Electrocatalytic Activity of Phthalocyanines in Secondary Lithium Cells
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Rhodium complexes as catalysts for hydrosilylation crosslinking of silicone rubber
Vulcanization of silicon rubber compound based on polysiloxanes containing vinyl and Si–H groups catalyzed by [RhCl(CO)2]2, [RhCl(C2H4)2]2, [RhCl(1,5-COD)]2, [RhCl(NBD)]2, RhCl[P(C6H5)3]3, and Rh(acac)3 (1,5-COD = 1,5-cyklooktadiene, NBD = norbornadiene, acac = acetylacetonate) has been studied in dependence on the ca…
Luminescence spectroscopy of CsI: Tl+
Emission and excitation spectra of the phosphor CsI: Tl+ have been measured between 4·2 K and room temperature. Quenched crystals of CsI: Tl+, when excited in any of the five absorption bands that lie between 290 and 238 nm, exhibit two overlapping luminescence bands that lie at 2·19 eV (560 nm) and 2·53 eV (490 nm) a…
Thermal alteration of oleic acid in the presence of clay catalysts with co‐catalysts
Abstract The effects of added co‐catalysts on the clay catalyzed polymerization of oleic acid have been investigated. Heating oleic acid at 230 C for 3 hr with a clay catalyst gave a polymer fraction (dimer and trimer acids, 35% yield) and a monomer fraction (branched chain isomers of oleic acid, 27% yield) as the maj…
Dielectric and mechanical properties of poly(vinyl chloride)–dioctylphthalate systems
The mechanical properties, tensile strength, and elongation were investigated for poly(vinyl chloride) (PVC) samples mixed with dioctylphthalate (DOP) at concentrations from 0 to 100 parts per hundred parts PVC at 23°C. It was found that the tensile strength decreased with the increase of concentration, and the elonga…
On grain boundary strength in sintered A12O3
Scanning and transmission electron microscopy and the C-Pt replica technique have been used to investigate grain boundary structures in sintered polycrystalline A12O3 with varying concentrations of MgO dopant. A method is proposed for evaluating the fracture toughness, Kβb c, and the strength of grain boundaries from…
A new hemispherical retarding field energy analyser for quantitative voltage measurements in the SEM
A retarding field energy analyser for quantitative voltage measurements which functionally connects a uniform extracting field with a hemispherical analysing field is described. The design principles are : (i) the centres of the hemispherical grids are to be put on the virtual source from which the secondary electron…
Preparation of amino group‐containing polymers by plasma polymerization
Abstract Plasma polymerizations of bis(dimethylamino)methylsilane (BDMAMVS), bis(dimethylamino) methylvinylsilane (BDMAMVS), and trimethylsilyldimethylamine (TMSDMA) were investigated by elemental analysis, IR spectroscopy, and ESCA. Polymer deposition was fairly faster in the BDMAMVS and TMSDMA systems than in the BD…
Darstellung und Struktur von Cs2As8S13 / Preparation and Structure of Cs2As8S13
Abstract The thioarsenate(III) Cs 2 As 8 S 13 has been prepared by the reaction of Cs 2 CO 3 with As 2 S 3 in aqueous solution under pressure at 180 °C. Its structure has been established by X-ray structural analysis. The polymeric anion (As 8 S 13 2- ) n is composed of individual As 4 S 4 -rings, which are each conne…
Viscoelastic Properties of a Class of Carboxylated Rubbers: The Carboxylato-Telechelic Polydienes
Abstract Halato telechelic polymers are well-characterized ion-containing polymers the investigation of which gives the scientist a clear insight into the role played by the ions in the modification of the base polymer properties. The end-neutralization of very short length, α,É-dicarboxylic acid polydienes by alkali…
Thermodynamic Stability of UMoO 6 by the Transpiration Method
The equilibrium vaporization of UMoO 6 (s) in dry air was studied by the transpiration method in the temperature interval 1110°≤ T (K) ≤ 1250°. Apparent pressure of the trimer measured over the two‐phase mixture UMoO 6 + U 3 O 8 , with dry air as the carrier gas, was used to calculate the partial pressure of the trime…
