallurgy of titanium alloys

Martin Jackson、Kevin Dring2006-08-01Materials Science and Technology

Titanium and its alloys exhibit excellent mechanical properties, unrivalled corrosion resistance and outstanding biocompatibility; however, annual global titanium production is dwarfed by commodity metals. This is in part due to the current primary production method (Kroll process), which requires a complex and discon…

Hydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and PropertiesAdvanced materials and composites

Functionalization of CNT: synthesis and applications in photovoltaics and biology

Stéphane Campidelli、Cédric Klumpp、Alberto Bianco 等 5 位作者2006-08-01Journal of Physical Organic Chemistry

Abstract Here, we review part of the work carried out in our laboratories on carbon nanotube functionalization. Both covalent (sidewall derivatization) and non‐covalent (using π‐π interactions) functionalization have been used to solubilize carbon nanotubes (NTs). The combination of NTs with various electron donors, m…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Three-Dimensional Microchannels in Biodegradable Polymeric Films for Control Orientation and Phenotype of Vascular Smooth Muscle Cells

Jin Shen、Mary B. Chan‐Park、Bin He 等 9 位作者2006-08-01Tissue Engineering

The poor mechanical strength and vasoactivity of current small-diameter tissue engineered blood vessels (TEBVs) remain unsolved problems. Given the plasticity of smooth muscle cells (SMCs), 1 of the main limitations of current scaffolding techniques is the difficulty in controlling SMC phenotype shifts in vitro. A syn…

Electrospun Nanofibers in Biomedical Applications3D Printing in Biomedical ResearchTissue Engineering and Regenerative Medicine

Electrical and Optical Properties of an Organic Semiconductor Based on Polyaniline Prepared by Emulsion Polymerization and Fabrication of Ag/Polyaniline/n-Si Schottky Diode

F. Yakuphanoğlu、E. Başaran、Bahire Filiz Şenkal 等 4 位作者2006-08-01The Journal of Physical Chemistry B

The electrical, optical, and metal-semiconductor contact properties of the polyaniline prepared by emulsion polymerization have been investigated to obtain an organic semiconductor material. The obtained results suggest that the polyaniline (PANI) studied is an organic semiconductor material with optical band gap (E(g…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces

Overview of Solid-State Thermoelectric Refrigerators and Possible Applications to On-Chip Thermal Management

Jeff Sharp、Jim Bierschenk、H.B. Lyon2006-08-01Proceedings of the IEEE

The concept of thermal management in microelectronic components is changing, and so is the potential for solid-state cooling to solve emerging problems. There is a qualitative change that differentiates the past from the future. We discuss past practices and future trends in the electronic cooling markets, setting the…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Thermal conductivity of composites of aligned nanoscale and microscale wires and pores

Ravi Prasher2006-08-01Journal of Applied Physics

Two-dimensional composite materials made from aligned nano- and microwires hold great promise for various applications such as thermoelectric device. Similarly, two-dimensional composites made from aligned nanoscale pores are also very important for various technologies. Phonon transport along such composites primaril…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Designing dielectric loss at microwave frequencies using multi-layered filler particles in a composite

Nicola Bowler2006-08-01IEEE Transactions on Dielectrics and Electrical Insulation

Microwave-absorbing materials find application in telecommunications, microwave heating and for representing the behavior of biological tissue in the presence of microwave radiation. Commonly, such materials are formed using ferromagnetic filler particles and rely on the phenomenon of ferromagnetic resonance for absor…

Electromagnetic wave absorption materialsDielectric materials and actuatorsAerosol Filtration and Electrostatic Precipitation

Formation of Stable Vaterite with Poly(acrylic acid) by the Delayed Addition Method

Kensuke Naka、Shu‐Chen Huang、Yoshiki Chujo2006-08-01Langmuir

The crystallization of CaCO3 was examined by changing the addition time of poly(acrylic acid) (PAA) to an aqueous solution of calcium carbonate by selectively interacting with the crystal at different stages during the crystal-forming process. The precipitation of CaCO3 was carried out by a double jet method to preven…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesCalcium Carbonate Crystallization and Inhibition

