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Electronic structure of low-spin ferric porphyrins: a single-crystal EPR and structural investigation of the influence of axial ligand orientation and the effects of pseudo-Jahn-Teller distortion

Robert E. Quinn、Joan Selverstone Valentine、Marianne P. Byrn 等 4 位作者1987-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic structure of low-spin ferric porphyrins: a single-crystal EPR and structural investigation of the influence of axial ligand orientation and the effects of pseudo-Jahn-Teller distortionRobert Quinn, Joan Selverstone Valentine, Marianne P. Byrn, and Charles E. Strou…

Electrocatalysts for Energy ConversionPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Study of transesterification in poly(ethylene terephthalate) by small-angle neutron scattering

J. Kugler、J. W. Gilmer、D. Wiswe 等 6 位作者1987-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudy of transesterification in poly(ethylene terephthalate) by small-angle neutron scatteringJ. Kugler, J. W. Gilmer, D. Wiswe, H. G. Zachmann, K. Hahn, and E. W. FischerCite this: Macromolecules 1987, 20, 5, 1116–1119Publication Date (Print):May 1, 1987Publication History…

Polymer crystallization and propertiesRecycling and Waste Management Techniques

Nonlinear susceptibilities of finite conjugated organic polymers

David N. Beratan、José N. Onuchic、Joseph W. Perry1987-05-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNonlinear susceptibilities of finite conjugated organic polymersDavid N. Beratan, Jose Nelson. Onuchic, and Joseph W. PerryCite this: J. Phys. Chem. 1987, 91, 11, 2696–2698Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Published inissue 1 M…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsNonlinear Optical Materials Research

Surface differential reflectivity spectroscopy of semiconductor surfaces

S. Selci、F. Ciccacci、G. Chiarotti 等 5 位作者1987-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

An overview of the method of surface differential reflectivity (SDR) for the study of semiconductor surfaces is presented. This includes the principles of the technique, the experimental apparatus, and some theoretical considerations concerning the connection of SDR data with the microscopic properties of the surface.…

Optical Coatings and GratingsSurface Roughness and Optical Measurements

BIOLOGICAL ACTIVITIES OF PHTHALOCYANINES—VI. PHOTOOXIDATION OF L‐TRYPTOPHAN BY SELECTIVELY SULFONATED GALLIUM PHTHALOCYANINES: SINGLET OXYGEN YIELDS AND EFFECT OF AGGREGATION

J. Richard Wagner、Hesham Ali、Réjean Langlois 等 5 位作者1987-05-01Photochemistry and Photobiology

Abstract— The photosensitized oxidation of L‐tryptophan by gallium phthalocyanines sulfonated to different degrees is studied as a function of both substrate and sensitizer concentrations in water and 50% MeOH‐H 2 O solutions. The maximum quantum yield of singlet oxygen was found to be nearly 0.5 for all sulfonated ga…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochromic and Fluorescence Chemistry

Carbon-13 enriched end groups of isotactic polypropylene and poly(1-butene) prepared in the presence of ethylenediindenyldimethyltitanium and methylalumoxane

Pasquale Longo、Alfonso Grassi、Claudio Pellecchia 等 4 位作者1987-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCarbon-13 enriched end groups of isotactic polypropylene and poly(1-butene) prepared in the presence of ethylenediindenyldimethyltitanium and methylalumoxanePasquale Longo, Alfonso Grassi, Claudio Pellecchia, and Adolfo ZambelliCite this: Macromolecules 1987, 20, 5, 1015–101…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

A Rapid Centrifugation Method for Obtaining Soil Solution

Elsayed A. Elkhatib、J. L. Hern、T. E. Staley1987-05-01Soil Science Society of America Journal

Abstract A modified centrifugation technique for obtaining soil solutions was developed and compared to immiscible displacement technique using different immiscible liquids. Coefficients of variation and standard deviations for ionic composition of soil solutions obtained by the modified centrifugation method were con…

Soil and Unsaturated FlowClay minerals and soil interactionsChemical and Physical Properties in Aqueous Solutions

Ceramic Powder Science

Gary L. Messing、James W. McCauley、K. S. Mazdiyasni 等 4 位作者1987-05-01Medical Entomology and Zoology

This book discusses the following topics: Solution synthesis of ceramic powders; vapor and solid state synthesis of ceramic powders; ceramic powder dispersions; consolidation of ceramic powders; and powder and pore structure characterization.

Advanced ceramic materials synthesis

Soils Developed in Sediments from Late Quaternary Water Bodies in Northern New York

J. Kern、Ray B. Bryant1987-05-01Soil Science Society of America Journal

Abstract Extensive areas of soils in northern New York have formed in parent materials deposited in late Quaternary water bodies. In previous studies, distinctions among these lacustrine, marine, and brackish‐water deposits have relied on the identification of fossils and continuous shoreline features; however, eviden…

Geology and Paleoclimatology ResearchSoil and Unsaturated FlowClay minerals and soil interactions

Quantitative Formation of a [2.2]Paracyclophane Derivative via Topochemical Photoreaction of Crystal Complex of Ethyl and Propyl α-Cyano-4-[2-(4-pyridyl)ethenyl]cinnamates

Masaki Hasegawa、Yasunari Maekawa、Satoshi Kato 等 4 位作者1987-05-01Chemistry Letters

Abstract The complex with the composition ranging from 6:4 to 2:8 of ethyl α-cyano-4-[2-(4-pyridyl)ethenyl]cinnamate (1) and propyl α-cyano-4-[2-(4-pyridyl)ethenyl]cinnamate (2) photodimerized quantitatively into the three types of tricyclic dimer crystal, indicating a disordered sequence of 1 and 2 in the monomer cry…

