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A XANES determination of the oxidation state of chromium in silicate glasses

Andrew J. Berry、Hugh O’Neill2004-05-01American Mineralogist

Cr K-edge X-ray absorption near-edge structure (XANES) spectra were recorded for silicate glasses of various compositions in the system CaO + MgO + Al 2 O 3 + SiO 2 ± TiO 2 , quenched from melts equilibrated as a function of oxygen fugacity (f O₂ ) at 1400 °C. The spectra vary systematically with fO 2 (logf O₂ ∼ 0 to…

X-ray Spectroscopy and Fluorescence AnalysisGlass properties and applicationsGeological and Geochemical Analysis

Molecular Targeting of Drug Delivery Systems to Cancer

Tamara Minko、S. Dharap、Refika I. Pakunlu 等 4 位作者2004-05-01Current Drug Targets

This review presents molecular targeting approaches in anticancer drug delivery systems (DDS) and identifies new developments in these systems. Targeting approaches include passive targeting (enhanced permeability and retention effect), targeting specific tumor conditions, topical delivery and active targeting, namely…

Nanoparticle-Based Drug DeliveryComputational Drug Discovery MethodsRNA Interference and Gene Delivery

Degradation of poly-L-lactide. Part 1: in vitro and in vivo physiological temperature degradation

N A Weir、Fraser Buchanan、J. F. Orr 等 4 位作者2004-05-01Proceedings of the Institution of Mechanical Engineers Part H Journal of Engineering in Medicine

Poly-L-lactide (PLLA) is one of the most significant members of a group of polymers regarded as bioresorbable. The degradation of PLLA proceeds through hydrolysis of the ester linkage in the polymer's backbone and is influenced by the polymer's initial molecular weight and degree of crystallinity. To evaluate its degr…

biodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing TechnologiesGraphene and Nanomaterials Applications

Formation of Concentrated Nanoemulsions by Extreme Shear

Kieche Meleson、Sara M. Graves、Thomas G. Mason2004-05-01Soft Materials

We have systematically investigated the production of “nanoemulsions,” droplets of one liquid phase in another immiscible liquid phase that have diameters less than 100 nm. Our approach relies on a combination of extreme shear due to multipass, high‐pressure microfluidic injection and systematic control of the emulsio…

Fluid Dynamics and Thin FilmsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Fatigue of Magnesium Alloys

Carsten Potzies、Karl Ulrich Kainer2004-05-01Advanced Engineering Materials

Abstract Magnesium alloys show a high specific strength and are therefore increasingly used for light‐weight constructions in transportation industry. [1,2] To predict the behaviour of the material under the influence of cyclic loading it is vital to understand the fatigue behaviour of magnesium alloys. Only when unde…

Aluminum Alloy Microstructure PropertiesMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites Properties

Development of novel tissue engineering scaffolds via electrospinning

Lakshmi S Nair、Subhabrata Bhattacharyya、Cato T. Laurencin2004-05-01Expert Opinion on Biological Therapy

Electrospinning has recently been developed as an efficient technique to develop polymeric nanofibres. Various synthetic and natural biodegradable polymers have been electrospun into fibres with diameters in the nanometre range (< 1 microm). The fibre diameter, structure and physical properties of the nanofibre matric…

Silk-based biomaterials and applicationsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Effect of MnO 2 Addition on the Structure and Electrical Properties of Pb(Zn 1/3 Nb 2/3 ) 0.20 (Zr 0.50 Ti 0.50 ) 0.80 O 3 Ceramics

Yudong Hou、Mankang Zhu、Feng Gao 等 7 位作者2004-05-01Journal of the American Ceramic Society

Pb(Zn 1/3 Nb 2/3 ) 0.20 (Zr 0.50 Ti 0.50 ) 0.80 O 3 ceramics of pure perovskite structure were prepared by the two‐stage method with the addition of 0–3.0 wt% MnO 2 and their piezoelectric properties were investigated systematically. The MnO 2 addition influences in a pronounced way both the crystal structure and the…

Multiferroics and related materialsMicrowave Dielectric Ceramics SynthesisFerroelectric and Piezoelectric Materials

A New Thermoelectric Material: CsBi4Te6

Duck Young Chung、Tim Hogan、Melissa Rocci‐Lane 等 9 位作者2004-05-01Journal of the American Chemical Society

The highly anisotropic material CsBi(4)Te(6) was prepared by the reaction of Cs/Bi(2)Te(3) around 600 degrees C. The compound crystallizes in the monoclinic space group C2/m with a = 51.9205(8) A, b = 4.4025(1) A, c = 14.5118(3) A, beta = 101.480(1) degrees, V = 3250.75(11) A(3), and Z = 8. The final R values are R(1)…

Thermal Radiation and Cooling TechnologiesAdvanced Thermodynamics and Statistical MechanicsAdvanced Thermoelectric Materials and Devices

SHAPE MEMORY ALLOYS IN SEISMIC RESISTANT DESIGN AND RETROFIT: A CRITICAL REVIEW OF THEIR POTENTIAL AND LIMITATIONS

Reginald DesRoches、Barton L. Smith2004-05-01Journal of Earthquake Engineering

Shape memory alloys (SMAs) are a class of materials that have unique properties, including Young's modulus-temperature relations, shape memory effects, superelastic effects, and high damping characteristics. These unique properties, which have led to numerous applications in the biomedical and aerospace industries, ar…

Shape Memory Alloy Transformations

Subphthalocyanines: Tuneable Molecular Scaffolds for Intramolecular Electron and Energy Transfer Processes

David González‐Rodríguez、Tomás Torres⊗、Dirk M. Guldi 等 6 位作者2004-05-01Journal of the American Chemical Society