Networks of channels for self-healing composite materials

Adrian Bejan、Sylvie Lorente、K.-M. Wang2006-08-01Journal of Applied Physics

This is a fundamental study of how to vascularize a self-healing composite material so that healing fluid reaches all the crack sites that may occur randomly through the material. The network of channels is built into the material and is filled with pressurized healing fluid. When a crack forms, the pressure drops at…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPolymer composites and self-healing

A diatom-based index for the biological assessment of eastern Canadian rivers: an application of correspondence analysis (CA)

Isabelle Lavoie、Stéphane Campeau、Martine Grenier 等 4 位作者2006-08-01Canadian Journal of Fisheries and Aquatic Sciences

We developed a diatom-based index that integrates the effects of multiple stresses on streams and provides information related to the "distance" from the nonimpacted state. The Eastern Canadian Diatom Index (IDEC) was based on a correspondence analysis (CA) to develop a chemistry-free index where the position of the s…

Marine and coastal ecosystemsMarine Biology and Ecology ResearchDiatoms and Algae Research

Lotus effect: Superhydrophobicity

Ho-Geun Lee、Stephen Michielsen2006-08-01Journal of the Textile Institute

The relationships among contact angles, surface tensions, and surface roughness are reviewed. The various numerical formulae related to contact angles were used to predict the surface tension and wetting behavior of polymer surfaces. The apparent contact angle of a droplet deposited on a textured surface is presented,…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAdhesion, Friction, and Surface Interactions

Linear-Source Ultrasonic Spray Chemical Vapor Deposition Method for Fabrication of ZnMgO Films and Ultraviolet Photodetectors

Y. Kamada、Toshiyuki Kawaharamura、Hiroyuki Nishinaka 等 4 位作者2006-08-01Japanese Journal of Applied Physics

Linear-Source Ultrasonic Spray Chemical Vapor Deposition Method for Fabrication of ZnMgO Films and Ultraviolet Photodetectors, Kamada, Yudai, Kawaharamura, Toshiyuki, Nishinaka, Hiroyuki, Fujita, Shizuo

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Surface Characteristics of Layered Silicates: Influence on the Properties of Clay/Polymer Nanocomposites

Fruzsina Kádár、László Százdi、Erika Fekete 等 4 位作者2006-08-01Langmuir

A sodium montmorillonite and six organophilic montmorillonites coated with different surfactants were characterized in various ways in the study. Particle and surface characteristics were determined by nitrogen adsorption and inverse gas chromatography, respectively. The gallery structure of organophilic montmorilloni…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesAdsorption, diffusion, and thermodynamic properties of materials

Cone-End Functionalization of Carbon Nanohorns

Georgia Pagona、Nikos Tagmatarchis、Jing Fan 等 5 位作者2006-08-01Chemistry of Materials

The cone end of carbon nanohorns is removed with a powerful but mild oxidative treatment avoiding shortening of nanohorns and formation of any type of impurities. Functionalization of carboxylic acid terminated nanohorns, with amines, alcohols, and thiols induced solubility enhancement. Intramolecular electron transfe…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Comparison of Water-Soluble CdTe Nanoparticles Synthesized in Air and in Nitrogen

Yuanfang Liu、Wei Chen、Alan G. Joly 等 8 位作者2006-08-01The Journal of Physical Chemistry B

It is commonly believed that high-quality CdTe nanoparticles with strong luminescence can only be prepared under the protection of an inert gas such as nitrogen or argon. Here, we report the preparation of highly luminescent CdTe nanoparticles in air and compare their luminescence properties with CdTe nanoparticles ma…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Biomimetic Self-Assembling Peptides as Injectable Scaffolds for Hard Tissue Engineering

A. Firth、Amalia Aggeli、Julie Burke 等 5 位作者2006-08-01Nanomedicine

The production of bone-, dentine- and enamel-like biomaterials for the engineering of mineralized (hard) tissues is a high-priority in regenerative medicine and dentistry. An emerging treatment approach involves the use of short biomimetic peptides that self-assemble to form micrometer-long nanofibrils with well defin…

Calcium Carbonate Crystallization and InhibitionSupramolecular Self-Assembly in MaterialsBone and Dental Protein Studies