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

Characterization, Redox Properties and Pulse-Radiolysis Study of Dichloro-(Tetraazacyclotetradecane)Manganese(III) Complexes, and X-Ray Crystal-Structure of the meso -5,7,7,12,14,14-Hexamethyl-1,4,8,11-Tetraazacyclotetradecane Complex

Trevor W. Hambley、GA Lawrance、DF Sangster 等 4 位作者1987-05-01Australian Journal of Chemistry

The complexes [Mn ( mac )Cl2]+ [ mac = 1,4,8,1l-tetraazacyclotetradecane (cyclam), meso and rac -5,7,7,12,14,14-hexamethylcyclam ( teta and tet b respectively)] have been prepared. The trans-[ Mn ( tet a )Cl2] Cl.3H2O complex crystallizes in the monoclinic space group P21 /c, Z 2, a 8.4006(8), b 12.465(2), c 11 .659(2…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

X-ray photoelectron spectroscopic characterization of carbon monoxide bonding sites on supported small rhodium clusters

G. Apai、B.G. Frederick1987-05-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray photoelectron spectroscopic characterization of carbon monoxide bonding sites on supported small rhodium clustersG. Apai and B. G. FrederickCite this: Langmuir 1987, 3, 3, 395–400Publication Date (Print):May 1, 1987Publication History Published online1 May 2002Publishe…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Rheological changes during the polymerization of polyurethane based interpenetrating polymer network(IPN)

Y. M. Lee、Yong Yang、L. J. Lee1987-05-01Polymer Engineering and Science

Abstract Experimental results on reactions forming polyurethanes and polyurethane‐polyester Interpenetrating polymer network (IPN) are discussed with particular interest in rheological and kinetic changes before the gel point. In the IPN formation, viscosity rise is affected by the amount of styrene and polyester in t…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingEpoxy Resin Curing Processes

Newly observed microscopic planar defects on {111} in natural diamond

John C. Walmsley、A. R. Lang、Madeline Rooney 等 4 位作者1987-05-01Philosophical Magazine Letters

Circular disc-crack-like defects randomly distributed on {111} planes have been discovered by 300kV transmission electron microscopy in diamond that had crystallized on non-faceted growth surfaces of mean orientation {100}. In a sample of ∼ 100 defects, disc diameters were narrowly distributed about a mean of 1·2 μm a…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

Defect study of yttrium-hydrogen solid solutions

P. Vajda、J. N. Daou、A. Lucasson 等 4 位作者1987-05-01Journal of Physics F Metal Physics

The resistivity anomaly near 170 K in alpha -YH(D)x solid solutions due to the ordering of hydrogen into a paired configuration is analysed in detail. Defects are introduced into the ordered structure by a quench from room temperature and by electron irradiation at 20 K (Ee-=0.35 to 0.8 MeV) resulting in residual resi…

Hydrogen Storage and MaterialsNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

Chemical Durability of Some Sodium Borosilicate Glasses Improved by Phase Separation *

Peter G. Taylor、SHEILA D. ASHMORE、Derrek G. Owen1987-05-01Journal of the American Ceramic Society

Dissolution of glass coupons with the general composition χNa 2 O.(100–χ)[0.33B 2 O 3 ·0.67SiO 2 ], with χ varying from 3 to 11, has been monitored with and without prior phase separation of the glasses. A major reduction in dissolution rates was noted upon phase separation of glasses with χ≃ 3. This was correlated wi…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionNuclear materials and radiation effects

Thermodynamic Evaluation of Amorphous Aluminosilicate Binding Agents in Fragipans of Western Kentucky

A. D. Karathanasis1987-05-01Soil Science Society of America Journal

Abstract Composition of soil solutions in contact with fragipan and nonfragipan horizons of Fragiudalfs in western Kentucky were related to the composition of soil amorphous constituents removed by various extractants. Increased amorphous Si/Al ratios in fragipan horizons were correlated well with reduced pH 4 SiO 4 s…

Soil and Unsaturated FlowGroundwater flow and contamination studiesClay minerals and soil interactions

Modification of Acrylic Fibers: An Overview

P. Bajaj、Surya Kumari1987-05-01Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

Among the vinyl monomers, acrylonitrile is the only monomer used for the production of synthetic fibers. Other vinyl monomers lack cohesive forces between the molecular chains of their polymers and, hence, can not compete with acrylonitrile [1]. Acrylic fiber has replaced wool in many major applications, particularly…

Textile materials and evaluations

Fast-Switching Low-Temperature Liquid Crystal Mixtures

W. Kuczyński、S. T. Lagerwall、M. Matuszczyk 等 6 位作者1987-05-01Molecular crystals and liquid crystals

The metastable chiral smectic C phases of the compounds have been made technically useful by alloying to different two- and three-component systems with enantiotropic behaviour. These systems can serve as a base for multi-component systems of higher order for optimizing various properties. In a similar way, the inconv…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochemistry and Electron Transfer Studies

Protection and polymerization of functional monomers. 10. Synthesis of well-defined poly(4-vinylbenzaldehyde) by the anionic living polymerization of N-[(4-ethenylphenyl)methylene]cyclohexamine

Akira Hirao、Seiichi Nakahama1987-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProtection and polymerization of functional monomers. 10. Synthesis of well-defined poly(4-vinylbenzaldehyde) by the anionic living polymerization of N-[(4-ethenylphenyl)methylene]cyclohexamineAkira Hirao and Seiichi NakahamaCite this: Macromolecules 1987, 20, 12, 2968–2972P…

Advanced Polymer Synthesis and CharacterizationSynthesis and properties of polymersPhotopolymerization techniques and applications