A series of four subphthalocyanine-C(60) fullerene dyads have been prepared through axial functionalization of the macrocycle with m-hydroxybenzaldehyde and a subsequent dipolar cycloaddition reaction. The subphthalocyanine moiety has been peripherally functionalized with substituents of different electronic character…

Synthesis and Properties of Aromatic CompoundsPorphyrin and Phthalocyanine ChemistryFullerene Chemistry and Applications

Modification of PEDOT:PSS as hole injection layer in polymer LEDs

Margreet M. de Kok、Michael Buechel、Simone I. E. Vulto 等 10 位作者2004-05-01physica status solidi (a)

Poly(3,4-ethylenedioxythiophene):poly(styrenesulphonic acid) (PEDOT:PSS) is commonly used as an anode in polymer light-emitting diodes (PLED). We have studied the effect of the pH and Na+ ion concentration of the aqueous PEDOT:PSS dispersion on the bulk and surface properties of spincoated films by various techniques,…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Advantages of Ferromagnetic Nanoparticle Composites in Microwave Absorbers

V.B. Bregar2004-05-01IEEE Transactions on Magnetics

Composites with nanosize ferromagnetic particles can be useful in microwave absorbers, since nanoparticles exhibit distinct magnetic properties compared to bulk materials. This paper examines theoretically the properties of composites with nanoparticles, the key material parameters, and the characteristics of a single…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsMultiferroics and related materials

Part I: Surface-Enhanced Raman Spectroscopy Investigation of Amino Acids and Their Homodipeptides Adsorbed on Colloidal Silver

Edyta Podstawka、Yukihiro Ozaki、Leonard M. Proniewicz2004-05-01Applied Spectroscopy

Surface-enhanced Raman scattering spectra (SERS) were measured for various amino acids: L-methionine (Met), L-cysteine (Cys), Lglycine (Gly), L-leucine (Leu), L-phenylalanine (Phe), and L-proline (Pro) and their homodipeptides (Met-Met, Cys-Cys, Gly-Gly, LeuLeu, Phe-Phe, and Pro-Pro) in silver colloidal solutions. The…

Protein Interaction Studies and Fluorescence AnalysisGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Efficient Load Transfer to Polymer‐Grafted Multiwalled Carbon Nanotubes in Polymer Composites

Gan Lin Hwang、Yeong‐Tarng Shieh、Kuo Chu Hwang2004-05-01Advanced Functional Materials

Abstract Multiwalled carbon nanotubes (MWNTs) grafted with poly(methyl methacrylate) (PMMA) were synthesized by emulsion reactions and used as a reinforcement for commercial PMMA. Both scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed that the applied tensile load on the composites…

Tribology and Wear AnalysisCarbon Nanotubes in CompositesFiber-reinforced polymer composites

Core-Cross-Linked Polymeric Micelles as Paclitaxel Carriers

Xintao Shuai、Thomas Merdan、Andreas Schaper 等 5 位作者2004-05-01OpenAlex

Cross-linkable di- and triblock copolymers of poly(epsilon-caprolactone) (PCL) and monomethoxyl poly(ethylene glycol) (MPEG) were synthesized. These amphiphilic copolymers self-assembled into nanoscale micelles capable of encapsulating hydrophobic paclitaxel in their hydrophobic cores in aqueous solutions. To further…

Polymer Surface Interaction StudiesAdvanced Polymer Synthesis and CharacterizationNanoparticle-Based Drug Delivery

Adsorption of Lysozyme over Mesoporous Molecular Sieves MCM-41 and SBA-15: Influence of pH and Aluminum Incorporation

Ajayan Vinu、V. Murugesan、Martin Hartmann2004-05-01OpenAlex

The adsorption of lysozyme on the mesoporous molecular sieves MCM-41 and SBA-15 from buffered solutions with different pH values has been studied as a model protein adsorption system. The amount adsorbed depends on the solution pH as well as on the pore volume and the composition of the adsorbent. The adsorption isoth…

Protein purification and stabilityMesoporous Materials and CatalysisNanoparticle-Based Drug Delivery

Influence of the Surface Properties on Nanoparticle-Mediated Transport of Drugs to the Brain

Jörg Kreuter2004-05-01OpenAlex

Poly(alkyl cyanoacrylate) nanoparticles enable the delivery of a number of drugs, including doxorubicin, loperamide, tubocurarine, the NMDA receptor antagonist MRZ 2/576, and the peptides dalargin and kytorphin across the blood-brain barrier (BBB) after coating with surfactants. However, only the surfactants polysorba…

Nanoparticle-Based Drug DeliveryDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

Low-field amorphous state resistance and threshold voltage drift in chalcogenide materials

A. Pirovano、Andrea L. Lacaita、F. Pellizzer 等 6 位作者2004-05-01OpenAlex

A detailed investigation of the time evolution for the low-field resistance R/sub off/ and the threshold voltage V/sub th/ in chalcogenide-based phase-change memory devices is presented. It is observed that both R/sub off/ and V/sub th/ increase and become stable with time and temperature, thus improving the cell read…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesLiquid Crystal Research Advancements

The sol-gel encapsulation of enzymes

Alain C. Pierre2004-05-01OpenAlex

In the past decade, the encapsulation of enzymes inside inorganic sol-gel matrices has become a generic method to prepare efficient biocatalysts which are easy to recycle. In this review, the sol-gel processes useful for enzyme encapsulation, (mostly sol-gel silica) are outlined. Then, the most recent developments in…

Mesoporous Materials and CatalysisElectrochemical sensors and biosensorsAnalytical Chemistry and Sensors