Nomenclature for crystal families, Bravais-lattice types and arithmetic classes. Report of the International Union of CrystallographyAd-HocCommittee on the Nomenclature of Symmetry
Standard symbols representing crystal families, two- and three-dimensional Bravais-lattice types and arithmetic classes are recommended for use by the IUCr. The six crystal families are designated by lower-case letters. The family letter in the symbol of each of the 14 lattice types is followed by an upper-case letter…
Density, Refractive Index and Ultrasonic Velocity Studies Involving N-(p-n-Pentyloxybenzylidene)-p-n-octylaniline
The density, refractive index and ultrasonic velocity dependence on temperature for N-(p-npentyloxybenzylidene)- p-n-octylaniline, 50.8, is presented. The compound 50.8 exhibits smectic-B, smectic-A and nematic phases between the solid and isotropic liquid phases. The nematic-isotropic and smectic A-smectic B phase tr…
The Preparation and Properties of Acrylic and Methacrylic Acid Grafted Cellulose Prepared by Ceric Ion Initiation. Part I. Preparation of the Grafted Cellulose
The ceric ion method has been used to graft acrylic acid directly onto cellulose with a minimum amount of homopolymer. The method utilizes the pretreatment of the cellulose with ceric ammonium nitrate followed by washing out any excess of the catalyst. Oxygen can be present with the pretreatment step, but must be excl…
Thermolysis rates and products of the putative ketochloroallyl groups in poly(vinyl chloride), as inferred from the behavior of analogous model compounds
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermolysis rates and products of the putative ketochloroallyl groups in poly(vinyl chloride), as inferred from the behavior of analogous model compoundsMary G. Panek, Gilberto M. Villacorta, and William H. Starnes Jr.Cite this: Macromolecules 1985, 18, 5, 1040–1041Publicati…
A New Equilibration Method for Cation‐Exchange Capacity Measurement
Abstract A method is proposed for the measurement of cation‐exchange capacity (CEC) of leached soils carrying both variable and constant negative charges at conditions pertinent to the field. The method consists of equilibrating a soil with 0.01 M SrCl 2 (five centrifuge washings), replacing the retained Sr with 0.5 M…
Synthesis and structure of the first 20-Bi-9 system: a discrete nine-coordinate 20-electron bismuth
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and structure of the first 20-Bi-9 system: a discrete nine-coordinate 20-electron bismuthConstantine A. Stewart, Joseph C. Calabrese, and Anthony J. Arduengo IIICite this: J. Am. Chem. Soc. 1985, 107, 11, 3397–3398Publication Date (Print):May 1, 1985Publication His…
Measures of the Molecular Tilt Angle and Optical Anisotropy n Ferroelectric Liquid Crystals
A pulse electr-optical technique is described which allows the molecular tilt angle and optical anisotropy of ferroelectric liquid crystals to be measured. The technique provides high accuracy and reproducibility of the measurement and is insensitive to the non-homogeneity of a liquid crystalline layer. The temperatur…
Combining direct methods with isomorphous replacement or anomalous scattering data. III. The incorporation of partial structure information
The probability formulas given in Parts I and II of this series have been improved by incorporating the information contained in Sim's distribution. Possible applications to the discrimination of the phase ambiguities arising from the single isomorphous replacement technique, the one-wavelength anomalous scattering (O…
High-spin .tautm. low-spin transition in solid Co(H2fsa2en)(H2O)2[H4fsa2en = N,N'-ethylenebis(3-carboxysalicylaldimine)]: a magnetic investigation
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-spin .tautm. low-spin transition in solid Co(H2fsa2en)(H2O)2[H4fsa2en = N,N'-ethylenebis(3-carboxysalicylaldimine)]: a magnetic investigationJacqueline Zarembowitch, Renee Claude, and Olivier KahnCite this: Inorg. Chem. 1985, 24, 10, 1576–1580Publication Date (Print):Ma…