Materials Literature
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Cross-linked co-polymers containing glycidyl azide polymer (GAP) and hydroxyl-terminated poly(butadiene) (HTPB) segments have been obtained by chemical reactions. The reactions involves two steps. In the first step the GAP macroinitiator (GAPMI) is synthesized by the condensation reaction of GAP-diol with 4,4'-azobis(…
Monolithic siliceous materials were prepared, using sol–gel based methods, from mixtures of trifunctional silanes based on sugar lactones, including silyl-modified gluconamide GLS and maltonamide MLS, and a tetrafunctional silane derived from glycerol. The tri- and tetrafunctional compounds cured at different rates, w…
In an effort to build effective photovoltaic cells based on porphyrin-functionalised polythiophenes we have focused on synthetic routes to three monomer types. By controlling the geometric structure of the monomer, oxidation of these materials should produce polymers with different architectural structures, and as a r…
A series of structurally characterised mu-cyanodicopper(II) cryptates shows moderately strong antiferromagnetic interaction in the range -2J= 150-200 cm(-1), at the high end of the observed range for such assemblies. The lowest magnetic exchange coupling parameter is displayed where there is slight bending of the M-CN…
The materials for use in nitric acid service have to be resistant to intergranular corrosion and have low general corrosion rates. End grain corrosion resulting from inclusions and segregation along dislocation bands needs to be minimised. The Nitric Acid Grade of stainless steel resistant to these corrosion problems…
Gelatin hydrogels cross-linked by y-ray irradiation using 60Co as gamma-ray source were prepared. As a model of controlled release of low-molecular-weight compounds, absorption and release of methylene blue, a water-soluble cationic dye, was investigated. Irradiated gelatin hydrogels did not redissolve at temperatures…
Rückamp, R.; Benckiser, E.; Haverkort, M. W.; Roth, H.; Lorenz, T.; Freimuth, A.; Jongen, L.; Möller, A.; Meyer, G.; Reutler, P.; Büchner, B.; Revcolevschi, A.; Cheong, S. W.; Sekar, C.; Krabbes, G.; Grüninger, M.
Author: Oettel, M. et al.; Genre: Journal Article; Issued: 2005-08-17; Keywords: MPI für Metallforschung; Abt. Dietrich; Wetting and Capillarity; Title: Attractions between charged colloids at water interfaces
Water is capable of reducing the rate of deactivation of gold-titania catalysts for propene epoxidation.
Hollow silica nanospheres containing iridium particles were synthesized by the Ir(NH3)6Cl3aq/NP-6/cyclohexane reversed micelle system. Hydrolysis of TEOS surrounding Ir(NH3)6Cl3 produced hollows which can absorb hydrogen under ambient conditions.
Specific three-point hydrogen bonding between diamidopyridine (DAP) and thymine (Thy) was employed to reversibly anchor "brush-like" Tri-DAP end-functionalized polystyrene onto Thy-modified silica surfaces.
Propagation of an axial crack has been characterized by means of the Pin-Loading Tension (PLT) test. The same experimental arrangement is used for the Delayed Hydrogen Cracking (DHC) and for the J-integral measurements. The DHC tests are performed under variable temperature and/or load conditions simulating a variable…
In this contribution, we report the successful preparation of large-scale and uniform europium-doped lutetium compounds with the varied morphologies of nanoflakes, nanoquadrels and nanorods, using colloidal Lu(OH)3–Eu at different concentrations as a precursor for the hydrothermal method (170 °C and pH = 13 for 24 h).…
This paper investigates two classes of generalized viscous Cahn-Hilliard equations, featuring two different laws for the mobility, which is assumed to depend on the chemical potential. Both equations can be obtained with the new derivation of equations of Cahn-Hilliard type proposed by M.E. GURTIN[14]. Approximation a…
A novel liquid-crystal (LC) Fresnel zone plate (FZP) is fabricated only by the LC molecular alignment process without the need for surface relief structures and patterned electrodes. It is theoretically described that the Fresnel-lens-like phase profile is achieved under optimum LC molecular orientation conditions and…
The synthesis of two phthalocyanine-porphyrin covalently linked heteromolecules are described. Intramolecular energy transfer is investigated and quantified in terms of the quantum yield of energy transfer and found to be highly effective in both molecules. The photophysical properties of both molecules are modified g…
A new tetranuclear compound containing Ru(II) and Ir(III) polypyridine subunits exhibits two independent emissions at room temperature, as a consequence of weak interchromophoric coupling; in contrast, at 77 K energy transfer from Ir-based chromophores to the Ru-based ones is quantitative.
Human skin metrology is an area of growing interest for many disciplines both in research and for commercial purposes. Changes in the skin topography are an early stage diagnosis tool not only for diseases but also give indication of the response to medical and cosmetic treatment. This paper focuses on the evaluation…
BEA zeolite has been simultaneously detemplated and Fe-exchanged by treating the parent zeolite with a Fenton's-type reagent (Fe3+-H2O2) at low temperature. This one-pot process simplifies and speeds up considerably the preparation route. The catalyst shows excellent performance on N2O decomposition compared to conven…
This paper describes an experimental study on the behavior of concrete panels with steel plate subjected to missile impact.Two tests were carried out, divided in accordance with the types of projectile, non-deformable and deformable.In all, 40 specimens of 750mm square were prepared.The panel specimen was suspended ve…